In situ photoemission observation of catalytic CO oxidation reaction on Pd(110) under near-ambient pressure conditions: Evidence for the Langmuir-Hinshelwood mechanism

Journal of Physical Chemistry C

Volumn 117, Issue 40, 2013, Pages 20617-20624

  Toyoshima, Ryo ^a   Yoshida, Masaaki ^a   Monya, Yuji ^a   Suzuki, Kazuma ^a   Amemiya, Kenta ^b   Mase, Kazuhiko ^b   Mun, Bongjin Simon ^c   Kondoh, Hiroshi ^a  

^a KEIO UNIVERSITY   (Japan)

^b INSTITUTE OF MATERIALS STRUCTURE SCIENCE   (Japan)

^c Gwangju Institute of Science and Technology (GIST)   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SURFACES; CHEMISORBED OXYGEN; CRITICAL TEMPERATURES; FORMATION RATES; LANGMUIR HINSHELWOOD MECHANISM; LOWER TEMPERATURES; MASS SPECTROSCOPY; PRESSURE CONDITIONS;

CHEMISORPTION; MASS SPECTROMETRY; PHOTOELECTRON SPECTROSCOPY;

CARBON DIOXIDE;

EID: 84885590312     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4054132     Document Type: Article

References (43)

1. Campbell, C. T.; Ertl, G.; Kuipers, H.; Segner, J. A Molecular Beam Study of the Catalytic Oxidation of CO on a Pt(111) Surface J. Chem. Phys. 1980, 73, 5862-5873
2. Witterlin, J.; Völkening, S.; Janssens, T. V. W.; Zambelli, T.; Ertl, G. Atomic and Macroscopic Reaction Rates of a Surface-Catalyzed Reaction Science 1997, 278, 1931-1934
3. Nagarajan, S.; Thirunavukkarasu, K.; Gopinath, C. S. A Revisit to Carbon Monoxide Oxidation on Pd(111) Surfaces J. Phys. Chem. C 2009, 113, 7385-7397
4. Nakai, I.; Kondoh, H.; Amemiya, K.; Nagasaka, M.; Shimada, T.; Yokota, R.; Nambu, A.; Ohta, T. Mechanism of the CO Oxidation Reaction on O-Precovered Pt(111) Surfaces Studied with Near-Edge X-ray Absorption Fine Structure Spectroscopy J. Chem. Phys. 2005, 122, 134709-134718
5. Nakai, I.; Kondoh, H.; Shimada, T.; Resta, A.; Andersen, J. N.; Ohta, T. Mechanism of CO Oxidation Reaction on O-Covered Pd(111) Surfaces Studied with Fast X-ray Photoelectron Spectroscopy: Change of Reaction Path Accompanying Phase Transition of O Domains J. Chem. Phys. 2006, 124, 224712-224719
6. Nagasaka, M.; Kondoh, H.; Nakai, I.; Ohta, T. CO Oxidation Reaction on Pt(111) Studied by the Dynamic Monte Carlo Method Including Lateral Interactions of Adsorbates J. Chem. Phys. 2007, 126, 044704-044710
7. Hendriksen, B. L. M.; Frenken, J. W. M. CO Oxidation on Pt(110): Scanning Tunneling Microscopy Inside a High-Pressure Flow Reactor Phys. Rev. Lett. 2002, 89, 046101-046104
8. Hendriksen, B. L. M.; Bobaru, S. C.; Frenken, J. W. M. Oscillatory CO Oxidation on Pd(100) Studied with in Situ Scanning Tunneling Microscopy Surf. Sci. 2004, 552, 229-242
9. Chen, M. S.; Cai, Y.; Gath, K. K.; Axnanda, S.; Goodman, D. W. Highly Active Surfaces for CO Oxidation on Rh, Pd, and Pt Surf. Sci. 2007, 601, 5326-5331
10. Gao, F.; McClure, S. M.; Cai, Y.; Gath, K. K.; Wang, Y.; Chen, M. S.; Guo, Q. M.; Goodman, D. W. CO Oxidation Trends on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures: A Combined In Situ PM-IRAS and Reaction Kinetics Study Surf. Sci. 2009, 603, 65-70
11. Gao, F.; Wang, Y.; Cai, Y.; Goodman, D. Y. CO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. 2. Palladium and Platinum J. Phys. Chem. C 2009, 113, 174-181
12. Chen, M.; Wang, X. V.; Zhang, L.; Tang, Z.; Wan, H. Active Surfaces for CO Oxidation on Palladium in the Hyperactive State Langmuir 2010, 26, 18113-18118
