Alkylammonium Chains on Layered Clay Mineral Surfaces

Rubber-Clay Nanocomposites: Science, Technology, and Applications

Volumn , Issue , 2011, Pages 101-125

  Heinz, Hendrik ^a  

^a University of Akron   (United States)

Author keywords

Alkylammonium chains; Clay mineral dispersion; Organoclay thermal property

Indexed keywords

EID: 84886576471     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9781118092866.ch4     Document Type: Chapter

References (42)

1. Lagaly, G.; Weiss, A. Arrangement and orientation of cationic tensides on silicate surfaces. 2. Paraffin-like structures in alkylammonium layer silicates with a high layer charge (mica). Koll. Z. Z. Polym., 237, 364-368 (1970).
2. Lagaly, G.; Weiss, A. Arrangement and orientation of cationic tensides on silicate surfaces. 4. Arrangement of alkylammonium ions in low-charged silicates in films. Koll. Z. Z. Polym., 243, 48-55 (1971).
3. Lagaly, G. Kink-block and gauche-block structures of bimolecular films. Angew. Chem. Int. Ed., 15, 575-586 (1976).
4. Vaia, R. A.; Teukolsky, R. K.; Giannelis, E. P. Interlayer structure and molecular environment of alkylammonium layered silicates. Chem. Mater., 6, 1017-1022 (1994).
5. Vaia, R. A.; Giannelis, E. P. Lattice model of polymer melt intercalation in organically modified layered silicates. Macromolecules, 30, 7990-7999 (1997).
6. Vaia, R. A.; Giannelis, E. P. Polymer melt intercalation in organically modified layered silicates: model predictions and experiment. Macromolecules, 30, 8000-8009 (1997).
7. Hackett, E.; Manias, E.; Giannelis, E. P. Molecular dynamics simulations of organically modified layered silicates. J. Chem. Phys., 108, 7410-7415 (1998).
8. Hayes, W. A.; Schwartz, D. K. Two-stage growth of octadecyltrimethyl-ammonium bromide monolayers at mica from aqueous solution below the Krafft point. Langmuir, 14, 5913-5917 (1998).
9. Brovelli, D.; Caseri, W. R.; Hahner, G. Self-assembled monolayers of alkylammonium ions on mica: direct determination of the orientation of the alkyl chains. J. Coll. Interface Sci. 216, 418-423 (1999).
10. Osman, M. A.; Seyfang, G.; Suter, U.W. Two-dimensional melting of alkane monolayers ionically bonded to mica. J. Phys. Chem. B, 104, 4433-4439 (2000).
11. Pospisil, M.; Capkova, P.; Merinska, D.; Malac, Z.; Simonik, J. Structure analysis of montmorillonite intercalated with cetylpyridinium and cetyltrimethylammonium: molecular simulations and XRD analysis. J. Coll. Interface Sci.; 236, 127-131 (2001).
12. Osman, M. A.; Ernst, M.; Meier, B. H.; Suter, U.W. Structure and molecular dynamics of alkane monolayers self-assembled on mica platelets. J. Phys. Chem. B, 106, 653-662 (2002).
13. Kuppa, V.; Manias, E. Computer simulation of PEO/layered silicate nanocomposites: 2. Lithiumdynamics in PEO/Lí montmorillonite intercalates. Chem. Mater., 14, 2171-2175 (2002).
14. Heinz, H.; Castelijns, H. J.; Suter, U.W. Structure and phase transitions of alkyl chains on mica. J. Am. Chem. Soc., 125, 9500-9510 (2003).
15. Pospisil, M.; Kalendova, A.; Capkova, P.; Simonik, J.; Valaskova, M. Structure analysis of intercalated layer silicates: combination of molecular simulations and experiment. J. Coll. Interface Sci., 277, 154-161 (2004).
16. Heinz, H.; Suter, U. W. Surface structure of organoclays. Angew. Chem. Int. Ed., 43, 2239-2243 (2004).
17. Osman, M. A.; Ploetze, M.; Skrabal, P. J. Structure and properties of alkylammonium monolayers self-assembled on montmorillonite platelets. Phys. Chem. B, 108, 2580-2588 (2004).
18. Heinz, H.; Paul, W.; Binder, K.; Suter, U.W. Analysis of the phase transitions in alkyl-mica by density and pressure profiles. J. Chem. Phys., 120, 3847-3854 (2004).
19. Zeng, Q. H.; Yu, A. B.; Lu, G. Q.; Standish, R. K. Molecular dynamics simulation of the structural and dynamic properties of dioctadecyldimethyl ammoniums in organoclays. J. Phys. Chem. B, 108, 10025-10033 (2004).
