Ln4(CH2)4 cubane-type rare-earth methylidene complexes consisting of "(C5Me4SiMe 3)LnCH2" Units (Ln = Tm, Lu)

Journal of the American Chemical Society

Volumn 133, Issue 15, 2011, Pages 5712-5715

  Zhang, Wen Xiong ^a,b   Wang, Zitao ^a,b   Nishiura, Masayoshi ^a   Xi, Zhenfeng ^b   Hou, Zhaomin ^a  

^a RIKEN   (Japan)

^b PEKING UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

C-C BOND FORMATION; C-H ACTIVATION; C-O BOND CLEAVAGE; OXO COMPLEXES; PHENYL GROUP; TRINUCLEAR COMPLEX;

ACTIVATION ANALYSIS;

ALKALINE EARTH METAL; ALKYL GROUP; BENZALDEHYDE; BENZOPHENONE; CARBON; CUBANE DERIVATIVE; HYDROGEN; METAL COMPLEX; METHANE; METHYLIDENE COMPLEX; OXYGEN; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHELATION; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTALLOGRAPHY; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY DIFFRACTION;

EID: 79954511788     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja200540b     Document Type: Article

References (50)

1. Fischer, E. O.; Maasböl, A. Angew. Chem., Int. Ed. Engl. 1964, 3, 580-581
2. Schrock, R. R. J. Am. Chem. Soc. 1974, 96, 6796-6797
3. Bourissou, D.; Guerret, O.; Gabbai, F. P.; Bertrand, G. Chem. Rev. 2000, 100, 39-91
4. Schrock, R. R. Angew. Chem., Int. Ed. 2006, 45, 3748-3759
5. Grubbs, R. H. Angew. Chem., Int. Ed. 2006, 45, 3760-3765
6. Arnold, P. L.; Casely, I. J. Chem. Rev. 2009, 109, 3599-3611
7. Arnold, P. L.; Pearson, S. Coord. Chem. Rev. 2007, 251, 596-609
8. Liddle, S. T.; Edworthy, I. S.; Arnold, P. L. Chem. Soc. Rev. 2007, 36, 1732-1744
9. Arnold, P. L.; Liddle, S. T. Chem. Commun. 2006, 3959-3971
10. Giesbrech, G. R.; Gordon, J. C. Dalton Trans. 2004, 2387-2393
11. Cavell, R. G.; Babu, R. P. K.; Aparna, K. J. Organomet. Chem. 2001, 617-618, 158-169
12. Schumann, H.; Müller, J. J. Organomet. Chem. 1979, 169, C1-C4
13. Aparna, K.; Ferguson, M.; Cavell, R. G. J. Am. Chem. Soc. 2000, 122, 726-727
14. Mills, D. P.; Soutar, L.; Lewis, W.; Blake, A. J.; Liddle, S. T. J. Am. Chem. Soc. 2010, 132, 14379-14381
15. Fustier, M.; Le Goff, X. F.; Le Floch, P.; Mézailles, N. J. Am. Chem. Soc. 2010, 132, 13108-13110
16. Mills, D. P.; Wooles, A. J.; McMaster, J.; Lewis, W.; Blake, A. J.; Liddle, S. T. Organometallics 2009, 28, 6771-6776
17. Mills, D. P.; Cooper, O. J.; McMaster, J.; Lewis, W.; Liddle, S. T. Dalton Trans. 2009, 4547-4555
18. Liddle, S. T.; McMaster, J.; Green, J. C.; Arnold, P. L. Chem. Commun. 2008, 1747-1749
19. Cantat, T.; Jaroschik, F.; Richard, L.; Le Floch, P.; Nief, F.; Mézailles, N. Organometallics 2006, 25, 1329-1332
20. Cantat, T.; Jaroschik, F.; Nief, F.; Richard, L.; Mézailles, N.; Le Floch, P. Chem. Commun. 2005, 5178-5180
21. Buchard, A.; Auffrant, A.; Ricard, L.; Le Goff, X. F.; Platel, R. H.; Williams, C. K.; Le Floch, P. Dalton Trans. 2009, 10219-10222
22. Liddle, S. T.; Mills, D. P.; Gardner, B. M.; McMaster, J.; Jones, C.; Woodul, W. D. Inorg. Chem. 2009, 48, 3520-3522
23. Wooles, A. J.; Cooper, O. J.; McMaster, J.; Lewis, W.; Blake, A. J.; Liddle, S. T. Organometallics 2010, 29, 2315-2321