13. Gustafson, J.; Westerström, R.; Balmes, O.; Resta, A.; van Rijn, R.; Torrelles, X.; Herbschleb, C. T.; Frenken, J. W. M.; Lundgren, E. Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic Conditions J. Phys. Chem. C 2010, 114, 4580-4583
14. van Rijn, R.; Balmes, O.; Resta, A.; Wermeille, D.; Westerström, R.; Gustafson, J.; Felici, R.; Lundgren, E.; Frenken, J. W. M. Surface Structure and Reactivity of Pd(100) during CO Oxidation near Ambient Pressures Phys. Chem. Chem. Phys. 2011, 13, 13167-13171
15. Chung, J.-Y.; Aksoy, F.; Grass, M. E.; Kondoh, H.; Ross, P., Jr.; Liu, Z.; Mun, B. S. In-Situ Study of the Catalytic Oxidation of CO on a Pt(110) Surface Using Ambient Pressure X-ray Photoelectron Spectroscopy Surf. Sci. Lett. 2009, 603, L35-L38
16. Blume, R.; Hävecker, M.; Zafeiratos, S.; Teschner, D.; Kleimenov, E.; Knop-Gericke, A.; Schlögl, R.; Barinov, A.; Dudin, P.; Kiskinova, M. Catalytically Active States of Ru(0001) Catalyst in CO Oxidation Reaction J. Catal. 2005, 239, 354-361
17. Toyoshima, R.; Yoshida, M.; Monya, Y.; Kousa, Y.; Suzuki, K.; Abe, H.; Mun, B. S.; Amemiya, K.; Mase, K.; Kondoh, H. In Situ Ambient Pressure XPS Study of CO Oxidation Reaction on Pd(111) Surfaces J. Phys. Chem. C 2012, 116, 18691-18697
18. Toyoshima, R.; Yoshida, M.; Monya, Y.; Suzuki, K.; Mun, B. S.; Amemiya, K.; Mase, K.; Kondoh, H. Active Surface Oxygen for Catalytic CO Oxidation on Pd(100) Proceeding under Near Ambient Pressure Conditions J. Phys. Chem. Lett. 2012, 3, 3182-3187
19. Butcher, D. R.; Grass, M. E.; Zeng, Z.; Askoy, F.; Bluhm, H.; Li, W.-X.; Mun, B. S.; Somorjai, G. A.; Liu, Z. In Situ Oxidation Study of Pt(110) and Its Interaction with CO J. Am. Chem. Soc. 2011, 133, 20319-20325
20. Blomberg, S.; Hoffmann, M. J.; Gustafson, J.; Martin, N. M.; Fernandes, V. R.; Borg, A.; Liu, Z.; Chang, R.; Matera, S.; Reuter, K.; Lundgren, E. In Situ X-Ray Photoelectron Spectroscopy of Model Catalysts: At the Edge of the Gap Phys. Rev. Lett. 2013, 110, 117601-1117605
21. Lundgren, E.; Kresse, G.; Klein, C.; Borg, M.; Andersen, J. N.; De Stantis, M.; Gauthier, Y.; Konvicka, C.; Schmid, M.; Varga, P. Two-Dimensional Oxide on Pd(111) Phys. Rev. Lett. 2002, 88, 246103-246106
22. Ketteler, G.; Ogletree, D. F.; Bluhm, H.; Liu, H.; Hebenstreit, E. L. D.; Salmeron, M. In Situ Spectroscopic Study of the Oxidation and Reduction of Pd(111) J. Am. Chem. Soc. 2005, 127, 18269-18273
23. -1 mbar Range Surf. Sci. 2006, 600, 2980-2989
24. Todorova, M.; Lundgren, E.; Blum, V.; Mikkelsen, A.; Gray, S.; Gustafson, J.; Borg, M.; Rogal, J.; Reuter, K.; Andersen, J. N. The Pd(100)- (√5×√5)R27 -O Surface Oxide Revisited Surf. Sci. 2003, 541, 101-112
25. Kostelník, P.; Seriani, N.; Kresse, G.; Mikkelsen, A.; Lundgren, E.; Blum, V.; Sikola, T.; Varga, P.; Schmid, M. The Pd(100)-(√5 × √5)R27 -O Surface Oxide: A LEED, DFT and STM Study Surf. Sci. 2007, 601, 1574-1581
26. Westerström, R.; Messing, M. E.; Blomberg, S.; Hellman, A.; Grönbeck, H.; Gustafson, J.; Martin, N. M.; Balmes, O.; van Rijn, R.; Andersen, J. N. Oxidation and Reduction of Pd(100) and Aerosol-Deposited Pd Nanoparticles Phys. Rev. B 2011, 83, 115440-115449
27. Westerström, R.; Gustafson, J.; Resta, A.; Mikkelsen, A.; Andersen, J. N.; Lundgren, E.; Seriani, N.; Mittendorfer, F.; Schmid, M.; Klikovits, J. Oxidation of Pd(553): From Ultrahigh Vacuum to Atmospheric Pressure Phys. Rev. B 2007, 76, 155410-155418
