Analysis of the kinetic slowing down during carbonation of CaO by CO 2

Journal of Thermal Analysis and Calorimetry

Volumn 113, Issue 3, 2013, Pages 1145-1155

  Rouchon, Lydie ^a   Favergeon, Loïc ^a   Pijolat, Michèle ^a  

^a ECOLE DES MINES DE SAINT ETIENNE   (France)

Author keywords

Calcium oxide; Carbonation; Kinetics; Porosity; TG

Indexed keywords

FRACTIONAL CONVERSION; INTENSIVE VARIABLES; ISOBARIC CONDITION; POROUS AGGREGATES; RATE DETERMINING STEP; REACTION MECHANISM; TEXTURAL PROPERTIES; TG;

CALCIUM CARBONATE; CARBONATION; ENZYME KINETICS; KINETICS; LIME; POROSITY; THERMOGRAVIMETRIC ANALYSIS;

CARBON DIOXIDE;

EID: 84883167995     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-013-2950-5     Document Type: Conference Paper

References (37)

1. Gray ML, Soong Y, Champagne KJ, Pennline H, Baltrus JP, Stevens RW Jr, Khatri R, Chuang SSC, Filburn T. Improved immobilized carbon dioxide capture solvants. Fuel Process Technol. 2005;86:1449-55.
2. 2 sequestration. Fuel Process Technol. 2005;86:1707-43.
3. Chrissafis K. Multicyclic study on the carbonation of CaO using different limestones. J Therm Anal Calorim. 2007;89:525-9.
4. Gupta H, Fan LS. Carbonation-calcination cycle using high reactivity calcium oxide for carbon dioxide separation from flue gas. Ind Eng Chem Res. 2002;41:4035-42.
5. 2 capture from flue gases. Vol. 17. In: 9th International Conference on Chemical and Process Engineering, Chemical Engineering Transactions; 2009. p. 403-8.
6. Kato Y, Saku D, Harada N, Yoshizawa Y. Utilization of high temperature heat using a calcium oxide lead oxide carbon dioxide chemical heat pump. J Chem Eng Jpn. 1997;30:1013-9.
7. Kato Y, Yamada M, Kanie T, Yoshizawa Y. Calcium oxide/carbon dioxide reactivity in a packed bed reactor of a chemical heat pump for high-temperature gas reactors. Nucl Eng Des. 2001;210:1-8.
8. Li G, Kanie T, Kato Y, Yoshizawa Y. Heat and mass transfer in a packed bed reactor for calcium oxide/carbon dioxide chemical heat pump. J Chem Eng Jpn. 2002;35:886-92.
9. Aihara M, Nagai T, Matsusita J, Negishi Y, Ohya H. Development of porous solid reactant for thermal-energy storage and temperature upgrade using carbonation/decarbonation reaction. Appl Energy. 2001;69:225-38.
10. Kyaw K, Matsuda H, Hasatani M. Applicability of carbonation decarbonation reactions to high-temperature thermal energy storage and temperature upgrading. J Chem Eng Jpn. 1996;29:119-25.
11. Kyaw K, Kubota M, Watanabe F, Matsuda H, Hasatani M. Study of carbonation of CaO for high temperature thermal energy storage. J Chem Eng Jpn. 1998;31:281-4.
12. Lin SY, Suzuki Y, Hatano H, Harada M. Developing an innovative method, HyPr-RING, to produce hydrogen from hydrocarbons. Energy Convers Manage. 2002;43:1283-90.
13. 2 removal utilizing the CaO carbonation for H-2 production. Chem Eng Sci. 2004;59:931-42.
14. 2 sorbent. Fuel Process Technol. 2012;96:27-36.
15. Bouquet E, Leyssens G, Schönnenbeck C, Gilot P. The decrease of carbonation efficiency of CaO along calcination-carbonation cycles: experiments and modeling. Chem Eng Sci. 2009;64:2136-46.
16. 2. Ind Eng Chem Res. 2005;44:5608-15.
17. Alvarez D, Abanades JC. Pore-size and shape effects on the recarbonation performance of calcium oxide submitted to repeated calcination/recarbonation cycles. Energy Fuels. 2005;19:270-8.
18. 2 with lime. Energy Fuels. 2003;17:308-15.
19. Grasa GS, Abanades JC, Alonso M, Gonzales B. Reactivity of highly cycled particles of CaO in a carbonation/calcinations loop. Chem Eng J. 2008;137:561-7.
20. 2. J Appl Chem Biotechnol. 1973;23:733-42.
21. 2-lime reaction. AIChE J. 1983;29:79-86.
22. Lee DK. An apparent kinetic model for the carbonation of calcium oxide by carbon dioxide. Chem Eng J. 2004;100:71-7.
23. 2 reaction. Chem Eng Sci. 2008;63:47-56.
24. 2 reaction. Chem Eng Sci. 2008;63:57-70.
25. 2. Energy Fuels. 2012;26:4607-16.
26. Pijolat M, Soustelle M. Experimental tests to validate the rate-limiting step assumption used in the kinetic analysis of solid-state reactions. Thermochim Acta. 2008;478:34-40.
27. Barret P. Cinétique hétérogène. Paris: Gauthier-Villars; 1973.
28. Delmon B. Introduction à la cinétique hété rogène, Publications de l'institut français du pétrole. Paris: Ed. Technip; 1969.
29. 3-CaO solar thermochemical cycle. Chem Eng J. 2007;129:75-83.
30. Rouquerol F, Rouquerol J, Sing KSW. Adsorption by powders and porous solids: principles, methodology and applications. San Diego: Academic press; 1999.
31. Pijolat M, Favergeon L, Soustelle M. From the drawbacks of the Arrhenius-f(α) rate equation towards a more general formalism and new models for the kinetic analysis of solid-gas reactions. Thermochim Acta. 2011;525:93-102.
32. Soustelle M. Heterogenous kinetics handbook. London: Wiley-ISTE; 2010.
33. Pijolat M, Valdivieso F, Soustelle M. Experimental test to validate the rate equation "dα/dt = kf(α)" used in the kinetic analysis of solid state reactions. Thermochim Acta. 2005;439:86-93.
34. Favergeon L. PhD thesis, Ecole Nationale Supérieure des Mines. Saint-Etienne: 2006.
35. 2: nucleation and growth, influence of hydration. Phys Chem Chem Phys. 1999;1:471-7.
36. Burgers WG, Groen LJ. Mechanism and kinetics of the allotropic transformation of tin. Discuss Faraday Soc. 1957;23:183-95.
37. Mess D, Sarofim AF, Longwell JP. Product layer diffusion during the reaction of calcium oxide with carbon dioxide. Energy Fuels. 1999;13:999-1005.