Aerobic, transition-metal-free, direct, and regiospecific mono-α-arylation of ketones: Synthesis and mechanism by DFT calculations

Journal of the American Chemical Society

Volumn 135, Issue 38, 2013, Pages 14048-14051

  Xu, Qing Long ^a   Gao, Hongyin ^a   Yousufuddin, Muhammed ^b   Ess, Daniel H ^c   Kürti, László ^a  

^a UNIVERSITY OF TEXAS SOUTHWESTERN MEDICAL CENTER   (United States)

^b UNIVERSITY OF TEXAS AT ARLINGTON   (United States)

^c Brigham Young University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

C-C BOND FORMATION; CONVENTIONAL METHODS; DFT CALCULATION; DIARYLIODONIUM SALTS; REGIO-SELECTIVE; REGIOSPECIFIC; SILYL ENOL ETHERS; SUBSTITUTION PATTERNS;

AROMATIC COMPOUNDS; DENSITY FUNCTIONAL THEORY; KETONES; TRANSITION METALS;

REGIOSELECTIVITY;

AROMATIC NITRO COMPOUND; CARBON; HYDROGEN; KETONE;

ARTICLE; ARYLATION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; HALOGENATION; HYDROGEN BOND; MONO ALPHA ARYLATION; OXIDATION; SYNTHESIS;

EID: 84884849151     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4074563     Document Type: Article

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