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Volumn 30, Issue 25, 1997, Pages 7990-7999

Lattice model of polymer melt intercalation in organically-modified layered silicates

Author keywords

[No Author keywords available]

Indexed keywords

CONFORMATIONS; CRYSTAL LATTICES; ENTROPY; FREE ENERGY; MATHEMATICAL MODELS; MOLTEN MATERIALS; NEMATIC LIQUID CRYSTALS; POLYMERS; SILICATES; SURFACE ACTIVE AGENTS;

EID: 0031335108     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9514333     Document Type: Article
Times cited : (872)

References (65)
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    • MRS Proceedings: Pittsburgh, PA
    • Nazar, L. F.; et al. Solid State Ionics II; MRS Proceedings: Pittsburgh, PA, 1991; p 210.
    • (1991) Solid State Ionics II , pp. 210
    • Nazar, L.F.1
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    • 0003544037 scopus 로고
    • Cornell University Press: Ithaca, NY, (see also references therein)
    • de Gennes, P. G. Scaling Concepts in Polymer Physics; Cornell University Press: Ithaca, NY, 1979 (see also references therein).
    • (1979) Scaling Concepts in Polymer Physics
    • De Gennes, P.G.1
  • 51
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    • Klatte, S. J.; Beck, T. L. J. Phys. Chem. 1993, 97, 5727. Vacatello, M.; Yoon, D. Y.; Laskowski, B. C. J. Chem. Phys. 1990, 93, 779.
    • (1993) J. Phys. Chem. , vol.97 , pp. 5727
    • Klatte, S.J.1    Beck, T.L.2
  • 53
    • 85033179792 scopus 로고    scopus 로고
    • note
    • 0. However, these alternative expressions do not add any additional qualitative insight to that obtained from the random-flight approximation.
  • 56
    • 85033168760 scopus 로고    scopus 로고
    • For simplicity, the ammonium head group of the aliphatic chains is assumed to interact with the system as part of the silicate surface
    • For simplicity, the ammonium head group of the aliphatic chains is assumed to interact with the system as part of the silicate surface.
  • 60
    • 85033170806 scopus 로고    scopus 로고
    • note
    • 58 For our purpose of establishing trends and guidelines, a is assumed to be zero.
  • 62
    • 85033173314 scopus 로고    scopus 로고
    • note
    • 30 Although this expression improves the approximation of the extended chain length by 5-10%, it substantially increases the complexity of the theoretical expressions because of the increased number of different segment units used to describe the tethered chain.


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