Sink or surf: Atmospheric implications for succinic acid at aqueous surfaces

Journal of Physical Chemistry A

Volumn 117, Issue 33, 2013, Pages 7887-7903

  Blower, Patrick G ^a   Ota, Stephanie T ^a   Valley, Nicholas A ^a   Wood, Suzannah R ^a   Richmond, Geraldine L ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION COMPOSITION; ATMOSPHERIC CONDITIONS; ATMOSPHERIC IMPLICATIONS; COMPUTATIONAL TECHNIQUE; SPECTROSCOPIC MEASUREMENTS; SURFACE CHARACTERISTICS; THEORETICAL SIMULATION; VIBRATIONAL SUM-FREQUENCY SPECTROSCOPIES;

PHYSICAL CHEMISTRY; PHYSICS;

SULFUR DIOXIDE;

EID: 84883195929     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp405067y     Document Type: Article

References (105)

1. Cruz, C. N.; Pandis, S. N. A Study of the Ability of Pure Secondary Organic Aerosol to Act as Cloud Condensation Nuclei Atmos. Environ. 1997, 31, 2205-2214
2. Finlayson-Pitts, B. J.; Pitts, J. N. Chemistry of the Lower and Upper Atmosphere; Academic Press: San Diego, CA, 2000.
3. Finlayson-Pitts, B. J. Reactions at Surfaces in the Atmosphere: Integration of Experiments and Theory as Necessary (But Not Necessarily Sufficient) for Predicting the Physical Chemistry of Aerosols Phys. Chem. Chem. Phys. 2009, 11, 7760-7779
4. Donaldson, D. J.; Valsaraj, K. T. Adsorption and Reaction of Trace Gas-Phase Organic Compounds on Atmoshperic Water Film Surfaces: A Critical Review Environ. Sci. Technol. 2010, 44, 865-873
5. Hayase, S.; Yabushita, A.; Kawasaki, M.; Enami, S.; Hoffman, M. R.; Colussi, A. J. Weak Acids Enhance Halogen Activation on Atmospheric Water's Surfaces J. Phys. Chem. A 2011, 115, 4935-4940
6. Martins-Costa, M. T. C.; Anglada, J. M.; Francisco, J. S.; Ruiz-Lopez, M. F. Reactivity of Atmospherically Relevant Small Radicals at the Air-Water Interface Angew. Chem., Int. Ed. 2012, 51, 5413-5417
7. Monge, M. E.; Rosenorn, T.; Favez, O.; Muller, M.; Adler, G.; Riziq, A. A.; Rudich, Y.; Hermann, H.; George, C.; D'Anna, B. Alternative Pathway for Atmospheric Particles Growth Proc. Natl. Acad. Sci. 2012, 109, 6840-6844
8. Jacobson, M. C.; Hansson, H.-C.; Noone, K. J.; Charlson, R. J. Organic Atmospheric Aerosols: Review and State of the Science Rev. Geophys. 2000, 38, 267-294
9. Ming, Y.; Russell, L. M. Organic Aerosol Effects on Fog Droplet Spectra J. Geophys. Res. 2004, 109, D10206/10201-D10206/10214
10. Stephanou, E. G. The Decay of Organic Aerosols Nature 2005, 434, 31
11. Maria, S. F.; Russell, L. M.; Gilles, M. K.; Myneni, S. C. B. Organic Aerosol Growth Mechanisms and Their Climate-Forcing Implications Science 2004, 306, 1921-1924
12. Goss, K.-U. Predicting Adsorption of Organic Chemicals at the Air-Water Interface J. Phys. Chem. A 2009, 113, 12256-12259
13. Ellison, G. B.; Tuck, A. F.; Vaida, V. Atmospheric Processing of Organic Aerosols J. Geophys. Res. 1999, 104, 11633-11641
14. 3 + Water Solutions Geophys. Res. Lett. 2005, 32, L16806
15. Eliason, T. L.; Gilman, J. B.; Vaida, V. Oxidation of Organic Films Relevant to Atmospheric Aerosols Atmos. Environ. 2004, 38, 1367-1378
16. Molina, M. J.; Ivanov, A. V.; Trakhtenberg, S.; Molina, L. T. Atmospheric Evolution of Organic Aerosol Geophys. Res. Lett. 2004, 31, L22104/22101-L22104/ 22105
17. O'Dowd, C. D.; Facchini, M. C.; Cavalli, F.; Ceburnis, D.; Decesari, S.; Fuzzi, S.; Yoon, J. J.; Putaud, J.-P. Biogenically Driven Organic Contribution to Marine Aerosol Nature 2004, 431, 676-680
18. Donaldson, D. J.; Vaida, V. The Influence of Organic Films at the Air-Aqueous Boundary on Atmospheric Processes Chem. Rev. 2006, 106, 1445-1461
19. Bluhm, H.; Siegmann, H. C. Surface Science with Aerosols Surf. Sci. 2009, 603, 1969-1978
