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Volumn 30, Issue 25, 1997, Pages 8000-8009

Polymer melt intercalation in organically-modified layered silicates: Model predictions and experiment

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIUM COMPOUNDS; ANNEALING; MOLECULAR WEIGHT; MOLTEN MATERIALS; POLYMERS; SILICATES; THERMAL EFFECTS;

EID: 0031341475     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9603488     Document Type: Article
Times cited : (1101)

References (36)
  • 16
    • 0001118411 scopus 로고
    • Bailey, S. W., Ed.; Reviews in Mineralogy Vol. 19; Mineralogical Society of America: Washington, DC
    • Güven, N. In Hydrous Phyllosilicates; Bailey, S. W., Ed.; Reviews in Mineralogy Vol. 19; Mineralogical Society of America: Washington, DC, 1988; pp 497-560.
    • (1988) Hydrous Phyllosilicates , pp. 497-560
    • Güven, N.1
  • 17
    • 85033163827 scopus 로고    scopus 로고
    • For a detailed discussion of the interlayer structure of alkylmodified OLS's, see ref 18 and references contained therein
    • For a detailed discussion of the interlayer structure of alkylmodified OLS's, see ref 18 and references contained therein.
  • 19
    • 85033169705 scopus 로고
    • Doctoral Thesis, Cornell University
    • Vaia, R. A. Doctoral Thesis, Cornell University, 1995.
    • (1995)
    • Vaia, R.A.1
  • 25
    • 85033165313 scopus 로고    scopus 로고
    • note
    • 1H NMR spectra of cyclohexane, toluene, pyridine, and 3-bromotoluene by comparing the relative shielding and deshielding of the ring protons.
  • 26
    • 85033159939 scopus 로고    scopus 로고
    • note
    • In contrast to the planar conformation of the rings with resonance structures, cyclohexane posses a boat conformation, and thus it might interact differently with the OLS. For a first approximation, we ignore these geometric effects.
  • 27
    • 85033174173 scopus 로고    scopus 로고
    • note
    • ap ∼ 0 determined from the surface tensions, lending validity to our methodology of calculating values for the interaction parameters.
  • 31
    • 85033180797 scopus 로고    scopus 로고
    • note
    • 14-16
  • 32
    • 85033182943 scopus 로고    scopus 로고
    • note
    • 19 the interlayer E→ field may be shown to be approximately zero using Gausses law. This is a reasonable assumption, since the cationic head group would prefer to reside close to the anionically-charged surface.
  • 33
    • 85033166878 scopus 로고    scopus 로고
    • note
    • 19


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.