A light-induced spin crossover actuated single-chain magnet

Nature Communications

Volumn 4, Issue , 2013, Pages

  Liu, Tao ^a   Zheng, Hui ^a   Kang, Soonchul ^b   Shiota, Yoshihito ^b   Hayami, Shinya ^c   Mito, Masaki ^d   Sato, Osamu ^b   Yoshizawa, Kazunari ^b   Kanegawa, Shinji ^b   Duan, Chunying ^a  

^a DALIAN UNIVERSITY OF TECHNOLOGY   (China)

^b KYUSHU UNIVERSITY   (Japan)

^c KUMAMOTO UNIVERSITY   (Japan)

^d KYUSHU INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

FERRIC ION; FERROUS ION;

HEAT BALANCE; IRON; LIGHT EFFECT; MAGNETIC PROPERTY; MOLECULAR ANALYSIS; TEMPERATURE EFFECT;

ACCELERATION; ARTICLE; HEAT; INFORMATION STORAGE; LIGHT; MAGNET;

EID: 84888253483     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms3826     Document Type: Article

References (43)

1. Gütlich, P. & Goodwin, H. A. (eds) Spin Crossover in Transition Metal Compounds I-III (Springer, 2004).
2. Real, J. A. et al. Spin crossover in a catenanesupramolecular system. Science 268, 265-267 (1995).
3. Kahn, O. & Martinez, C. J. Spin-transition polymers: from molecular materials toward memory devices. Science 279, 44-48 (1998). (Pubitemid 28079148)
4. Halder, G. J., Kepert, C. J., Moubaraki, B., Murray, K. S. & Cashion, J. D. Guestdependent spin crossover in a nanoporousmolecular framework material. Science 298, 1762-1765 (2002). (Pubitemid 35404114)
5. Bousseksou, A., Molnár, G., Demont, P. & Menegotto, J. Observation of a thermal hysteresis loop in the dielectric constant of spin crossover complexes: toward molecular memory devices. J. Mater. Chem. 13, 2069-2071 (2003).
6. Prins, F. et al. Room-temperature electrical addressing of a bistable spincrossover molecular system. Adv. Mater. 23, 1545-1549 (2011).
7. Venkataramani, S. et al. Magnetic bistability of molecules in homogeneous solution at room temperature. Science 331, 445-448 (2011).
8. Gatteschi, D., Sessoli, R. & Villain, J. Molecular Nanomagnets (Oxford Universuty Press, 2006).
9. Sessoli, R., Gatteschi, D., Caneschi, A. & Novak, M. A. Magnetic bistability in a metal-ion cluster. Nature 365, 141-143 (1993).
10. Mannini, M. et al. Quantum tunneling of the magnetization in a monolayer of oriented single-molecule magnets. Nature 468, 417-421 (2010).
11. Rinehart, J. D., Fang, M., Evans, W. J. & Long, J. R. Strong exchange and magnetic blocking in N2 3-radical-bridged lanthanide complexes. Nat. Chem. 3, 538-542 (2011).
12. Vincent, R., Klyatskaya, S., Ruben, M., Wernsdorfer, W. & Balestro, F. Electronic read-out of a single nuclear spin using amolecular spin transistor. Nature 488, 357-359 (2012).
13. Bogani, L. & Wernsdorfer, W. Molecular spintronics using single-molecule magnets. Nat. Mater. 7, 179-186 (2008). (Pubitemid 351311291)
14. Clérac, R., Miyasaka, H., Yamashita, M. & Coulon, C. Evidence for single-chain magnet behaviour in a MnIII-NiII chain designed with high spin magnetic units: a route to high temperature metastable magnets. J. Am. Chem. Soc. 124, 12837-12844 (2002). (Pubitemid 35216007)
15. Caneschi, A. et al. Cobalt(ii)-nitronyl nitroxide chains as molecular magnetic nanowires. Angew. Chem. Int. Ed. 40, 1760-1763 (2001). (Pubitemid 32441103)
16. Miyasaka, H., Julve, M., Yamashita, M. & Clérac, R. Slow dynamics of the magnetization in one-dimensional coordination polymers: single-chain magnets. Inorg. Chem. 48, 3420-3427 (2009).
17. Zhang, W. X., Ishikawa, R., Breedlove, B. & Yamashita, M. Single-chain magnets: beyond the Glauber model. RSC Adv. 3, 3772-3798 (2013).
18. Sun, H. L., Wang, Z. M. & Gao, S. Strategies towards single-chain magnets. Coord. Chem. Rev. 254, 1081-1100 (2010).
19. Decurtins, S., Gütlich, P., Köhler, C. P., Spiering, H. & Hauser, A. Ligt-induced excited spin state trapping in a transition-metal complex: the hexa-1-propyltetrazole-iron(II) tetrafluoroborate spin-crossover system. Chem. Phys. Lett. 105, 1-4 (1984).