20. Fuzzi, S.; Andreae, M. O.; Huebert, B. J.; Kulmala, M.; Bond, T. C.; Boy, M.; Doherty, S. J.; Guenther, A.; Kanakidou, M.; Kawamura, K.; Kerminen, V.-M.; Lohmann, U.; Russell, L. M.; Pöschl, U. Critical Assessment of the Current State of Scientific Knowledge, Terminology, and Research Needs Concerning the Role of Organic Aerosols in the Atmosphere, Climate, and Global Change Atmos. Chem. Phys. Discuss. 2005, 5, 11729-11780
21. Rudich, Y. Laboratory Perspectives on the Chemical Transformation of Organic Matter in Atmospheric Particles Chem. Rev. 2003, 103, 5097-5124
22. Rudich, Y.; Donahue, N. M.; Mentel, T. F. Aging of Organic Aerosol: Bridging the Gap Between Laboratory and Field Studies Annu. Rev. Phys. Chem. 2007, 58, 321-352
23. Valsaraj, K. T.; Thibodeaux, L. J. On the Physicochemical Aspects of the Global Fate and Long-Range Atmospheric Transport of Persistent Organic Pollutants J. Phys. Chem. Lett. 2010, 1, 1694-1700
24. Gilman, J. B.; Eliason, T. L.; Fast, A.; Vaida, V. Selectivity and Stability of Organic Films at the Air-Aqueous Interface J. Colloid Interface Sci. 2004, 280, 234-243
25. Russell, L. M.; Maria, S. F.; Myneni, S. C. B. Mapping Organic Coatings on Atmospheric Particles Geophys. Res. Lett. 2002, 29, 1779/1771-1779/1774
26. Prenni, A. J.; De Mott, P. J.; Kreidenweis, S. M.; Sherman, D. E.; Russell, L. M.; Ming, Y. The Effects of Low Molecular weight Dicarboxylic Acids on Cloud Formation J. Phys. Chem. A 2001, 105, 11240-11248
27. Bilde, M.; Svenningsson, B.; Mønster, J.; Rosenørn, T. Even-Odd Alternation of Evaporation Rates and Vapor Pressures of C3-C9 Dicarboxilic Acid Aerosols Environ. Sci. Technol. 2003, 37, 1371-1378
28. Kim, H. I.; Goddard, W. A. I.; Beauchamp, J. L. Cluster Phase Chemistry: Gas-Phase Reactions of Anionic Sodium Salts of Dicarboxylic Acid Clusters With Water Molecules J. Phys. Chem. A 2006, 110, 7777-7786
29. Grunwald, E.; Pan, K.-C.; Effio, A. Hydrogen Bonding in Polar Liquid Solutions. 4. Effect of Hydrogen-Bonding Solutes on Dielectric Constant and Solvent Structures in 1-Octanol J. Phys. Chem. 1976, 80, 2937-2940
30. Beyer, K. D.; Friesen, K.; Bothe, J. R.; Palet, B. Phase Diagrams and Water Activities of Aqueous Dicarboxylic Acid Systems of Atmospheric Importance J. Phys. Chem. A 2008, 112, 11704-11713
31. Clegg, S. L.; Seinfeld, J. H. Thermodynamic Models of Aqueous Solutions Containing Inorganic Electrolytes and Dicarboxylic Acids at 298.151 K. 2. Systems Including Dissociation Equilibria J. Phys. Chem. A 2006, 110, 5718-5734
32. Rosado-Reyes, C. M.; Francisco, J. S. Atmospheric Oxidation Pathways of Acetic Acid J. Phys. Chem. A 2006, 110, 4419-4433
33. Freedman, M. A.; Hasenkopf, C. A.; Beaver, M. R.; Tolbert, M. A. Optical Properties of Internally Mixed Aerosol Particles Composed of Dicarboxylic Acids and Ammonium Sulfate J. Phys. Chem. A 2009, 113, 13584-13592
34. Choi, M. Y.; Chan, C. K. The Effect of Organic Species on the Hygroscopic Behaviors of Inorganic Aerosols Environ. Sci. Technol. 2002, 36, 2422-2428
35. Jung, J.; Tsatral, B.; Kim, Y. J.; Kawamura, K. Organic and Inorganic Aerosol Composition in Ulaanbaatar, Mongolia, During the Cold Winter of 2007 to 2008: Dicarboxylic Acids, Ketocarboxylic Acids, and α-Dicarbonyls J. Geophys. Res. 2010, 115, D22203/22201-D22203/22215
36. Legrand, M.; Preunkert, S.; Galy-Lacaux, C.; Liousse, C.; Wagenback, D. Atmospheric Year-Round Records of Dicarboxylic Acids and Sulfate at Three French Sites Located Between 630 and 4361 m Elevation J. Geophys. Res. 2005, 110, 13302
37. Kawamura, K.; Kobayashi, M.; Tsubonuma, N.; Mochida, M.; Watanabe, T.; Lee, M. Organic and Inorganic Compositions of Marine Aerosols from East Asia: Seasonal Variations of Water-Soluble Dicarboxylic Acids, Major Ions, Total Carbon and Nitrogen, and Stable C and N Isotopic Composition; Elsevier: New York, 2004.
