Compositional controls on hydrogen generation during serpentinization of ultramafic rocks

Lithos

Volumn 178, Issue , 2013, Pages 55-69

  Klein, Frieder ^a   Bach, Wolfgang ^b   McCollom, Thomas M ^c  

^a WOODS HOLE OCEANOGRAPHIC INSTITUTION   (United States)

^b UNIVERSITY OF BREMEN   (Germany)

^c UNIVERSITY OF COLORADO   (United States)

Author keywords

Fayalite; Hydrogen; Peridotite; Pyroxenite; Serpentinization; Thermodynamic models

Indexed keywords

CHEMICAL COMPOSITION; FAYALITE; FLUID COMPOSITION; HYDROGEN; LITHOLOGY; PERIDOTITE; PYROXENITE; SECONDARY MINERAL; SERPENTINITE; SERPENTINIZATION; THERMODYNAMICS; ULTRAMAFIC ROCK; WATER TEMPERATURE;

EID: 84882869137     PISSN: 00244937     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.lithos.2013.03.008     Document Type: Article

References (82)

1. Allen D.E., Seyfried W.E.J. Compositional controls on vent fluids from ultramafic-hosted hydrothermal systems at mid-ocean ridges: an experimental study at 400°C, 500bars. Geochimica et Cosmochimica Acta 2003, 67:1531-1542.
2. Anderson G. Thermodynamics of natural systems 2005, Cambridge University Press, (662pp.).
3. 2-rich brine through peridotites. Environmental Science & Technology 2009, 43:1226-1231.
4. Austrheim H., Prestvik T. Rodingitization and hydration of the oceanic lithosphere as developed in the Leka ophiolite, north-central Norway. Lithos 2008, 104:177-198.
5. Bach W., Klein F. The petrology of seafloor rodingites: insights from geochemical reaction path modeling. Lithos 2009, 112:103-117.
6. Bach W., Garrido C.J., Harvey J., Paulick H., Rosner M. Seawater-Peridotite Interactions - First Insights from ODP Leg 209, MAR 15oN. Geochemistry, Geophysics, Geosystems 2004, 5:Q09F26. 10.1029/2004GC000744.
7. Bach W., Paulick H., Garrido C.J., Ildefonse B., Meurer W.P., Humphris S.E. Unraveling the sequence of serpentinitzation reactions: petrography, mineral chemistry, and petrophyscis of serpentinites from MAR 15oN (ODP Leg 209, Site 1274). Geophysical Research Letters 2006, 33:L13306. doi:13310.11029/12006GL025681.
8. Barber D.J. Matrix phyllosilicates and associated minerals in C2M carbonaceous chondrites. Geochimica et Cosmochimica Acta 1981, 45(6):945-970.
9. Barnes I., Lamarche V.C., Himmelberg G. Geochemical evidence of present-day serpentinization. Science 1967, 156:830-832.
10. Barnes I., O'Neil J.R., Trescases J.J. Present day serpentinization in New Caledonia, Oman and Yugoslavia. Geochimica et Cosmochimica Acta 1978, 42:144-145.
11. Beard J.S., Hopkinson L. A fossil, serpentinization-related hydrothermal vent, Ocean Drilling Program Leg 173, Site 1068 (Iberia Abyssal Plain): some aspects of mineral and fluid chemsitry. Journal of Geophysical Research 2000, 105:16527-16539.
12. Beard J.S., Frost B.R., Fryer P., McCaig A., Searle R., Ildefonse B., Zinin P., Sharma S.K. Onset and progression of serpentinization and magnetite formation in olivine-rich troctolite from IODP Hole U1309D. Journal of Petrology 2009, 50:387-403.
13. Blais S., Auvray B. Serpentinization in the Archean komatiitic rocks of the Kuhmo greenstone-belt, eastern Finland. The Canadian Mineralogist 1990, 28:55-66.
14. 2O. Geological Society of America Bulletin 1949, 60:439-460.
15. Brazelton W.J., Ludwig K.A., Sogin M.L., Andreishcheva E.N., Kelley D.S., Shen C.-C., Edwards R.L., Baross J.A. Archaea and bacteria with surprising microdiversity show shifts in dominance over 1,000-year time scales in hydrothermal chimneys. Proceedings of the National Academy of Sciences 2010, 107:1612-1617.
16. 4 vent fluids issuing from ultramafic rocks at the Rainbow hydrothermal field (36°14'N, MAR). Chemical Geology 2002, 191:345-359.
17. Cox M.E., Launay J., Paris J.P. Geochemistry of low temperature geothermal systems in New Caledonia. Proceedings of the Pacific Geothermal Conference 1982, 453-459. University of Auckland, New Zealand, (Part 2).
18. D'Antonio M., Kristensen M.B. Serpentine and brucite of ultramafic clasts from the South Chamorro Seamount (Ocean Drilling Program Leg 195, Site 1200): inferences for the serpentinization of the Mariana forearc mantle. Mineralogical Magazine 2004, 68:887-904.
19. Deer W.A., Howie R.A., Zussman J. Ortho- and ring silicates 1962, Wiley.
20. Delacour A.l, Früh-Green G.L., Frank M., Gutjahr M., Kelley D.S. Sr- and Nd-isotope geochemistry of the Atlantis Massif (30°N, MAR): implications for fluid fluxes and lithospheric heterogeneity. Chemical Geology 2008, 254:19-35.
21. Drummond S.E. Boiling and Mixing of Hydrothermal Fluids: Chemical Effects on Mineral Precipitation 1981, The Pennsylvania State University.
22. Dungan M.A. Bastite pseudomorphs after orthopyroxene, clinopyroxene and tremolite. The Canadian Mineralogist 1979, 17:729-740.
