Piezo- and Photo-Crystallography Applied to Spin-Crossover Materials

Spin-Crossover Materials: Properties and Applications

Volumn , Issue , 2013, Pages 507-526

  Guionneau, Philippe ^a   Collet, Eric ^b  

^a UNIVERSITÉ DE BORDEAUX   (France)

^b UNIVERSITÉ DE RENNES 1   (France)

Author keywords

Photo crystallography; Photoexcited SCO materials; Piezo crystallography; Spin crossover (SCO) materials

Indexed keywords

EID: 84886504209     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9781118519301.ch20     Document Type: Chapter

References (116)

1. Cambi, L., Szego, L. (1931) Über die magnetische Susceptibilität der komplexen Verbindungen. Ber. Drsch. Chem. Ges. Teil B, 64: 2591-2598.
2. 2 states in iron(III) dithio chelates. Inorg. Chem., 8: 1837-1846.
3. Bargeron, C. B.,Avinor, M., Drickamer, H. G. (1971) Effect of pressure on the spin state of iron(II) in manganese(IV) sulfide. Inorg. Chem., 10: 1338-1339.
4. 11 complexes by pulsed laser irradiation in the metal-to-ligand charge-transfer absorption band. J. Chem. Soc. Chem. Comm., 906-907.
5. Decurtins, S., Gütlich, P., Kölher, C. P., Spiering, H., Hauser, A. (1984) Light-induced excited spin state trapping in a transition-metal complex: the hexa-1-propyltetrazole-iron (II) tetrafluoroborate spin-crossover system. Chem. Phys. Lett., 105: 1-4.
6. Fisher, D. C., Drickamer, H. G. (1971) Effect of pressure on the spin state of iron in ferrous phenanthroline compounds. J. Chem. Phys., 54: 4825-4837.
7. Slichter, C. P., Drickamer, H. G. (1972) Pressure-induced electronic changes in compounds of iron. J. Chem. Phys., 56: 2142-2160.
8. Grey, J. K., Butler, I. S. (2001) Effects of high external pressures on the electronic spectra of coordination compounds. Coord. Chem. Rev., 219-221: 713-759.
9. 3) by application of high external pressures. Inorg. Chim. Acta, 35: 317-318.
10. Ohnishi, S. (1978) A theory of the pressure-induced high-spin-low-spin transition of transition-metal oxides. Phys. Earth Planet. Int., 17: 130-139.
11. McGammon, C., Kantor, I., Narygina, O., Rouquette, J., Ponkratz, U., Sergueev, I., Mezouar, M., Prakapenka, V., Dubrovinsky, L. (2008) Stable intermediate-spin ferrous iron in lower-mantle perovskite. Nature Geosci., 1: 684-687.
12. Fortes, A. D., Suard, E., Knight, K. S. (2011) Negative linear compressibility and massive anisotropic thermal expansion in methanol monohydrate. Science, 311: 742-746.
13. Weber, G., Drickamer, H. G. (1983) The effect of high pressure upon proteins and other biomolecules. Q. Rev. Biophys., 16: 89-112.
14. Perutz, M. F., Kilmartin, J. V., Nagai, K., Szabo, A., Simon, S. R. (1976) Influence of globin structures on the state of the heme: ferrous low spin derivatives. Biochemistry, 15: 378-387.
15. Di Primo, C., Deprez, E., Hoa, G. H. B., Douzou, P. (1995) Antagonistic effects of hydrostatic pressure and osmotic pressure on cytochrome P-450cam spin transition. Biophys. J., 68: 2056-2061.
16. Gütlich, P., Ksenofontov, V., Gaspar, A. B. (2005) Pressure effect studies on spin crossover systems. Coord. Chem. Rev., 249: 1811-1829.
