Inverse kinetic isotope effect in the excited-state relaxation of a Ru(II)-aquo complex: Revealing the impact of hydrogen-bond dynamics on nonradiative decay

Journal of the American Chemical Society

Volumn 135, Issue 34, 2013, Pages 12500-12503

  Hewitt, Joshua T ^a   Concepcion, Javier J ^b   Damrauer, Niels H ^a  

^a UNIVERSITY OF COLORADO   (United States)

^b The University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EXCITED-STATE LIFETIME; INVERSE KINETIC ISOTOPE EFFECTS; ISOTOPE EFFECT; NONRADIATIVE DECAYS; PHOTOPHYSICS; PUMP-PROBE SPECTROSCOPY; ROOM TEMPERATURE; TERPYRIDINES;

CARRIER MOBILITY; ISOTOPES;

EXCITED STATES;

DEUTERIUM OXIDE; ISOTOPE; PYRIDINE DERIVATIVE; RUTHENIUM COMPLEX; WATER;

ABSORPTION SPECTROSCOPY; ARTICLE; CATALYST; COMPLEX FORMATION; ELECTROCHEMISTRY; ENERGY; HYDROGEN BOND; ISOTOPE ANALYSIS; KINETICS; METAL TO LIGAND CHARGE TRANSFER; MOLECULAR DYNAMICS; MOLECULE; PHOTOCHEMISTRY; ROOM TEMPERATURE;

EID: 84883295066     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4037498     Document Type: Article

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