Magnetic resonance in reaction engineering: Beyond spectroscopy

Current Opinion in Chemical Engineering

Volumn 2, Issue 3, 2013, Pages 331-337

  Gladden, Lynn F ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; MAGNETISM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUMERICAL METHODS;

CATALYTIC REACTOR; DIFFERENT LENGTH SCALE; DIFFUSION PROCESS; HETEROGENEOUS CATALYST; MOLECULAR ADSORPTION; NUCLEAR MAGNETIC RESONANCE (NMR); REACTION ENGINEERING; WORKING ENVIRONMENT;

NUCLEAR MAGNETIC RESONANCE;

EID: 84888356122     PISSN: None     EISSN: 22113398     Source Type: Journal    
DOI: 10.1016/j.coche.2013.05.005     Document Type: Review

References (58)

1. Bell AT, Pines A (Eds): NMR Techniques in Catalysis. New York: Marcel Dekker; 1994.
2. Engelhardt G, Koller H: 29Si NMR of inorganic solids. In NMR Basic Principles and Progress, edn 2 Edited by Blümich B. Berlin, Heidelberg, New York: Springer Verlag; 1994:1-29.
3. Pfiefer HH: In NMR of Solid Surfaces in NMR Basic Principles and Progress, edn 2 Edited by Blümich B. Berlin, Heidelberg, New York: Springer Verlag; 1994:31-90.
4. Hunger M, Wang W: Solid state NMR spectroscopy. In Handbook of Heterogeneous Catalysis, edn 2 Edited by Ertl G, Knoezinger H, Schueth F, Weitkamp J.Weinheim: Wiley-VCH; 2008:912-932.
5. Van der Klink JJ: The surface of supported metal catalysts probed by NMR. Adv Catal 1999, 44:1-117.
6. van der Klink JJ, Brom HB: NMR in metals, metal particles and metal cluster compounds. Prog Nucl Magn Reson Spectrosc 2000, 36:89-201.
7. Gladden LF, Lutecki M, McGregor J: Nuclear magnetic resonance spectroscopy. In Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity, vol 1 Edited by Che M, Védrine C. Wiley-VCH Verlag GmbH & Co. KGaA; 2012.
8. Haw JF, Nicholas JB, Xu T, Beck LW, Ferguson DB: Physical organic chemistry of solid acids: lessons from in situ NMR and theoretical chemistry. Acc Chem Res 1996, 29:259-267.
9. Ernst H, Freude D, Mildner T: Temperature-switched MAS, NMR: a new method for time-resolved in situ studies of reaction steps in heterogeneous catalysis. Chem Phys Lett 1994, 229:291-296.
10. Ferguson DB, Haw JF: Transient methods for in situ NMR of reactions on solid catalysts using temperature jumps. Anal Chem 1995, 67:3342-3348.
11. Keeler C, Xiong JC, Lock H, Dec S, Tao T, Maciel GE: A new in situ chemical reactor for studying heterogeneous catalysis by NMR: the GRASSHopper. Catal Today 1999, 49:377-383. (Pubitemid 129586860)
12. MacNamara E, Raftery D: A high-resolution solid-state NMR probe for in situ studies of heterogeneous catalysis under flowing conditions. J Catal 1998, 175:135-137. (Pubitemid 128684714)
13. Hunger M: In situ flow MAS NMR spectroscopy: state of the art and applications in heterogeneous catalysis. Prog Nucl Magn Reson Spectrosc 2008, 53:105-127.
14. Gladden LF: Magnetic resonance: ongoing and future role in chemical engineering research. AIChE J 2003, 49:2-9. (Pubitemid 36378207)
15. Gladden LF, Mantle MD, Sederman LF: Magnetic resonance imaging of catalysts and catalytic processes. Adv Catal 2006, 50:1-75. (Pubitemid 43636880)
16. Dumesic JA, Rudd DF, Aparicio LM, REkoske JE, Trevino AA: The Microkinetics of Heterogeneous Catalysis. Washington, DC: American Chemical Society; 1993, .
17. Rekoske JE, Cortright RD, Goddard SA, Sharma SB, Dumesic JA: Microkinetic analysis of diverse experimental data for ethylene hydrogenation on platinum. J Phys Chem 1992, 96:1880-1888.
18. Gokhale AA, Dumesic JA, Mavrikakis M: On the mechanism of low-temperature water gas shift reaction on copper. J Am Chem Soc 2008, 130:1402-1414. (Pubitemid 351171021)