17. Létard, J.-F., Guionneau, P., Goux-Capes, L. (2004) Towards spin crossover applications, in: Gütlich, P., Goodwin, H. A. (Eds.) Spin crossover in transition metal compounds III. Top. Curr. Chem., 235: 221-249.
18. Ksenofontov, V., Gaspar, A. B., Gütlich, P. (2004) Pressure effect studies on spin crossover and valence tautomeric systems, in: Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds III. Top. Curr. Chem., 235: 23-64.
19. Gütlich, P., Gaspar, A. B., Ksenofontov, V., Garcia, Y. (2004) Pressure effect studies in molecular magnetism. J. Phys. Condens. Matter, 16: S1087-S1108.
20. Spiering, H. (2004) Elastic interaction in spin-crossover compounds, in: Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds III. Top. Curr. Chem., 235: 171-195.
21. 2. Phys. Rev. B, 74: 064424/1-064424/8.
22. Bousseksou, A., Molnár, G., Salmon, L., Nicolazzi, W. (2011) Molecular spin crossover phenomenon: recent achievements and prospects. Chem. Soc. Rev., 40: 3313-3335.
23. Stoleriu, L., Chakraborty, P., Hauser, A., Stancu, A., Enachescu, C. (2011) Thermal hysteresis in spin-crossover compounds studied within the mechanoelastic model and its potential application to nanoparticles. Phys. Rev. B, 84: 134102/1-134102/9.
24. 2] spin crossover complex. J. Phys. Chem. Solids, 69: 2681-2686.
25. Bargeron, C. B., Drickamer, H. G. (1971) Effect of pressure on the electronic structure of complexes of ferrous iron with substituted phenanthrolines. J. Chem. Phys., 7: 3471-3482.
26. 2 (x = 0.1, 1; ptz = 1-propyltetrazole). J. Phys. Chem. Solids, 57: 1743-1750.
27. Jeftic, J., Menéndez, N., Wack, A., Codjovi, E., Linarés, J., Goujon, A., Hamel, G., Klotz, S., Syfosse, G., Varret, F. (1999) Helium gas pressure apparatus with optical reflectivity detection. Meas. Sci. Technol., 10: 1059-1064.
28. 2 complexes with L = L' and L ≠ L': a XANES investigation. Inorg. Chem., 35: 574-580.
29. Hannay, C., Hubin-Franskin, M. J., Grandjean, F., Briois, V., Itié, J. P., Polian, A., Trofimenko, S., Long, G. J. (1997) X-ray absorption spectroscopic study of the temperature and pressure dependence of the electronic spin states in several iron(II) and cobalt(II) tris(pyrazolyl)borate complexes. Inorg. Chem., 36: 5580-5588.
30. 2 compounds with substituted 2⇋-pyridylmethylene 4-anilino ligands. Chem. Phys. Lett., 294: 545-553.
31. 2. Inorg. Chem., 32: 5305-5312.
32. 2O (M= Ni, Pd, Pt). First observation of a piezo-hysteresis loop at room temperature. J. Phys. Chem. B, 107: 3149-3155.
33. II complexes under pressure. J. Appl. Cryst., 41: 637-640.
34. Antonangeli, D., Siebert, J., Aracne, C. M., Farber, D. L., Bosak, A., Hoesch, M., Krisch, M., Ryerson, F. J., Fiquet, G., Badro, J. (2011) Spin crossover in ferropericlase at high pressure: a seismologically transparent transition? Science, 331: 64-67.
35. König, E., Ritter, G.,Waigel, J., Goodwin, H. A. (1985) The effect of pressure on the thermal hysteresis of the firstorder spin transition in bis(1,10-phenanthroline-2-carbaldehyde phenylhydrazone) iron (II) complexes. J. Chem. Phys., 83: 3055-3061.
36. 2O, pure and diluted in Ni matrix. C. R. Chimie, 4: 181-188.
37. 2O (n ≤ 2/3, M = Ag(I), Au(I)). Chem. Phys. Lett., 434: 68-72.
