Modeling and simulation for the methane steam reforming enhanced by in situ CO2 removal utilizing the CaO carbonation for H2 production

Chemical Engineering Science

Volumn 59, Issue 4, 2004, Pages 931-942

  Lee, Deuk Ki ^a   Baek, Il Hyun ^b   Yoon, Wang Lai ^b  

^a Kwangju University   (South Korea)

^b Korea Institute of Energy Research (KIER)   (South Korea)

Author keywords

CaO carbonation; CO2 removal; H2 production; Methane steam reforming; Modeling; Packed bed

Indexed keywords

CARBON MONOXIDE; CARBONATION; CATALYSIS; HYDROGEN; MATHEMATICAL MODELS; REACTION KINETICS; STEAM; THERMAL EFFECTS;

METHANE STEAM REFORMING (MSR); PACKED BED REACTORS;

METHANE;

CARBON DIOXIDE; CARBONATION; HYDROGEN; MATHEMATICAL ANALYSIS; METHANE; MODELING; PACKED BED; REMOVAL;

EID: 1442360278     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2003.12.011     Document Type: Article

References (19)

1. 3. Chemical Engineering Journal, 90 303-306.
2. Balasubramanian, B., Ortiz, A. L., Kaytakouglu, S., & Harrison, D. P. (1999). Hydrogen from methane in a single-step process. Chemical Engineering Science, 54 3543-3552.
3. Barin, I. (1989). Thermochemical data of pure substance. VCH: Weinheim.
4. 2-lime reaction. A.I.Ch.E. Journal, 29(1), 79-86.
5. Brun-Tsekhovoi, A.R., Zadorin, A.N., Katsobashvili, Y.R., Kourdyumov, S.S., 1986. The process of catalytic steam-reforming of hydrocarbons in the presence of carbon dioxide acceptor. In: Proceedings of the World Hydrogen Energy Conference, Vol. 2, Pergamon Press, New York, pp. 885-900.
6. Carvill, B. T., Hufton, J. R., Anand, M., & Sircar, S. (1996). Sorption-enhanced reaction process. A.I.Ch.E. Journal, 42(10), 2765-2772.
7. 3. Transactions of the Faraday Society, 58 2027-2035.
8. De Wash, A. P., & Froment, G. F. (1972). Heat transfer in packed bed. Chemical Engineering Science, 27 567-576.
9. Ding, Y., & Alpay, E. (2000). Adsorption-enhanced steam-methane reforming. Chemical Engineering Science, 55 3929-3940.
10. Ergun, S. (1952). Fluid flow through packed columns. Chemical Engineering Progress, 48 89-94.
11. Feyo De Azevedo, S., Romero-Ogawa, M. A., & Wardle, A. P. (1990). Modeling of tubular fixed bed catalytic reactors: a brief review. Transactions of the Institution of Chemical Engineers, Part A, 68 483-502.
12. Han, C., & Harrison, D. P. (1994). Simultaneous shift reaction and carbon dioxide separation for the direct production of hydrogen. Chemical Engineering Science, 49 5875-5883.
13. Hufton, J. R., Mayorga, S., & Sircar, S. (1999). Sorption-enhanced reaction process for hydrogen production. A.I.Ch.E. Journal, 45 248-256.
14. Lee, D.K., 2004. An apparent kinetic model for the carbonation of calcium oxide by carbon dioxide. Chemical Engineering Journal, in press.
15. Li, C., & Finlayson, B. A. (1977). Heat transfer in packed beds-A reevaluation. Chemical Engineering Science, 32 1055-1066.
16. Ortiz, A. L., & Harrison, D. P. (2001). Hydrogen production using sorption-enhanced reaction. Industrial and Engineering Chemistry Research, 40 5102-5109.
17. Waldron, W. E., Hufton, J. R., & Sircar, S. (2001). Production of hydrogen by cyclic sorption enhanced reaction process. A.I.Ch.E. Journal, 47(6), 1477-1479.
18. Xiu, G., Li, P., & Rodrigues, A. E. (2002). Sorption-enhanced reaction process with reactive regeneration. Chemical Engineering Science, 57 3893-3908.
19. Xu, J., & Froment, G. F. (1989). Methane steam reforming, methanation and water-gas shift: I. Intrinsic kinetics. A.I.Ch.E. Journal, 35 88-96.