20. Gütlich, P., Hauser, A. & Spiering, H. Thermal and optical switching of iron(II) complexes. Angew. Chem. Int. Ed. 33, 2024-2054 (1994). (Pubitemid 24987674)
21. Nasu, K. Relaxations of Excited States and Photo-Induced Structural Phase Transitions (Springer, 1997).
22. Létard, J. F. et al. Structural, magnetic, and photomagnetic studies of a mononuclear iron(II) derivative exhibiting an exceptionally abrupt spintransition. Light-induced thermal hysteresis phenomenon. Inorg. Chem. 37, 4432-4441 (1998).
23. Ogawa, Y. et al. Dynamical aspects of the photoinduced phase transition in spincrossover complexes. Phys. Rev. Lett. 84, 3181-3184 (2000).
24. Hayami, S. et al. First observation of light-induced excited spin state trapping for an Iron(III) complex. J. Am. Chem. Soc. 122, 7126-7127 (2000). (Pubitemid 30639893)
25. Létard, J. F. et al. Light induced excited pair spin state in an Iron(II) binuclear spin-crossover compound. J. Am. Chem Soc. 121, 10630-10631 (1999).
26. Breuning, E. et al. Spin crossover in a supramolecular Fe4II [2-2] grid triggered by temperature, pressure, and light. Angew. Chem. Int. Ed. 39, 2504-2507 (2000).
27. Renz, F. et al. Strong field iron (II) complex converted by light into a long-lived high-spin state. Angew. Chem. Int. Ed. 39, 3699-3700 (2000).
28. Nihei, M. et al. Two-step spin conversion in a cyanide-bridged ferrous square. Angew. Chem. Int. Ed. 44, 6484-6487 (2005). (Pubitemid 41509130)
29. Hayami, S., Juhasz, G., Maeda, Y., Yokoyama, T. & Sato, O. Novel structural and magnetic properties of a 1-D Iron(II)-Manganese(II) LIESST compound bridged by cyanide. Inorg. Chem. 44, 7289-7291 (2005).
30. Ould-Moussa, N. et al. Wavelength selective light-induced magnetic effects in the binuclear spin crossover compound {[Fe(bt)(NCS)2]2(bpym)}. Phys. Rev. B 75, 054101 (2007).
31. Nishihara, T., Nihei, M., Oshio, H. & Tanaka, K. The light-induced spin transition of tetranuclear spin crossover complex [Fe4(CN)4(bpy)4(tpa)2] (PF6)4. J. Phys. Confer. Ser. 148, 012033 (2009).
32. Wei, R.-J., Huo, Q., Tao, J., Huang, R.-B. & Zheng, L.-S. Spin-crossover FeII 4 squares: two-step complete spin transition and reversible single-crystal-tosingle-crystal transformation. Angew. Chem. Int. Ed. 50, 8940-8943 (2011).
33. Mondal, A. et al. Photomagnetic effect in a cyanide-bridged mixed-valence {FeII 2FeIII 2} molecular square. Chem. Commun. 48, 5653-5655 (2012).
34. Ohkoshi, S., Imoto1, K., Tsunobuchi, Y., Takano, S. & Tokoro, H. Lightinduced spin-crossover magnet. Nat. Chem. 3, 564-569 (2011).
35. Dong, D.-P. et al. Photoswitchable dynamic magnetic relaxation in a wellisolated {Fe2Co} double-zigzag chain. Angew. Chem. Int. Ed. 51, 5119-5123 (2012).
36. Hoshino, N. et al. Three-way switching in a cyanide-bridged [CoFe] chain. Nat. Chem. 4, 921-926 (2012).
37. Heintze, E. et al. Dynamic control of magnetic nanowires by light-induced domain-wall kickoffs. Nat. Mater. 12, 202-206 (2013).
38. Mitsumoto, K., Ui, M., Nihei, M., Nishikawa, H. & Oshio, H. Single chain magnet of a cyanide bridged FeII/FeIIIcomplex. CrystEngComm 12, 2697-2699 (2010).
39. Li, D. et al. Single-molecule magnets constructed from cyanometalates: {[TpFeIII(CN)3MII(DMF)4]2[OTf]2}-2DMF (MIICo, Ni). Inorg. Chem. 44, 4903-4905 (2005).
40. Reiher, M., Salomon, O. & Hess, B. A. Reparameterization of hybridfunctionals based on energy differences of states of different multiplicity. Theor. Chem. Acc. 107, 48-55 (2001). (Pubitemid 33576519)
41. Dolg, M., Wedig, U., Stoll, H. & Preuss, H. Energy-adjusted ab initio pseudopotentials for the first row transition elements. J. Chem. Phys. 86, 866-872 (1987).
42. Dunning, Jr. T. H. & Hay, P. J. in Modern Theoretical Chemistry Vol. 3 (Ed. Schaefer, III H. F.) 1-28 (Plenum, New York, 1976).
43. Frisch, M. J. et al. Gaussian 09, Revision C.1 (Gaussian, Inc., Wallingford, CT, 2009).