38. 2EtOH (pic = 2-picolylamine). J. Phys. Chem. Solids, 59: 265-275.
39. 2] (X = S, and Se): synthesis, structure and magnetic properties. Monatsh. Chem., 134: 285-294.
40. 2] (pmea = bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine). Inorg. Chem., 49: 745-751.
41. Shepherd, H. J., Bonnet, S., Guionneau, P., Bedoui, S., Garbarino, G., Nicolazzi, W., Bousseksou, A., Molnár, G. (2011) Pressure-induced two-step spin transition with structural symmetry breaking: X-ray diffraction, magnetic, and Raman studies. Phys. Rev. B, 84: 144107/1-144107/9.
42. Long, G. J., Hutchinson, B. B. (1987) Spin equilibrium in iron(II) poly(1-pyrazolyl)borate complexes: lowtemperature and high-pressure Mössbauer spectral studies. Inorg. Chem., 26: 608-613.
43. 2]. Bull. Chem. Soc. Jpn., 64: 339-345.
44. Boillot, M.-L., Zarembovitch, J., Itié, J.-P., Polian, A., Bourdet, E., Haasnoot, J. G. (2002) Pressure-induced spinstate crossovers at room temperature in iron(II) complexes: comparative analysis; a XANES investigation of some new transitions. New J. Chem., 26: 313-322.
45. 2O (btr = 4,4⇋-bis-1,2,4-triazole). J. Phys. Chem. B, 104: 5045-5048.
46. 4]. Chem. Phys. Lett., 423: 152-156.
47. 2]. Chem. Mater., 21: 1123-1136.
48. Weir, C. E., Lippincott, E. R., Van Valkenburg, A., Bunting, E. N. (1959) Infrared studies in the 1-micron to 15-micron region to 30000 atmosphere. J. Res. Natl. Bur. Stand. Sect. A, 63: 55-62.
49. Merrill, L., Basset, W. A. (1974) Miniature diamond anvil pressure cell for single crystal X-ray diffraction studies. Rev. Sci. Instrum., 45: 290-294.
50. Ahsbahs, H. (1984) Diamond-anvil high pressure cell for improved single-crystal X-ray diffraction measurements. Rev. Sci. Instrum., 55: 99-102.
51. Katrusiak, A. (2008) High-pressure crystallography. Acta Cryst. Sect. A, 64: 135-148.
52. Basset, W. A. (2009) Diamond anvil cell, 50th birthday. High Press. Res., 29: 163-186.
53. Tilton, R. F. (1988) A fixture for X-ray crystallographic studies of biomolecules under high gas pressure. J. Appl. Cryst., 21: 4-10.
54. Yufit, D. S., Howard, J. A. K. (2005) Simple pressure cell for single-crystal X-ray crystallography. J. Appl. Cryst., 38: 583-586.
55. Dawson, A., Allan, D. R., Parsons, S., Rulf, M. (2004) Use of a CCD diffractometer in crystal structure determinations at high pressure. J. Appl. Cryst., 37: 410-416.
56. Boldyreva, E. V. (2008) High-pressure diffraction studies of molecular organic solids. A personal view. Acta Cryst. Sect. A, 64: 218-231.
57. Guionneau, P., Brigouleix, C., Barrans, Y., Goeta, A. E., Létard, J.-F., Howard, J. A. K., Gaultier, J., Chasseau, D. (2001) High pressure and very low temperature effects on the crystal structures of some iron(II) complexes. C. R. Chimie, 4: 161-171.
58. 2]·py. Angew. Chem. Int. Ed., 51: 3910-3914.
59. 3tren] probed by high-pressure and low-temperature X-ray diffraction. Phys. Rev. B, 72: 214408/1-214408/8.
60. Shepherd, H. J., Rosa, P., Vendier, L., Casati, N., Létard, J.-F., Bousseksou, A., Guionneau, P., Molnár, G. (2012) High-pressure spin-crossover in a dinuclear Fe(II) complex. Phys. Chem. Chem. Phys., 14: 5265-5271.