38. Decesari, S.; Facchini, M. C.; Matta, E.; Lettini, F.; Mircea, M.; Fuzzi, S.; Tagliavini, E.; Putaud, J.-P. Chemical Features and Seasonal Variation of Fine Aerosol Water-Soluble Organic Compounds in the Po Valley, Italy Atmos. Environ. 2001, 35, 3691-3699
39. Decesari, S.; Facchini, M. C.; Fuzzi, S. Characterization of Water-Soluble Organic Compounds in Atmospheric Aerosol: A New Approach J. Geophys. Res. 2000, 105, 1481-1489
40. Simoneit, B. R. T.; Kobayashi, M.; Mochida, M.; Kawamura, K. Aerosol Particles Collected on Aircraft Flights Over the Northwestern Pacific Region During the ACE-Asia Campaign: Composition and Major Sources of the Organic Compounds J. Geophys. Res. 2004, 109, S09
41. Booth, A. M.; Topping, D. O.; McFiggans, G.; Percival, C. J. Surface Tension of Mixed Inorganic and Dicarboxylic Acid Aqueous Solutions at 298.15 K and Their Importance for Cloud Activation Predictions Phys. Chem. Chem. Phys. 2009, 11, 8021-8028
42. Varga, Z.; Kiss, G.; Hansson, H.-C. Modelling the Cloud Condensation Nucleus Activity of Organic Acids on the Basis of Surface Tension and Osmolality Measurements Atmos. Chem. Phys. 2007, 7, 4601-4611
43. Hyvärinen, A.-P.; Lihavainen, H.; Gaman, A.; Vairila, L.; Ojala, H.; Kulmala, M.; Viiasnen, Y. Surface Tensions and Densities of Oxalic, Malonic, Succinic, Maleic, Malic, and cis -Pinonic Acids J. Chem. Eng. Data 2006, 51, 255-260
44. Kawamura, K.; Kaplan, I. R. Motor Exhaust Emissions as a Primary Source for Dicarboxylic Acids in Los Angeles Ambient Air Environ. Sci. Technol. 1987, 21, 105-110
45. 2O Complex Found at the Vapor/Water Interface J. Am. Chem. Soc. 2005, 127, 16806-16807
46. 2 at a Water Surface J. Am. Chem. Soc. 2006, 128, 3256-3267
47. Ota, S. T.; Richmond, G. L. Chilling Out: A Cool Aqueous Environment Promotes the Formation of Gas-Surface Complexes J. Am. Chem. Soc. 2011, 133, 7497-7508
48. Shen, Y. R. Exploring New Opportunities with Sum-Frequency Nonlinear Optical Spectroscopy Pure Appl. Chem. 2001, 73, 1589-1598
49. Richmond, G. L. Molecular Bonding and Interactions at Aqueous Surfaces as Probed by Vibrational Sum Frequency Spectroscopy Chem. Rev. 2002, 102, 2693-2724
50. Jubb, A. M.; Hua, W.; Allen, H. C. Environmental Chemistry at Vapor/Water Interfaces: Insights from Vibrational Sum Frequency Generation Spectroscopy Annu. Rev. Phys. Chem. 2012, 63, 107-130
51. Bain, C. D.; Davies, P. B.; Ong, T. H.; Ward, R. N. Quantitative Analysis of Monolayer Composition by Sum-Frequency Vibrational Spectroscopy Langmuir 1991, 7, 1563-1566
52. Soule, M. C. K.; Blower, P. G.; Richmond, G. L. Effects of Atmospherically Important Solvated Ions on Organic Acid Adsorption at the Surface of Aqueous Solutions J. Phys. Chem. B 2007, 111, 13703-13713
53. Soule, M. C. K.; Blower, P. G.; Richmond, G. L. Nonlinear Vibrational Spectroscopic Studies of the Adsorption and Speciation of Nitric Acid at the Vapor/Acid Solution Interface J. Phys. Chem. A 2007, 111, 3349-3357
54. Gragson, D. E.; Alavi, D. S.; Richmond, G. L. Tunable Picosecond Infrared Laser System Based on Parametric Amplification in KTP with a Ti:Sapphire Oscillator Opt. Lett. 1995, 20, 1991-1993
