Magnetic bistability of molecules in homogeneous solution at room temperature

Science

Volumn 331, Issue 6016, 2011, Pages 445-448

  Venkataramani, S ^a   Jana, U ^a,b   Dommaschk, M ^a   Sonnichsen F D ^a   Tuczek, F ^a   Herges, R ^a  

^a UNIVERSITY OF KIEL   (Germany)

^b JADAVPUR UNIVERSITY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AZOBENZENE; BENZALDEHYDE; DIMETHYL SULFOXIDE; FERRIC ION; FERROMAGNETIC MATERIAL; FERROUS ION; HOMOGENEOUS SOLUTION; MISCELLANEOUS DRUGS AND AGENTS; NICKEL COMPLEX; PORPHYRIN; PYRIDINE; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CIS ISOMER; DENSITY FUNCTIONAL THEORY; ENERGY TRANSFER; HALF LIFE TIME; HYSTERESIS; IRRADIATION; ISOMERIZATION; LIGHT; MAGNETIC BISTABILITY; MOLECULAR STABILITY; MOLECULE; NUCLEAR MAGNETIC RESONANCE IMAGING; NUCLEAR OVERHAUSER EFFECT; PHOTOREACTIVITY; PRIORITY JOURNAL; ROOM TEMPERATURE; ULTRAVIOLET SPECTROPHOTOMETRY;

EID: 79954531326     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1201180     Document Type: Article

References (41)

1. P. Gütlich, H. A. Goodwin, Eds., Spin Crossover in Transition Metal Compounds I-III (Springer, Berlin, 2004).
2. O. Sato, J. Tao, Y.-Z. Zhang, Angew. Chem. Int. Ed. Engl. 46, 2152 (2007).
3. K. S. Murray, C. J. Kepert, Top. Curr. Chem. 233, 195 (2004).
4. J. Larionova et al., Angew. Chem. Int. Ed. Engl. 47, 8236 (2008).
5. I. Šalitroš, N. T. Madhu, R. Boča, J. Pavlik, M. Ruben, Monatsh. Chem. 140, 695 (2009).
6. F. Renz et al., Angew. Chem. Int. Ed. Engl. 39, 3699 (2000).
7. J.-F. Létard, J. Mater. Chem. 16, 2550 (2006).
8. I. Boldog et al., Angew. Chem. Int. Ed. Engl. 47, 6433 (2008).
9. C. Roux, J. Zarembowitch, B. Gallois, T. Granier, R. Claude, Inorg. Chem. 33, 2273 (1994).
10. M.-L. Boillot, C. Roux, J.-P. Audière, A. Dausse, J. Zarembowitch, Inorg. Chem. 35, 3975 (1996).
11. A. Sour, M.-L. Boillot, E. Rivière, P. Lesot, Eur. J. Inorg. Chem. 1999, 2117 (1999).
12. M.-L. Boillot, S. Chantrine, J. Zarembowitch, J.-Y. Lallemond, J. Prunet, N. J. Chem. 1999, 19 (1999).
13. K. Sénéchal-David et al., Dalton Trans. 2009 (14), 1932 (2008).
14. J. S. Kolb et al., C. R. Chim. 10, 125 (2007).
15. M.-L. Boillot et al., Inorg. Chem. 48, 4729 (2009).
16. Y. Hasegawa, S. Kume, H. Nishihara, Dalton Trans. 2009, 280 (2009).
17. S. Hirose, S. Hayami, Y. Maeda, Bull. Chem. Soc. Jpn. 73, 2059 (2000).
18. F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann, Advanced Inorganic Chemistry (Wiley Interscience, New York, ed. 6, 1999).
19. S. Thies et al., Chemistry 16, 10074 (2010).
20. E. V. Brown, G. R. Granneman, J. Am. Chem. Soc. 97, 621 (1975).
21. J. Otsuki, K. Narutaki, J. M. Bakke, Chem. Lett. 33, 356 (2004).
22. J. Otsuki, K. Narutaki, Bull. Chem. Soc. Jpn. 77, 1537 (2004).
23. K. Suwa, J. Otsuki, K. Goto, Tetrahedron Lett. 50, 2106 (2009).
24. For a similar molecular design, see (40).
25. TURBOMOLE, version 6.0, R. Ahlrichs et al., Universität Karlsruhe, 2009; www.turbomole.com.
26. Materials and methods are available as supporting material on Science Online.
27. G. N. LaMar, W. D. Horrocks, R. H. Holm, NMR of Paramagnetic Molecules: Principles and Applications (Academic Press, New York, 1973).
28. L. J. Berliner, J. Reuben, NMR of Paramagnetic Molecules (Plenum, New York, 1993).
29. D. Kim, C. Kirmaier, D. Holten, Chem. Phys. 75, 305 (1983).
30. D. Kim, D. Holten, Chem. Phys. Lett. 98, 584 (1983).
31. J. Rodriguez, D. Holten, J. Chem. Phys. 92, 5944 (1990).
32. H. Sugimoto, T. Kimura, S. Inoue, J. Am. Chem. Soc. 121, 2325 (1999).
33. R. S. Stoll et al., J. Am. Chem. Soc. 131, 357 (2009).
34. A. Berkessel, J. W. Bats, C. Schwarz, Agnew. Chem. Int. Ed. Engl. 29, 106 (1990).
35. Special issue on Molecular Spintronics and Quantum Computing, J. Mater. Chem. 19, 1661–1767 (2009).
36. J. Otsuki, Coord. Chem. Rev. 254, 2311 (2010).
37. F. Matino et al., Chem. Commun. (Camb.) 46, 6780 (2010).
38. R. B. Lauffer, Chem. Rev. 87, 901 (1987).
39. L. Knutsson, F. Ståhlberg, R. Wirestam, Magn. Reson. Mater. Phys. 23, 1 (2010).
40. H. Sugimoto, K. Kuramoto, S. Inoue, Perkin Trans. 1, 1826 (2002).
41. This work was supported by the Deutsche Forschungsgemeinschaft through SFB 677. We thank the Alexander von Humboldt Foundation for a research