Photocatalytic Reactions on Model Single Crystal TiO2 Surfaces

On Solar Hydrogen & Nanotechnology

Volumn , Issue , 2010, Pages 77-89

  Waterhouse, G I N ^a   Idriss, H ^b,c  

^a UNIVERSITY OF AUCKLAND   (New Zealand)

^b UNIVERSITY OF ABERDEEN   (United Kingdom)

^c ROBERT GORDON UNIVERSITY   (United Kingdom)

Author keywords

Ethanol; Gold TiO2; Hydrogen; Photo oxidation; photo reduction; Structure sensitivity; photo reaction cross section; TiO2 single crystal

Indexed keywords

EID: 84886065402     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9780470823996.ch3     Document Type: Chapter

References (41)

1. Fujishima, A. and Honda, K. (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature, 238, 37.
2. Kudo, A. and Miseki, Y. (2009) Heterogeneous photocatalyst materials for water splitting. Chemical Society Reviews, 38, 253.
3. Idriss, H. and Barteau, M.A. (2000) Active sites on oxides: from single crystals to catalysts. Advances in Catalysis, 45, 261.
4. Diebold, U. (2003) The surface science of titanium dioxide. Surface Science Reports, 48, 53.
5. Qiu, H., Idriss, H., Wang, Y., and Wöll, C. (2008) Carbon-carbon bond formation on model titanium oxide surfaces: identification of surface reaction intermediates by high-resolution electron energy loss spectroscopy. Journal of Physical Chemistry C, 112, 9828.
6. Jayaweera, P.M., Quah, E.L., and Idriss, H. (2007) Photoreaction of ethanol on TiO2(110) single-crystal surface. Journal of Physical Chemistry C, 111, 1764.
7. Henderson, M.A., White, J.M., Uetsukab, H., and Onishi, H. (2006) Selectivity changes during organic photooxidation on TiO2: Role of O2 pressure and organic coverage. Journal of Catalysis, 238, 153.
8. Lyubinetsky, I., Yu, Z.Q., and Henderson, M.A. (2007) Direct observation of adsorption evolution and bonding configuration of TMAA on TiO2(110). Journal of Physical Chemistry C, 111, 4342.
9. White, J.M., Szanyi, J., and Henderson, M.A. (2004) Thermal chemistry of trimethyl acetic acid on TiO2(110). Journal of Physical Chemistry B, 108, 3592.
10. Henderson, M.A. (2005) Photooxidation of acetone on TiO2(110): conversion to acetate via methyl radical ejection. Journal of Physical Chemistry B, 109, 12062.
11. Wilson, J.N. and Senanayake, S.D. (2004) Carbon coupling on titanium oxide at surface oxygen defects, H. Idriss. Surface Science, L231, 562.
12. Ni, M., Leung, M.K.H., Leung, D.Y.C., and Sumathy, K. (2007) A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production. Renewable and Sustainable Energy Reviews, 11, 401.
13. Ruzycki, N., Herman, G.S., Boatner, L.A., and Diebold, U. (2003) Scanning tunneling microscopy study of the anatase (1 0 0) surface. Surface Science, 529, L239.
14. Tanner, R.E., Sasahara, A., Liang, Y., Altman, E.I., and Onishi, H. (2002) Formic acid adsorption on anatase TiO2(001)-(1 x 4) thin films studied by NC-AFM and STM. Journal of Physical Chemistry B, 106, 8211.
15. Lazzeri, M. and Selloni, A. (2001) Stress-driven reconstruction of an oxide surface: the anatase TiO2(001)-(1 x 4) surface. Physical Review Letters, 87, 266105.
16. Bonapasta, A.A. and Filippone, F. (2005) Photocatalytic reduction of oxygen molecules at the (100) TiO2 anatase surface. Surface Science, 577, 59.
17. Czekaj, I., Piazzesi, G., Kröcher, O., and Wokaun, A. (2006) DFT modeling of the hydrolysis of isocyanic acid over the TiO2 anatase (101) surface: Adsorption of HNCO species. Surface Science, 600, 5158.
18. Ramamoorthy,M. and Vanderbilt, A. (1994) First principles calculations of the energetic of stoichiometric TiO2 surfaces. Physical Review B-Condensed Matter, 49, 16721.
19. McGill, P.R. and Idriss, H. (2008) Plane wave density functional theory computation of the molecular adsorption of ammonia on the (011) surface of titanium dioxide. Langmuir, 24, 97.
20. Gong, X.-Q., Khorshidi, N., Stierle, A.,Vonk,V., Ellinger, C., Dosch, H., Cheng, H., Selloni, A., He,Y., Dulub, O., and Diebold, U. (2009) The 2 x 1 reconstruction of the rutile TiO2(011) surface: A combined density functional theory, X-ray diffraction, and scanning tunneling microscopy study. Surface Science, 603, 138.