55. Gragson, D. E.; McCarty, B. M.; Richmond, G. L.; Alavi, D. S. High-Power Broadly Tunable Picosecond IR Laser System for Use in Nonlinear Spectroscopic Investigations J. Opt. Soc. Am. B. 1996, 13, 2075-2083
56. Allen, H. C.; Raymond, E. A.; Richmond, G. L. Surface Structural Studies of Methanesulfonic Acid at Air/Aqueous Solution Interfaces Using Vibrational Sum Frequency Spectroscopy J. Phys. Chem. A 2001, 105, 1649-1655
57. Davies, J. T.; Rideal, E. K. Interfacial Phenomena, 2 nd ed.; Academic Press: New York, 1963.
58. Borkowski, M. BATE pH Calculator, 1.0.3.15 ed, 2008.
59. 2O Mixtures and Molecular Dynamics Simulations J. Phys. Chem. B 2003, 107, 546-556
60. Raymond, E. A.; Richmond, G. L. Probing the Molecular Structure and Bonding of the Surface of Aqueous Salt Solutions J. Phys. Chem. B 2004, 108, 5051-5059
61. Raymond, E. A.; Tarbuck, T. L.; Richmond, G. L. Isotopic Dilution Studies of the Vapor/Water Interface as Investigated by Vibrational Sum-Frequency Spectroscopy J. Phys. Chem. B 2002, 106, 2817-2820
62. Ostroverkhov, V.; Waychunas, G. A.; Shen, Y. R. New Information on Water Interfacial Structure Revealed by Phase-Sensitive Surface Spectroscopy Phys. Rev. Lett. 2005, 94, 046102/046101-046102/046104
63. Tian, C.-S.; Shen, Y. R. Isotopic Dilution Study of the Water/Vapor Interface by Phase-Sensitive Sum-Frequency Vibrational Spectroscopy J. Am. Chem. Soc. 2009, 131, 2790-2791
64. Tian, C. S.; Shen, Y. R. Sum-Frequency Vibrational Spectroscopic Studies of Water/Vapor Interfaces Chem. Phys. Lett. 2009, 470, 1-6
65. Fan, Y.; Chen, X.; Yang, L.; Cremer, P. S.; Gao, Y. Q. On the Structure of Water at the Aqueous/Air Interface J. Phys. Chem. B. 2009, 113, 11672-11679
66. Ishiyama, T.; Morita, A. Vibrational Spectroscopic Response of Intermolecular Orientational Correlation at the Water Surface J. Phys. Chem. C 2009, 113, 16299-16302
67. Ishiyama, T.; Morita, A. Analysis of Anisotropic Local Field in Sum Frequency Generation Spectroscopy with the Charge Response Kernel Water Model J. Chem. Phys. 2009, 131, 244714/244711-244714/244717
68. Sovago, M.; Vartiainen, E.; Bonn, M. Determining Absolute Molecular Orientation at Interfaces: A Phase Retrieval Approach for Sum Frequency Generation Spectroscopy J. Phys. Chem. C 2009, 113, 6100-6106
69. Bakker, H. J.; Skinner, J. L. Vibrational Spectroscopy as a Probe of Structure and Dynamics in Liquid Water Chem. Rev. 2010, 110, 1498-1517
70. Buch, V. Molecular Structure and the OH-Stretch Spectra of Liquid Water Surface J. Phys. Chem. B 2005, 109, 17771-17774
71. 2O Mixtures Studied Using Molecular Dynamics Simulations J. Phys. Chem. C 2007, 111, 8321-8330
72. Walker, D. S.; Hore, D. K.; Richmond, G. L. Understanding the Population, Coordination, and Orientation of Water Species Contributing to the Nonlinear Optical Spectroscopy of the Vapor-Water Interface through Molecular Dynamics Simulations J. Phys. Chem. B 2006, 110, 20451-20459