61. König, E. (1987) Structural changes accompanying continuous and discontinuous spin-state transitions Prog. Inorg. Chem., 35: 527-622.
62. 2] complexes in: Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds II. Top. Curr. Chem. 234: 97-128.
63. Halcrow, M. A. (2011) Structure: function relationships in molecular spin-crossover complexes. Chem. Soc. Rev., 40: 4119-4142.
64. Marchivie, M., Guionneau, P., Howard, J. A. K., Chastanet, G., Létard, J.-F., Goeta, A. E., Chasseau, D. (2002) Structural characterization of a photoinduced molecular switch. J. Am. Chem. Soc., 124: 194-195.
65. Kaiba, A., Shepherd, H. J., Fedaouik, D., Rosa, P., Goeta, A. E., Rebbani, N., Létard, J.-F., Guionneau, P. (2010) Crystallographic elucidation of purely structural, thermal and light-induced spin transitions in an iron(ii) binuclear complex. Dalton Trans., 39: 2910-2918.
66. Fedaoui, D., Bouhadja, Y., Kaiba, A., Guionneau, P., Létard, J.-F., Rosa, P. (2008) Complexation of 2,6-bis(3- pyrazolyl)pyridine-bis(thiocyanato)iron(II) with a bridging 4,4_-bipyridine: a new example of a dinuclear spin crossover complex. Eur. J. Inorg. Chem., 1022-1026.
67. 2]py. Z. Kristallogr., 226: 576-584.
68. 2] polymorph I using reflectance detection. J. Appl. Phys., 106: 053515/1-053515/5.
69. 2. Physica B, 404: 379-381.
70. 2. J. Magn. Magn. Mater., 310: 1792-1793.
71. 2 spin-crossover compounds. Acta Cryst. Sect. B, 68: 40-56.
72. 3) under high pressure toward ligand-driven light-induced spin change. Polyhedron, 30: 3127-3130.
73. Paszkowicz, W. (2002) High-pressure powder X-ray diffraction at the turn of the century. Nucl. Instr. Methods in Phys. Res. Sect. B, 198: 142-182.
74. 3]2. Solid State Sci., 3: 705-714.
75. Gaudon, M., Deniard, P., Demourgues, A., Thiry, A.-E., Carbonera, C., LeNestour, A., Largeteau, A., Létard, J.-F., Jobic, S. (2007) Unprecedented "one-finger-push"-induced phase transition with a drastic color change in an inorganic material. Adv. Mater., 19: 3517-3519.
76. Fabbiani, F. P. A., Pulham, C. R. (2006) High-pressure studies of pharmaceutical compounds and energetic materials. Chem. Soc. Rev., 35: 932-942.
77. Oswald, I. D. H., Allan, D. R., Motherwell, W. D. S., Parsons, S. (2005) Structures of the monofluoro- and monochlorophenols at low temperature and high pressure. Acta Cryst. Sect. B, 61: 69-79.
78. Coppens, P., Vorontsov, I. I., Graber, T., Gembicky, M., Kovalevsky, A. Y. (2005) The structure of shortlived excited states of molecular complexes by time-resolved X-ray diffraction. Acta Cryst. Sect. A, 61: 162-172.
79. Collet, E., Buron-Le Cointe, M., Cailleau, H. (2006) X-ray diffraction investigation of the nature and the mechanism of photoinduced phase transition in molecular materials. J. Phys. Soc. Jpn., 75: 011002/1-011002/9.
80. Woike, T., Schaniel, D. (2008) Photocrystallography. Z. Kristallogr., 223: 235-369.
81. Buron, M., Collet, E. (2005) Second international conference on photoinduced phase transition; cooperative, nonlinear and functional properties. J. Phys.: Conf. Ser., 21: doi:10.1088/1742-6596/21/1/E01.
