From the drawbacks of the Arrhenius-f(α) rate equation towards a more general formalism and new models for the kinetic analysis of solid-gas reactions

Thermochimica Acta

Volumn 525, Issue 1-2, 2011, Pages 93-102

  Michle, Pijolat ^a   Loïc, Favergeon ^a   Michel, Soustelle ^a  

^a CENTRE SPIN   (France)

Author keywords

Growth; Kinetics; Nucleation; Rate equation; Simulation; Software; Solid gas reactions

Indexed keywords

APPARENT ACTIVATION ENERGY; ARRHENIUS DEPENDENCE; CHEMICAL TRANSFORMATIONS; CRITICAL ANALYSIS; FREE ACCESS; GAS-SOLID; GENERAL EQUATIONS; KINETIC ANALYSIS; KINETIC CURVES; KINETIC MODELS; MATHEMATICAL FUNCTIONS; NEW MODEL; NUCLEATION AND GROWTH; NUCLEATION PROCESS; RATE DETERMINING STEP; RATE EQUATIONS; SIMULATION; SIMULATION AND OPTIMIZATION; SOFTWARE TOOL; SOLID GAS REACTION; SOLID GAS REACTIONS; THERMODYNAMIC VARIABLES;

ACTIVATION ENERGY; CHEMICAL ANALYSIS; COMPUTER SOFTWARE; ENZYME KINETICS; FUNCTIONS; GROWTH (MATERIALS); GROWTH KINETICS; KINETIC THEORY; NUCLEATION; PYROLYSIS; REACTION KINETICS; TEMPERATURE;

KINETICS;

EID: 80053373933     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2011.07.026     Document Type: Article

References (24)

1. A.K. Galwey, and M.E. Brown Thermal Decomposition of Ionic Solids 1999 Elsevier Amsterdam
2. J.H. Sharp, G.W. Brindley, and B.N.N. Achar Numerical data for some commonly used solid state reaction equations J. Am. Ceram. Soc. 49 1966 379
3. A. Ortega The kinetics of solid-state reactions toward consensus - Part I: uncertainties, failures, and successes of conventional methods Int. J. Chem. Kinet. 33 2001 343 353 (Pubitemid 32495881)
4. M. Pijolat, and M. Soustelle Experimental tests to validate the rate-limiting step assumption used in the kinetic analysis of solid-state reactions Thermochim. Acta 478 2008 34 40
5. K.L. Mampel Time-conversion formulae for heterogenous reactions in phase limits of solid bodies - 2. The time-conversion formulae for a powder from globular particles Z Phys. Chem. A 187 1940 235 249
6. W.A. Johnson, and R.F. Mehl Reaction kinetics in processes of nucleation and growth Trans. Am. Inst. Min. Metall. Eng. 135 1939 416 442
7. B. Delmon Introduction la cinétique hétérogne 1969 Technip Paris
8. 2: nucleation and growth influence of hydration Phys. Chem. Chem. Phys. 1 1999 471 477
9. K. Nahdi, S. Perrin, M. Pijolat, F. Rouquerol, N. Ariguib, and M. Ayadi Nucleation and anisotropic growth model for isothermal kaolinite dehydroxylation under controlled water vapour pressure Phys. Chem. Chem. Phys. 4 2002 1972 1977
10. M. Tupin, M. Pijolat, F. Vadivieso, and M. Soustelle Oxidation kinetics of ZrNbO in steam differences between the pre- and post-transition stages J. Nucl. Mater. 342 2005 108 118 (Pubitemid 40833804)
11. P. Kofstad High Temperature Oxidation of Metals 1966 Wiley New York
12. D. Young High Temperature Oxidation and Corrosion of Metals 2008 Elsevier Amsterdam
13. L. Neveux, D. Chiche, D. Bazer-Bachi, L. Favergeon, M. Pijolat, ZnO sulfidation. A microstructural approach of the reaction mechanism, Chem. Eng. J., submitted for publication.
14. M. Soustelle Handbook of Heterogeneous Chemistry 2010 Wiley and ISTE Ltd. London
15. L. Favergeon, M. Pijolat, M. Soustelle, M. Dupoizat, L. Alconada, S. Hébrard, Thermochim. Acta, submitted for publication.
16. H.G. McIlvried, and F.E. Massoth Effect of particle size distribution on gas-solid reaction kinetics for spherical particles Ind. Eng. Chem. Fundam. 12 1973 225 229
17. G. Thomas, and D. Ingrain Lois cinétiques pour les reactions solide-solide J. Chim. Phys. 79 1982 729 733
18. A. Fevre, and M. Murat Theoretical-analysis of kinetic laws currently used in thermoanalysis for studying solid-gas reactions.1. Laws of diffusion J. Therm. Anal. 7 1975 429 433
19. L. Favergeon, Germination en surface dans les transformations chimiques de solides, Cas de la déshydratation du sulfate de lithium monohydraté, Thse, Saint-Etienne, France, 2006.
20. A.K. Burnham, R.K. Weese, and B.L. Weeks A distributed activation energy model of thermodynamically inhibited nucleation and growth reactions and its application to the beta-delta phase transition of HMX J. Phys. Chem. B 108 2004 19432 19441 (Pubitemid 40011194)
21. M. Pijolat, and M. Soustelle Experimental test to validate the rate equation dalpha/dt = kf (alpha) used in the kinetic analysis of solid state reactions Thermochim. Acta 439 2005 86 93 (Pubitemid 41693381)
22. K. Miyokawa, and I. Masuda Influence of particle-size distribution of a sample on the kinetic-parameters determined by thermogravimetric curves Thermochim. Acta 86 1985 113 118
23. A.K. Lahiri The effect of particle-size distribution on TG Thermochim. Acta 40 1980 289 295
24. N. Koga, and J.M. Criado Influence of the particle size distribution on the CRTA curves for the solid-state reactions of interface shrinkage J. Therm. Anal. 49 1997 1477 1484 (Pubitemid 127822027)