73. Sovago, M.; Campen, R. K.; Wurpel, G. W. H.; Müller, M.; Bakker, H. J.; Bonn, M. Vibrational Response of Hydrogen-Bonded Interfacial Water is Dominated by Intramolecular Coupling Phys. Rev. Lett. 2008, 100, 173901/173901-173901/173904
74. Sovago, M.; Campen, R. K.; Bakker, H. J.; Bonn, M. Hydrogen Bonding Strength of Interfacial Water Determined With Surface Sum-Frequency Generation Chem. Phys. Lett. 2009, 470, 7-12
75. Tarbuck, T. L.; Ota, S. T.; Richmond, G. L. Spectroscopic Studies of Solvated Hydrogen and Hydroxide Ions at Aqueous Surfaces J. Am. Chem. Soc. 2006, 128, 14519-14527
76. Case, D. A.; Cheatham, T., III; Darden, T. A.; Simmerling, C. L.; Wang, J.; Duke, R. E.; Luo, R.; Walker, R. C.; Zhang, W.; Merz, K. M.; Roberts, B.; Hayik, S.; Roitberg, A.; Seabra, G.; Swails, J.; Gotz, A. W.; Kolossvary, I.; Wong, K. F.; Paesani, F.; Vanicek, J.; Wolf, R. M.; Liu, J.; Wu, X.; Brozell, S. R.; Steinbrecher, T.; Gohlke, H.; Cai, Q.; Ye, X.; Wang, J.; Hsieh, M.-J.; Cui, G.; Roe, D. R.; Mathews, D. H.; Seetin, M. G.; Salomon-Ferrer, R.; Sagui, C.; Babin, V.; Luchko, T.; Gusarov, S.; Kovalenko, A.; Kollman, P. A. Amber 12; University of California: San Francisco, CA, 2012.
77. Martinez, L.; Andrade, R.; Birgin, E.; Martinez, J. PACKMOL: A Package for Building Initial Configurations for Molecular Dynamics Simulations J. Comput. Chem. 2009, 30, 2157-2164
78. Caldwell, J. W.; Kollman, P. A. Structure and Properties of Neat Liquids Using Nonadditive Molecular Dynamics: Water, Methanol, and N -Methylacetamide J. Phys. Chem. 1995, 99, 6208-6219
79. Case, D. A.; Cheatham, T. E.; Darden, T.; Gohlke, H.; Luo, R.; Merz, K. M.; Onufriev, A.; Simmerling, C.; Wang, B.; Woods, R. J. The Amber Biomolecular Simulation Programs J. Comput. Chem. 2005, 26, 1668-1688
80. Valiev, M.; Bylaska, E. J.; Govind, N.; Koawlski, K.; Straatsma, T. P.; Dam, H. J. J. V.; Wang, D.; Nieplocha, J.; Apra, E.; Windus, T. L.; Jong, W. A. d. NWChem: A Comprehensive and Scalable Open-Source Solution for Large Scale Molecular Simulations Comput. Phys. Commun. 2010, 181, 1477-1489
81. Saxena, P.; Hildemann, L. M. Water-Soluble Organics in Atmospheric Particles: A Critical Review of the Literature and Application of Thermodynamics to Identify Candidate Compounds J. Atmos. Chem. 1996, 24, 57-109
82. Johnson, C. M.; Tyrode, E.; Baldelli, S.; Rutland, M. W.; Leygraf, C. A Vibrational Sum Frequency Spectroscopy Study of the Liquid-Gas Interface of Acetic Acid-Water Mixtures: 1. Surface Speciation J. Phys. Chem. B 2005, 109, 321-328
83. Blower, P. G.; Shamay, E.; Kringle, L.; Ota, S. T.; Richmond, G. L. Surface Behavior of Malonic Acid Adsorption at the Air/Water Interface J. Phys. Chem. A 2013, 117, 2529-2542
84. Vinaykin, M.; Benderskii, A. V. Vibrational Sum-Frequency Spectrum of the Water Bend at the Air/Water Interface J. Phys. Chem. Lett. 2012, 3, 3348-3352
85. L Bands from Liquid Water J. Phys. Chem. 1988, 92, 2433-2438
86. Pavlovic, M.; Baranovic, G.; Lovrekovic, D. Raman Study of the Bending Band of Water Spectrochim. Acta 1991, 47A, 897-906
87. 2O J. Chem. Phys. 2008, 129, 064503
88. Cabaniss, S. E.; Leenheer, J. A.; McVey, I. F. Aqueous Infrared Carboxylate Absorbances: Aliphatic Di-Acids Spectrochim. Acta, Part A 1998, 54, 449-458
