Straightforward and highly efficient synthesis of α-acetoxy ketones through gold-catalyzed intermolecular oxidation of terminal alkynes

Synthesis (Germany)

Volumn 45, Issue 18, 2013, Pages 2605-2611

  Wu, Chao ^a   Liang, Zhiwu ^a   Yan, Dong ^b   He, Weimin ^a   Xiang, Jiannan ^a  

^a HUNAN UNIVERSITY   (China)

^b Hunan Chemical Industry Vocation Technology Institute   (China)

Author keywords

alkynes; carbene complexes; esters; gold; homogeneous catalysis; ketones; oxidations

Indexed keywords

ALKYNES; CARBENE COMPLEXES; CARBENES; EFFICIENT SYNTHESIS; HOMOGENEOUS CATALYSIS; O-H INSERTION; TERMINAL ALKYNE;

CATALYSIS; ESTERS; GOLD; HYDROCARBONS; KETONES; OXIDATION; REACTION KINETICS;

GOLD COMPOUNDS;

2 (2 BROMOPHENYL) 2 OXOETHYL ACETIC ACID; 2 (2 NAPHTHYL) 2 OXOETHYL ACETIC ACID; 2 (4 BROMOPHENYL) 2 OXOETHYL ACETIC ACID; 2 (4 FLUOROPHENYL) 2 OXOETHYL ACETIC ACID; 2 (4 METHOXYPHENYL) 2 OXOETHYL ACETIC ACID; 2 CYCLOHEX 1 EN 1 YL 2 OXOETHYL ACETIC ACID; 2 CYCLOPROPYL 2 OXOETHYL ACETIC ACID; 2 OXO 2 (2 TOLYL)ETHYL ACETIC ACID; 2 OXO 2 (3,4,5 TRIMETHOXYPHENYL)ETHYL ACETIC ACID; 2 OXO 2 (4 TOLYL)ETHYL ACETIC ACID; 2 OXO 2 [3 (TRIFLUOROMETHYL)PHENYL]ETHYL ACETIC ACID; 2 OXO 2 PHENYLETHYL ACETIC ACID; 2 OXO 4 PHENYLBUTYL ACETIC ACID; 2 OXO 6 (TOSYLOXY)HEXYL ACETIC ACID; 2 OXODODECYL ACETIC ACID; 2 OXOHEXANE 1,6 DIYL DIACETIC ACID; 3,3 DIMETHYL 2 OXOBUTYL ACETIC ACID; 5 [[TERT BUTYL(DIMETHYL)SILYL]OXY] 2 OXOPENTYL ACETIC ACID; 6 (BENZYLOXY) 2 OXOHEXYL ACETIC ACID; 6 (MESYLOXY) 2 OXOHEXYL ACETIC ACID; 6 CHLORO 2 OXOHEXYL ACETIC ACID; 6 METHOXY 2 OXOHEXYL ACETIC ACID; 8 METHYLQUINOLINE 1 OXIDE; ALKYNE; ALPHA ACETOXY KETONE; CARBENE; GOLD; KETONE; OXIDIZING AGENT; UNCLASSIFIED DRUG; UNINDEXED DRUG;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; MOLECULAR INTERACTION; OXIDATION; SYNTHESIS;

EID: 84883823483     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0033-1338513     Document Type: Article

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