82. Bréfuel, N., Watanabe, H., Toupet, L., Come, J., Matsumoto, N., Collet, E., Tanaka, K., Tuchagues, J.-P. (2009) Concerted spin crossover and symmetry breaking yield three thermally and one light-induced crystallographic phases of a molecular material. Angew. Chem. Int. Ed., 48: 9304-9307.
83. Bréfuel, N., Collet, E., Watanabe, H., Kojima, M., Tsumoto, N., Toupet, L., Tanaka, K., Tuchagues, J.-P. (2010) Nanoscale self-hosting of molecular spin-states in the intermediate phase of a spin-crossover material. Chem. Eur. J., 16: 14060-14068.
84. Huby, N., Guérin, L., Collet, E., Ameline, J.-C., Cailleau, H., Roisnel, T., Tayagaki, T., Tanaka, K. (2004) Photoinduced spin transition probed by X-ray diffraction. Phys. Rev. B, 69: 020101/1-020101/4.
85. 2 showing continuous photoinduced transformation. Phys. Rev. B, 73: 104413/1-104413/5.
86. 2O. Phys. Rev. B, 74: 140101/1-140101/4.
87. 2]. Phys. Rev. B, 73: 060408/1-060408/4.
88. Nicolazzi,W., Pillet, S. (2012) Structural aspects of the relaxation process in spin crossover solids: Phase separation, mapping of lattice strain, and domain wall structure. Phys. Rev. B, 85: 094101/1-094101/13.
89. Collet, E. (Ed.) (2010) Dynamical structural science. Acta Cryst. Sect. A, 66: 133-280.
90. Collet, E., Lorenc, M., Cammarata, M., Guérin, L., Servol, M., Tissot, A., Boillot, M.-L., Cailleau, H., Buron-Le Cointe, M. (2012) 100 Picosecond diffraction catches structural transients of laser-pulse triggered switching in a spin-crossover crystal. Chem. Eur. J., 18: 2051-2055.
91. Lorenc, M., Hébert, J., Moisan, N., Trzop, E., Servol, M., Buron-Le Cointe, M., Cailleau, H., Boillot, M.-L., Pontecorvo, E., Wulff, M., Koshihara, S., Collet, E. (2009) Successive dynamical steps of photoinduced switching of a molecular Fe(III) spin-crossover material by time-resolved X-ray diffraction. Phys. Rev. Lett., 103: 028301/1-028301/4.
92. Collet, E., Moisan, N., Baldé, C., Bertoni, R., Trzop, E., Laulhé, C., Lorenc, M., Servol, M., Cailleau, H., Tissot, A., Boillot, M.-L., Graber, T., Henning, R., Coppens, P., Buron-Le Cointe, M. (2012) Ultrafast spin-state photoswitching in a crystal and slower consecutive processes investigated by femtosecond optical spectroscopy and picosecond X-ray diffraction. Phys. Chem. Chem. Phys., 14: 6192-6199.
93. Gütlich, P., Goodwin, H. A. (Eds) (2004) Spin Crossover in Transition Metal Compounds I-III. Top. Curr. Chem., vols. 233-235. Springer, Berlin/Heidelberg, Germany.
94. Buron-Le Cointe, M., Hébert, J., Baldé, C., Moisan, N., Toupet, L., Guionneau, P., Létard, J.-F., Freysz, E., Cailleau, H., Collet, E. (2012) Intermolecular control of thermoswitching and photoswitching phenomena in two spin-crossover polymorphs. Phys. Rev. B, 85: 064114/1-064114/9.
95. 2O. J. Am. Chem. Soc., 128: 13921-13931.
96. 2]2(bpym)}: toward controlled multi-stepped molecular switches. J. Appl. Cryst., 40: 158-164.
97. 2]2}. Dalton Trans., 642-649.
98. 2] complex. Phys. Rev. B,78: 134112/1-134112/9.
99. Pillet, S., Legrand, V., Weber, H.-P., Souhassou, M., Létard, J.-F., Guionneau, P., Lecomte, C. (2008) Out-ofequilibrium charge density distribution of spin crossover complexes from steady-state photocrystallographic measurements: experimental methodology and results. Z. Kristallogr., 223: 235-249.