89. Bardet, L.; Maillols, J.; Maillols, H. Spectre Raman de lAcide Succinique en Solution Aqueuse Saturee G. R. Acad. Sci. Paris 1970, 270 (Serie B) 158-161
90. Gericke, A.; Huhnerfuss, H. In Situ Investigations of Saturated Long-Chain Fatty Acids at the Air/Water Interface by External Infrared Reflection-Absorption Spectroscopy J. Phys. Chem. 1993, 97, 12899-12908
91. Johann, R.; Vollhardt, D.; Mohwald, H. Study of the pH Dependence of Head Group Bonding in Arachidic Acid Monolayers by Polarization Modulation Infrared Reflection Absorption Spectroscopy Colloids Surf., A 2001, 182, 311-320
92. Muro, M.; Itoh, Y.; Hasegawa, T. A Conformation and Orientation Model of the Carboxylic Group of Fatty Acids Dependent on Chain Length in a Langmuir Monolayer Film Studied by Polarization-Modulation Infrared Reflection Absorption Spectroscopy J. Phys. Chem. B 2010, 114, 11496-11501
93. Socrates, G. Infrared and Raman Characteristic Group Frequencies: Tables and Charts; John Wiley and Sons, Ltd.: New York, 2001.
94. Mitsui, K.; Ukaji, T. Infrared Spectra of Some Aqueous Solutions Ikutoku Kogyo Daigaku Kenkyu Hokoku, B 1977, B-2, 77-82
95. Rosen, M. J. Surfactants and Interfacial Phenomena, 3 rd ed.; John Wiley & Sons, Inc.: New York, 2004.
96. Rao, Y.; Li, X.; Lei, X.; Jockusch, S.; George, M. W.; Turro, N. J.; Eisenthal, K. B. Observations of Interfacial Population and Organization of Surfactants with Sum Frequency Generation and Surface Tension J. Phys. Chem. C 2001, 115, 12064-12067
97. Tyrode, E.; Johnson, C. M.; Kumpulainen, A.; Rutland, M. W.; Claesson, P. M. Hydration State of Nonionic Surfactant Monolayers at the Liquid/Vapor Interface: Structure Determination by Vibrational Sum Frequency Spectroscopy J. Am. Chem. Soc. 2005, 127, 16848-16859
98. CRC Handbook of Chemistry and Physics, 85 ed.; CRC Press: Boca Raton, FL, 2004.
99. Crans, D. C.; Levinger, N. E. The Conundrum of pH in Water Nanodroplets: Sensing pH in Reverse Micelle Water Pools Acc. Chem. Res. 2011, 45, 1637-1645
100. Krivacsy, Z.; Molnar, A. Size Distribution of Ions in Atmospheric Aerosols Atmos. Res. 1998, 46, 279-291
101. Jeffrey, L.; Collett, J.; Bator, A.; Rao, X.; Demoz, B. B. Acidity Variations Across the Cloud Drop Size Spectrum and Their Influence on Rates of Atmospheric Sulfate Production Geophys. Res. Lett. 1994, 21, 2393-2396
102. Keene, W. C.; Sander, R.; Pszenny, A. A. P.; Vogt, R.; Crutzen, P. J.; Galloway, J. N. Aerosol pH in the Marine Boundary Layer: A Review and Model Evaluation J. Aerosol Sci. 1998, 29, 339-356
103. Keene, W. C.; Pszenny, A. A. P.; Maben, J. R.; Stevenson, E.; Wall, A. Closure Evaluation of Size-Resolved Aerosol pH in the New England Coastal Atmosphere During Summer J. Geophys. Res. 2004, 109, D23307
104. Zhang, Q.; Jimenez, J. L.; Worsnop, D. R.; Canagaratna, M. A Case Study of Urban Particle Acidity and Its Influence on Secondary Organic Aerosol Environ. Sci. Technol. 2007, 41, 3213-3219
105. Ludwig, J.; Klemm, O. Organic Acids in Different Size Classes of Atmophseric Particulate Materials Tellus 1988, 40B, 340-347