19. Hansen N, Heyden A, Bell AT, Keil F: Microkinetic modelling of nitrous oxide decomposition on dinuclear oxygen bridged iron sites in Fe-ZSM-5. J Catal 2007, 248:213-225. (Pubitemid 46726352)
20. Gladden LF, Mitchell J: Measuring adsorption, diffusion and flow in chemical engineering: applications of magnetic resonance to porous media. New J Phys 2011, 13:035001.
21. Weber D, Mitchell J, McGregor J, Gladden LF: Comparing strengths of surface interactions for reactants and solvents in porous catalysts using two-dimensional NMR relaxation correlations. J Phys Chem C 2009, 113:6610-6615.
22. Mitchell J, Chandrasekera TC, Gladden LF: Numerical estimation of relaxation and diffusion distributions in two dimensions. Prog Nucl Magn Reson Spectrosc 2012, 62:34-50.
23. Stejskal ED, Tanner JE: Spin diffusion measurements: spin echoes in the presence of a time-dependent field gradient. J Chem Phys 1965, 42:288-292.
24. Tanner JE: Use of stimulated echo in NMR diffusion studies. J Chem Phys 1970, 52:2523-2526.
25. Hollewand MP, Gladden LF: Transport heterogeneity in porous pellets. 1. PGSE NMR studies. Chem Eng Sci 1995, 50:309-326.
26. Hollewand MP, Gladden LF: Transport heterogeneity in porous pellets. 2. NMR imaging studies under transient and steadystate conditions. Chem Eng Sci 1995, 50:327-344.
27. Fripiat JJ, Letellier M, Levitz P: Interaction of water with clay surfaces. Philos Trans R Soc Lond Ser A 1984, 311:287-299.
28. Halperin WP, Jehng JY, Song YQ: Application of spin-spin relaxation measurement to measurement of surface area and pore size distributions in a hydrating cement paste. Magn Reson Imaging 1994, 12:207-208.
29. Cotts RM, Hoch MJR, Sun T, Markert JT: Pulsed field gradient stimulated echo methods for improved NMR diffusion measurements in heterogeneous systems. J Magn Reson 1989, 83:252-266.
30. Weber D, Sederman AJ, Mantle MD, Mitchell J, Gladden LF: Surface diffusion in porous catalysts. Phys Chem Chem Phys 2010, 12:2619-2624.
31. Youngs TGA, Weber D, Gladden LF, Hardacre C: Liquid structure and dynamics of aqueous isopropanol over g-alumina. J Phys Chem C 2009, 113:21342-21352.
32. D'Agostino C, Brett GL, Miedziak PJ, Knight DW, Hutchings GJ, Gladden LF, Mantle MD: Understanding the solvent effect on the catalytic oxidation of 1,4-butanediol in methanol over Au/ TiO2 catalyst: NMR diffusion and relaxation studies. Chem Eur J 2012, 18:14426-14433.
33. D'Agostino C, Mitchell J, Gladden LF, Mantle MD: Hydrogen bonding network disruption in mesoporous catalyst supports probed by PFG-NMR diffusometry and relaxometry. J Phys Chem C 2012, 116:8975-8982.
34. Sederman AJ, Johns ML, Alexander P, Gladden LF: Structureflow correlations in packed beds. Chem Eng Sci 1998, 53:2117-2128.
35. Johns ML, Sederman AJ, Bramley AS, Gladden LF: Local transitions in flow phenomena through packed beds identified by MRI. AIChE J 2000, 46:2151-2161.
36. Sederman AJ, Gladden LF: Magnetic resonance imaging as a quantitative probe of gas-liquid distribution and wetting efficiency in trickle-bed reactors. Chem Eng Sci 2001, 56:2615-2628.
37. Ren XH, Stapf S, Blumich B: NMR velocimetry of flow in model fixed-bed reactors of low aspect ratio. AIChE J 2005, 51:392-405. (Pubitemid 40321672)
38. Anadon LD, Sederman AJ, Gladden LF: Mechanism of the trickle-to-pulse flow transition in fixed-bed reactors. AIChE J 2006, 52:1522-1532.
39. Yuen EHL, Sederman AJ, Gladden LF: In situ magnetic resonance visualisation of the spatial variation of catalytic conversion within a fixed-bed reactor. Appl Catal A 2002, 232:29-38. (Pubitemid 34614177)