28. Vlad, A.; Stierle, A.; Westerström, R.; Blomberg, S.; Mikkelsen, A.; Lundgren, E. Oxygen Interaction with the Pd(112) Surface: From Chemisorption to Bulk Oxide Formation Phys. Rev. B 2012, 86, 035407-035415
29. Dhanak, V. R.; Comelli, G.; Paolucci, G.; Prince, K. C.; Rosei, R. Metastable (1 × 2) and (1 × 3) reconstructions of Pd(110) Surf. Sci. Lett. 1992, 260, L24-L27
30. Tanaka, H.; Yoshinobu, J.; Kawai, M. Oxygen-Induced Reconstruction of the Pd(110) Surface: an STM Study Surf. Sci. Lett. 1995, 327, L505-L509
31. Bennett, R. A.; Poulston, S.; Jones, I. Z.; Bowker, M. High-Temperature Scanning Tunneling Microscopy Studies of Oxygen-Induced Reconstructions of Pd(110) Surf. Sci. 1998, 401, 72-81
32. Kralj, M.; Pertram, T.; Seriani, N.; Mittendorfer, F.; Krupski, A.; Becker, C.; Wandelt, K. Pd(110) Surface Oxide Structures Investigated by STM and DFT Surf. Sci. 2008, 602, 3706-3713
33. Westerström, R.; Weststrate, C. J.; Resta, A.; Mikkelsen, A.; Schnadt, J.; Andersen, J. N.; Lundgren, E.; Schmid, M.; Seriani, N.; Harl, J. Stressing Pd Atoms: Initial Oxidation of the Pd(110) Surface Surf. Sci. 2008, 602, 2440-2447
34. Westerström, R.; Weststrate, C. J.; Gustafson, J.; Mikkelsen, A.; Schnadt, J.; Andersen, J. N.; Lundgren, E.; Seriani, N.; Mittendorfer, F.; Kresse, G. Lack of Surface Oxide Layers and Facile Bulk Oxide Formation on Pd(110) Phys. Rev. B 2009, 80, 125431-125441
35. Surnev, S.; Sock, M.; Ramsey, M. G.; Netzer, F. P.; Wiklund, M.; Borg, M.; Andersen, J. N. CO Adsorption on Pd(111): A High-Resolution Core Level Photoemission and Electron Energy Loss Spectroscopy Study Surf. Sci. 2000, 470, 171-185
36. Kaichev, V. V.; Prosvirion, I. P.; Bukhtiyarov, V. I.; Unterhalt, H.; Rupprechter, G.; Freund, H.-J. High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation J. Phys. Chem. B 2003, 107, 3522-3527
37. Andersen, J. N.; Qvarford, M.; Nyholm, R.; Sorensen, S. L.; Wigren, C. Surface Core-Level Shifts as a Probe of the Local Overlayer Structure: CO on Pd(100) Phys. Rev. Lett. 1991, 67, 2822-2825
38. Toyoshima, R.; Yoshida, M.; Monya, Y.; Suzuki, K.; Amemiya, K.; Mase, K.; Mun, B. S.; Kondoh, H. Photoelectron Spectroscopic Study of CO and NO Adsorption on Pd(100) Surface under Ambient Pressure Conditions Surf. Sci. 2013, 615, 33-40
39. Raval, R.; Haq, S.; Harrison, M. A.; Blyholder, G.; King, D. A. Molecular Adsorbate-Induced Surface Reconstruction: CO/Pd(110) Chem. Phys. Lett. 1990, 167, 391-398
40. Lpcatelli, A.; Brena, B.; Lizzit, S.; Comelli, G.; Cautero, G.; Paolucci, G.; Rosei, R. Adsorption Site Determination by Means of Surface Core Level Shift High Energy Photoelectron Diffraction: Pd(110) (2 × 1)p2mg-CO Phys. Rev. Lett. 1994, 73, 90-93
41. Ramsey, M. G.; Leisenberger, F. P.; Netzer, F. P.; Roberts, A. J.; Raval, R. High-Resolution Core-Level Photoemission of the CO-Induced Pd(110) Surface Reconstruction Surf. Sci. 1997, 387, 207-215
42. Toyoshima, A.; Tanaka, H.; Kikuchi, T.; Amemiya, K.; Mase, K. Present Status of a New Vacuum Ultraviolet and Soft X-ray Undulator Beamline BL-13A for the Study of Organic Thin Films Adsorbed on Surfaces J. Vac. Soc. Jpn. 2011, 54, 580-584
43. Toyoshima, A.; Kikuchi, T.; Tanaka, H.; Mase, K.; Amemiya, K.; Ozawa, K. J. Phys.: Conf. Ser. 2013, 425, 152019(1)-152019(4)