20. Zhu, J. X.; He, H. P.; Zhu, L. Z.;Wen, X. Y.; Deng, F. J. Characterization of organic phases in the interlayer of montmorillonite using FTIR and 13C NMR. J. Coll. Interface. Sci., 286, 239-244 (2005).
21. Lewin, M.; Mey-Marom, A.; Frank, R. Surface free energies of polymeric materials, additives, and minerals. Polym. Adv. Technol., 16, 429-441 (2005).
22. Osman, M. A., Rupp, J. E. P.; Suter, U. W. Gas permeation properties of polyethylenelayered silicate nanocomposites. J. Mater. Chem., 15, 1298-1304 (2005).
23. Pandey, R. B.; Anderson, K. L.; Heinz, H.; Farmer, B. L. Conformation and dynamics of a self-avoiding sheet: bond-fluctuation computer simulation. J. Polym. Sci. B, 43, 1041-1046 (2005)
24. Heinz, H.; Koerner, H.; Anderson, K. L.; Vaia, R. A.; Farmer, B. L. Force field for micatype silicates and dynamics of octadecylammonium chains grafted to montmorillonite. Chem. Mater., 17, 5658-5669 (2005).
25. Greenwell, H. C.; Harvey, M. J.; Boulet, P.; Bowden, A. A.; Coveney, P. V.; Whiting, A. Interlayer structure and bonding in nonswelling primary amine intercalated clays. Macromolecules, 38, 6189-6200 (2005).
26. He, H. P.; Galy, J.; Gerard, J. F. Molecular simulation of the interlayer structure and the mobility of alkyl chains in HDTMA{thorn}/montmorillonite hybrids. J. Phys. Chem. B, 109, 13301-13306 (2005).
27. Heinz, H.; Vaia, R. A.; Farmer, B. L. Interaction energy and surface reconstruction between sheets of layered silicates. J. Chem. Phys., 124, 224713 (2006).
28. Jacobs, J. D.; Koerner, H.; Heinz, H.; Farmer, B. L.; Mirau, P.; Garrett, P. H.; Vaia, R. A. Dynamics of alkyl ammonium intercalants within organically modified montmorillonite:dielectric relaxation and ionic conductivity. J. Phys. Chem. B, 110, 20143-20157 (2006).
29. Heinz, H.; Vaia, R. A.; Krishnamoorti, R.; Farmer, B. L. Self-assembly of alkylammonium chains on montmorillonite: effect of chain length, headgroup structure, and cation exchange capacity. Chem. Mater., 19, 59-68 (2007).
30. Fermeglia, M.; Pricl, S. Multiscale modeling for polymer systems of industrial interest. Prog. Org. Coat., 58, 187-199 (2007).
31. Scocchi, G.; Posocco, P.; Fermeglia, M.; Pricl, S. Polymer-clay nanocomposites: a multiscale molecular modeling approach. J. Phys. Chem. B, 111, 2143-2151 (2007).
32. Heinz, H., Vaia, R.A.;Farmer, B.L. Relationbetweenpackingdensityandthermal transitions of alkyl chains on layered silicate and metal surfaces. Langmuir, 24, 3727-3733 (2008).
33. Heinz, H.; Vaia, R. A.; Koerner, H.; Farmer, B. L. Photoisomerization of azobenzene grafted to montmorillonite: simulation and experimental challenges. Chem. Mater., 20, 6444-6456 (2008).
34. Fu, Y. T.; Heinz, H. Cleavage energy of alkylammonium-modified montmorillonite and the relation to exfoliation in nanocomposites: influence of cation density, head group structure, and chain length. Chem. Mater., 22, 1595-1605 (2010).
35. Fu, Y. T.; Heinz, H. Structure and cleavage energy of surfactant-modified clay minerals:Influence of CEC, head group, and chain length. Phil. Mag., 90, 2415-2424 (2010).
36. Heinz, H.; Suter, U.W. Atomic charges for classical simulations of polar systems. J. Phys. Chem. B, 108, 18341-18352 (2004).
37. Zartman, G. D.; Liu, H.; Akdim, B.; Pachter, R.; Heinz, H. Nanoscale tensile, shear, and failure properties of layered silicates as a function of cation density and stress. J. Phys. Chem. C, 114, 1763-1772 (2010).
38. Giese, R. F.; van Oss, C. J. Colloid and Surface Properties of Clays and Related Minerals, Dekker, New York, 2002.
39. Yariv, S.; Cross, H (eds.). Organo-Clay Complexes and Interactions, Dekker, New York, 2002.
40. Kamal, M. R.; Calderon, J. U.; Lennox, R. B. Surface energy of modified nanoclays and its effect on polymer/clay nanocomposites. J. Adhesion Sci. Technol., 23, 663-688 (2009).
41. Chen, B.; Evans, J. R. G. Elastic moduli of clay platelets. Scripta Mater., 54, 1581-1585 (2006).
42. Brandrup, J.; Immergut, E. H.; Grulke, E. A. (eds.). Polymer Handbook, Wiley, New York, 1999.