21. Firment, L.E. (1982) Thermal faceting of the rutile TiO2(001) surface. Surface Science, 116, 205.
22. Kim, K.S. and Barteau, M.A. (1990) Structure and composition requirements for deoxygenation, dehydration, and ketonization reactions of carboxylic acids on TiO2(001) single-crystal surfaces. Journal of Catalysis, 125, 353.
23. Idriss, H., Kim, K.S., and Barteau, M.A. (1991) Structure-activity and structure-selectivity relations for reactions of carboxylic acids on TiO2(001) surfaces. Studies in Surface Science and Catalysis, 64, 327.
24. Senanayake, S.D. and Idriss, H. (2006) Photo-catalyses and the origin of life. The synthesis of nucleotides from formamide onTiO2(001) single surfaces. Proceedings of the National Academy of Sciences of the United States of America, 103, 1194.
25. Ariga, H., Taniike, T., Morikawa, H., Tero, R., Kondoh, H., and Iwasawa, Y. (2008) Lattice-work structure of a TiO2(001) surface studied by STM, core-level spectroscopies and DFT calculations. Chemical Physics Letters, 454, 350.
26. Valentin, C., Tilocca, A., Selloni, A., Beck, T.J., Klust, A., Batzill, M., Losovyj, Y., and Diebold, U. (2005) Adsorption of water on reconstructed rutile TiO2(011)-(2 x 1): TiO double bonds and surface reactivity. Journal of the American Chemical Society, 127, 9895.
27. Torrelles, X., Cabailh, G., Lindsay, R., Bikondoa, O., Roy, J., Zegenhagen, J., Teobaldi, G., Hofer, W.A., and Thornton, G. (2009) Geometric structure of TiO2(011) (2 x 1). Physical Review Letters, 101, 185501.
28. Fujishima, A., Zhang, X., and Tryk, D.A. (2008) TiO2 photocatalysis and related surface phenomena. Surface Science Reports, 63, 515 and reference therein.
29. Al-Mazroai, L.S., Bowker, M., Davies, P., Dickinson, A., Greaves, J., James, D., and Millard, L.M. (2007) The photocatalytic reforming of methanol. Catalysis Today, 122, 46.
30. Yang, Y.Z., Chang, C.H., and Idriss, H. (2006) Photo-catalytic production of hydrogen from ethanol over M/TiO2 catalysts (M = Pd, Pt or Rh). Applied Catalysis B-Environmental, 67, 217.
31. Zhang, Z., Bondarchuk, O., Kay, B.D., White, J.M., and Dohnálek, Z. (2007) Direct visualization of 2-butanol adsorption and dissociation on TiO2(110). The Journal of Physical Chemistry C, 111, 3021.
32. Bates, S.P., Kresse, G.K., and Gillan, M.J. (1998) The adsorption and dissociation of ROH molecules on TiO2(110). Surface Science, 409, 336.
33. Reztova, T., Chang, C.-H., Koresh, J., and Idriss, H. (1999) Dark and photoreactions of ethanol and acetaldehyde over TiO2/carbon molecular sieve fiber. Journal of Catalysis, 185, 223.
34. Yu, Z. and Chuang, S.S.C. (2007) In situ IR study of adsorbed species and photogenerated electrons during photocatalytic oxidation of ethanol on TiO2. Journal of Catalysis, 246, 118.
35. Zehr, R.T. and Henderson, M.A. (2008) Acetaldehyde photochemistry on TiO2(110). Surface Science, 602, 2238.
36. Wilson, J.N. and Idriss, H. (2002) Structure-sensitivity and photo-catalytic reactions of semiconductors. Effect of the last layer atomic arrangement. Journal of the American Chemical Society, 124, 11284.
37. Wilson, J.N. and Idriss, H. (2003) Effect of surface reconstruction ofTiO2(001) single crystal on the photoreaction of acetic acid. Journal of Catalysis, 214, 46.
38. Goodman, D.W. and Lai, X. (2000) Structure-reactivity correlations for oxide-supported metal catalysts: new perspectives from STM. Journal of Molecular Catalysis A-Chemical, 162, 33.
39. Haruta, M. (1997) Size- and support-dependency in the catalysis of gold. Catalysis Today, 36, 153.
40. Kamat, P.V. (2008) Quantum dot solar cells. semiconductor nanocrystals as light harvesters. Journal of Physical Chemistry C, 112, 18737 and references therein.
41. Mller, B.R., Majoni, S., Memming, R., and Meissner, D. (1997) Particle size and surface chemistry in photoelectrochemical reactions at semiconductor particles. Journal of Physical Chemistry B, 101, 2501.