100. Dupouy, G., Marchivie, M., Triki, S., Sala-Pala, J., Gómez-García, C. J., Pillet, S., Lecomte, C., Létard, J.-F. (2009) Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand. Chem. Commun., 3404-3406.
101. 2-sal-N(1,4,7,10))]: 292, 153, and 103 K X-ray crystal and molecular structure, infrared, magnetic, Mössbauer, calorimetric, and theoretical studies. Inorg. Chem., 33: 271-281.
102. Bonnet, S., Siegler, M. A., Costa, J. S, Molnár, G., Bousseksou, A., Spek, A. L., Gamez, P., Reedijk, J. (2008) A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase Chem. Commun., 5619-5621.
103. 2·EtOH. Angew. Chem. Int. Ed., 42: 3825-3830.
104. Neville, S. M., Leita, B. A., Halder, G. J., Kepert, C. J., Moubaraki, B., Létard, J.-F., Murray, K. S. (2008) Understanding the two-step spin-transition phenomenon in iron(II) 1D chain materials. Chem. Eur. J., 14: 10123-10133.
105. 3LMe = tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine). Inorg. Chem., 42: 8406-8416.
106. 3LMe = Tris[2-{[(2-methylimidazol-4-yl)methylidene] amino}ethyl]amine). Chem. Eur. J., 12: 4536-4549.
107. Nicolazzi, W., Pillet, S., Lecomte, C. (2009) Photoinduced phase separation in spin-crossover materials: numerical simulation of a dynamic photocrystallographic experiment. Phys. Rev. B, 80: 132102/1-132102/4.
108. 2 single crystals explained by optical microscopy in terms of inhomogeneous stresses. Chem. Phys. Lett., 504: 29-33.
109. 2O single crystals, observed by optical microscopy. New J. Chem., 35: 2333-2340.
110. 4)). J. Am. Chem. Soc., 130: 9019-9024.
111. 3] compounds inside and outside their thermal hysteresis loops. Chem. Phys. Lett. 500: 18-22.
112. Collet, E., Lemée-Cailleau, M. H., Buron-Le Cointe, M., Cailleau, H., Wulff, M., Luty, T., Koshihara, S.-Y., Meyer, M., Toupet, L., Rabiller, P., Techert, S. (2003) Laser-induced ferroelectric structural order in an organic charge-transfer crystal. Science, 300: 612-615.
113. Nozawa, S., Adachi, S., Takahashi, J., Tazaki, R., Guérin, L., Daimon, M., Tomita, A., Sato, T., Chollet, M., Collet, E., Cailleau, H., Yamamoto, S., Tsuchiya, K., Shioya, T., Sasaki, H., Mori, T., Ichiyanagi, K., Sawa, H., Kawata, H., Koshihara, S. (2007) Developing 100 ps-resolved X-ray structural analysis capabilities on beamline NW14A at the Photon Factory Advanced Ring. J. Synchrotron Rad., 14: 313-319.
114. Bressler, C., Milne, C., Pham, V. T., El Nahhas, A., van der Veen, R. M., Gawelda, W., Johnson, S., Beaud, P., Grolimund, D., Kaiser, M., Borca, C. N., Ingold, G., Abela, R., Chergui, M. (2009) Femtosecond XANES study of the light-induced spin crossover dynamics in an iron(II) complex. Science, 323: 489-492.
115. Chergui, M. (2010) Picosecond and femtosecond X-ray absorption spectroscopy of molecular systems. Acta Cryst. Sect. A, 66: 229-239.
116. Cailleau, H., Lorenc, M., Guérin, L., Servol, M., Collet, E., Buron-Le Cointe, M. (2010) Structural dynamics of photoinduced molecular switching in the solid state. Acta Cryst. Sect. A, 66: 189-197.