24. Wooles, A. J.; Mills, D. P.; Lewis, W.; Blake, A. J.; Liddle, S. T. Dalton Trans. 2010, 39, 500-510
25. Roos, B. O.; Pyykkö, P. Chem.-Eur. J. 2010, 16, 270-275
26. Zhang, X.; Schwarz, H. Chem.-Eur. J. 2010, 16, 5882-5888
27. Cho, H.-G.; Andrews, L. Organometallics 2007, 26, 633-643
28. Clark, D. L.; Gordon, J. C.; Hay, P. J.; Poli, R. Organometallics 2005, 24, 5747-5758
29. Dietrich, H. M.; Törnroos, K. W.; Anwander, R. J. Am. Chem. Soc. 2006, 128, 9298-9299 For a methine cluster, see: Dietrich, H. M.; Grove, H.; Törnroos, K. W.; Anwander, R. J. Am. Chem. Soc. 2006, 128, 1458-1459
30. Litlabø, R.; Zimmermann, M.; Saliu, K.; Takats, J.; Törnroos, K. W.; Anwander, R. Angew. Chem., Int. Ed. 2008, 47, 9560-9564
31. Zimmermann, M.; Takats, J.; Kiel, G.; Törnroos, K. W.; Anwander, R. Chem. Commun. 2008, 612-614
32. Scott, J.; Fan, H.; Wicker, B. F.; Fout, A. R.; Baik, M.-H.; Mindiola, D. J. J. Am. Chem. Soc. 2008, 130, 14438-14439
33. Scott, J.; Basuli, F.; Fout, A. R.; Huffman, J. C.; Mindiola, D. J. Angew. Chem., Int. Ed. 2008, 47, 8502-8505
34. Scott, J.; Mindiola, D. J. Dalton Trans. 2009, 8463-8472
35. Zimmermann, M.; Rauschmaier, D.; Eichele, K.; Törnroos, K. W.; Anwander, R. Chem. Commun. 2010, 46, 5346-5348
36. Hong, J.; Zhang, L.; Yu, X.; Li, M.; Zhang, Z.; Zheng, P.; Nishiura, M.; Hou, Z.; Zhou, X. Chem.-Eur. J. 2011, 17, 2130-2137
37. Tardif, O.; Nishiura, M.; Hou, Z. Organometallics 2003, 22, 1171-1173
38. Nishiura, M.; Baldamus, J.; Shima, T.; Mori, K.; Hou, Z. Chem.-Eur. J., in press; DOI: 10.1002/chem.201002998.
39. Robert, D.; Spaniol, T. P.; Okuda, J. Eur. J. Inorg. Chem. 2008, 2801-2809
40. Zimmermann, M.; Litlabø, R.; Törnroos, K. W.; Anwander, R. Organometallics 2009, 28, 6646-6649
41. Kenward, A. L.; Piers, W. E.; Parvez, M. Organometallics 2009, 28, 3012-3020
42. Zhang, L.; Nishiura, M.; Yuki, M.; Luo, Y.; Hou, Z. Angew. Chem., Int. Ed. 2008, 47, 2642-2645
43. Sommerfeldt, H.-M.; Meermann, C.; Schrems, M. G.; Törnroos, K. W.; Frøystein, N. Å.; Miller, R. J.; Scheidt, E.-W.; Scherer, W.; Anwander, R. Dalton Trans. 2008, 1899-1907
44. Zimmermann, M.; Frøystein, N. Å.; Fischbach, A.; Sirsch, P.; Dietrich, H. M.; Törnroos, K. W.; Herdtweck, E.; Anwander, R. Chem.-Eur. J. 2007, 13, 8784-8800
45. Fischbach, A.; Anwander, R. Adv. Polym. Sci. 2006, 204, 155-281
46. Anwander, R.; Klimpel, M. G.; Dietrich, H. M.; Shorokhov, D. J.; Scherer, W. Chem. Commun. 2003, 1008-1009
47. Structural characterization of the same tetraoxo Lu complex has been reported previously. See: Shima, T.; Hou, Z. J. Am. Chem. Soc. 2006, 128, 8124-8125
48. The reaction of 3-Tm with PhCOMe or PhCHO gave a complicated product mixture from which a characterizable species could not be obtained.
49. 2H NMR spectroscopy were not successful, probably because of the low concentration of the gas in the solution and the influence of the paramagnetic Tm(III) species. Hydrolysis of the reaction mixture caused dehydration to give a product mixture containing 1,1-diphenylethylene, which made it difficult to obtain a decisive H/D ratio in the hydrolysis products.
50. w) = 0.052 (0.138).