40. Koptyug IV, Lysova AA, Kulikov A, Kirillov VA, Parmon VN, Sagdeev RZ: Functional imaging and NMR spectroscopy of an operating gas-liquid-solid catalytic reactor. Appl Catal A 2004, 267:143-148.
41. Sederman AJ, Mantle MD, Dunckley CP, Huang ZY, Gladden LF: In situ MRI study of 1-octene isomerisation and hydrogenation within a trickle-bed reactor. Catal Lett 2005, 103:1-8.
42. Dietrich W, Anadon L, Sederman A, Gladden L, Agar D: Simulation studies on the performance enhancement in periodically operated trickle-bed reactors based on experimental local liquid distribution measurements. Ind Eng Chem Res 2012, 51:1672-1679.
43. Bouchard L-S, Burt SR, Anwar MS, Kovtunov KR, Koptyug IV, Pines A: NMR imaging of catalytic hydrogenation in microreactors with the use of para-hydrogen. Science 2008, 319:442-445. (Pubitemid 351160572)
44. Kovtunov KV, Beck IE, Zhivonitko, Barskiy DA, Bukhtiyarov VI, Koptyug IV: Heterogeneous addition of H2 to double and triple bonds over supported Pd catalysts: a parahydrogen-induced polarisation technique study. Phys Chem Chem Phys 2012, 14:11008-11014.
45. Golman K, Petersson JS: Metabolic imaging and other applications of hyperpolarized 13Cl. Acad Radiol 2006, 13:932-942. (Pubitemid 44037467)
46. Lingwood M, Sederman AJ, Mantle MD, Gladden LF, Han S-I: Overhauser dynamic nuclear polarization amplification of NMR flow imaging. J Magn Reson 2012, 216:94-100.
47. Holub RA, Dudukovic MP, Ramachandran PA: Pressure drop, liquid holdup and flow regime transition in trickle flow. AIChE J 1993, 39:302-321. (Pubitemid 23616069)
48. Holub RA, Dudukovic MP, Ramachandran PA: A phenomenological model for the pressure drop, liquid holdup and flow regime transition in gas-liquid trickle flow. Chem Eng Sci 1992, 47:2343-2348. (Pubitemid 23603946)
49. Attou A, Boyer C, Ferschneider G: Modelling of the hydrodynamics of the cocurrent gas-liquid trickle flow through a trickle-bed reactor. Chem Eng Sci 1999, 54:785-802. (Pubitemid 29267166)
50. Lustig M, Donoho, Pauly JM: Sparse MRI: the application of compressed sensing for rapid MR imaging. Magn Reson Med 2007, 58:1182-1195. (Pubitemid 350234205)
51. Holland DJ, Malioutov DM, Blake A, Sederman AJ, Gladden LF: Reducing data acquisition times in phase-encoded velocity imaging using compressed sensing. J Magn Reson 2010, 203:236-246.
52. Tayler AB, Holland DJ, Sederman AJ, Gladden LF: Exploring the origins of turbulence in multiphase flow using compressed sensing MRI. Phys Rev Lett 2012, 108:264505.
53. Müller CR, Holland DJ, Sederman AJ, Dennis JS, Gladden LF: Magnetic resonance measurements of high-velocity particle motion in a three-dimensional gas-solid spouted bed. Phys Rev E 2010, 82:050302.
54. Holland DJ, Müller CR, Dennis JS, Gladden LF, Sederman AJ: Spatially resolved measurement of anisotropic granular temperature in gas-fluidized beds. Powder Technol 2008, 182:171-181. (Pubitemid 351186594)
55. Holland DJ, Müller CR, Dennis JS, Gladden LF, Davidson JF: Magnetic resonance studies of fluidization regimes. Ind Eng Chem Res 2010, 49:5891-5899.
56. Müller CR, Holland DJ, Third JR, Sederman AJ, Dennis JS, Gladden LF: Multi-scale magnetic resonance measurements and discrete element model simulations. Particuology 2011, 9:330-341.
57. Müller CR, Scott SA, Holland DJ, Clarke BC, Sederman AJ, Dennis JS, Gladden LF: Validation of a discrete element model using magnetic resonance measurements. Particuology 2009, 7:297-306.
58. Müller CR, Holland DJ, Sederman AJ, Scott SA, Dennis JS, Gladden LF: Granular temperature: comparison of magnetic resonance measurements with discrete element model simulations. Powder Technol 2008, 184:241-253.