23. Eckstrand O.R. The Dumont Serpentinite: a model for control of nickeliferous opaque mineral assemblages by alteration reactions in ultramafic rocks. Economic Geology 1975, 70:183-201.
24. Evans B.W. The serpentine multisystem revisited: chrysotile is metastable. International Geology Review 2004, 46:479-506.
25. -1 exchange potential of olivine and orthopyroxene. Journal of Petrology 2008, 49:1873-1887.
26. Evans B., Trommsdorff V. Der Einfluss des Eisens auf die Hydratisierung von Duniten. Schweizerische Mineralogische und Petrographische Mitteilungen 1972, 52:251-256.
27. Evans B.W., Kuehner S.M., Chopelas A. Magnetite-free, yellow lizardite serpentinization of olivine websterite, Canyon Mountain complex, NE Oregon. American Mineralogist 2009, 94:1731-1734.
28. Evans K.A., Powell R., Frost B.R. Using equilibrium thermodynamics in the study of metasomatic alteration, illustrated by an application to serpentinites. Lithos 2013, 168:67-84. 10.1016/j.lithos.2013.01.016.
29. Flaschen S.S., Osborn E.F. Studies of the system iron-oxide-silica-water at low oxygen partial pressures. Economic Geology 1957, 52:923-943.
30. 2. American Mineralogist 1969, 54:1399-1408.
31. Foustoukos D.I., Seyfried W.E. Hydrocarbons in hydrothermal vent fluids: the role of chromium-bearing catalysts. Science 2004, 304:1002-1005.
32. Foustoukos D.I., Savov I.P., Janecky D.R. Chemical and isotopic constraints on water/rock interactions at the Lost City hydrothermal field, 30°N Mid-Atlantic Ridge. Geochimica et Cosmochimica Acta 2008, 72:5457-5474.
33. Frost B.R., Beard J.S. On silica activity and serpentinization. Journal of Petrology 2007, 48:1351-1368.
34. Frost B.R., Beard J.S., McCaig A., Condliffe E. The formation of micro-rodingites from IODP Hole U1309D: key to understanding the process of serpentinization. Journal of Petrology 2008, 49:1529-1588.
35. Frost B.R., Evans K., Swapp S.M., Beard J.S. The process of serpentinization in dunite from New Caledonia. Lithos 2013, 178:24-39.
36. Hansen L.D., Dipple G.M., Gordon T.M., Kellett D.A. Carbonated serpentinite (listwanite) at Atlin, British Columbia: a geological analogue to carbon dioxide sequestration. The Canadian Mineralogist 2005, 43:225-239.
37. Helgeson H.C., Delany J.M., Nesbitt H.W., Bird D.K. Summary and critique of the thermodynamic properties of rock-forming minerals. American Journal of Science 1978, 278A:1-229.
38. Horita J., Berndt M.E. Abiogenic methane formation and isotopic fractionation under hydrothermal conditions. Science 1999, 285:1055-1057.
39. Hostetler P.B., Coleman R.G., Mumpton F.A., Evans B.W. Brucite in alpine serpentinites. American Mineralogist 1966, 51:75-98.
40. 2O=serpentine+brucite. Contributions to Mineralogy and Petrology 1968, 19:305-319.
41. Johnson J.W., Oelkers E.H., Helgeson H.C. SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1-5000bars and 0-1000°C. Computers & Geosciences 1992, 18:899-947.
42. Jöns N., Bach W., Klein F. Magmatic influence on reaction paths and element transport during serpentinization. Chemical Geology 2010, 274:196-211.
43. Katayama I., Kurosaki I., Hirauchi K.-I. Low silica activity for hydrogen generation during serpentinization: an example of natural serpentinites in the Mineoka ophiolite complex, central Japan. Earth and Planetary Science Letters 2010, 298:199-204.
44. Kelley D.S., Karson J.A., Blackman D.K., Früh-Green G.L., Butterfield D.A., Lilley M.D., Olson E.J., Schrenk M.O., Roe K.K., Lebon G.T., Rivizzigno P., Party A.-S. An off-axis hydrothermal vent field near the Mid-Atlantic Ridge at 30°N. Nature 2001, 412:127-128.
45. Kelley D.S., Karson J.A., Früh-Green G.L., Yoerger D.R., Shank T.M., Butterfield D.A., Hayes J.M., Schrenk M.O., Olson E.J., Proskurowski G., Jakuba M., Bradley A., Larson B., Ludwig K., Glickson D., Buckman K., Bradley A.S., Brazelton W.J., Roe K., Elend M.L., Delacour A., Bernasconi S.M., Lilley M.D., Baross J.A., Summons R.E., Sylva S.P. A serpentinite-hosted ecosystem: the Lost City Hydrothermal Field. Science 2005, 307:1428-1434.
46. Klein F., Garrido C.J. Thermodynamic constraints on mineral carbonation of serpentinized peridotite. Lithos 2011, 126:147-160.
47. Klein F., Bach W., Jöns N., McCollom T., Moskowitz B., Berquó T. Iron partitioning and hydrogen generation during serpentinization of abyssal peridotites from 15°N on the Mid-Atlantic Ridge. Geochimica et Cosmochimica Acta 2009, 73:6868-6893.
48. Kodolanyi J., Pettke T., Spandler C., Kamber B.S., Gmeling K. Geochemistry of ocean floor and fore-arc serpentinites: constraints on the ultramafic input to subduction zones. Journal of Petrology 2012, 53:235-270.
49. Li X.-P., Rahn M., Bucher K. Serpentinites of the Zermatt-Saas ophiolite complex and their texture evolution. Journal of Metamorphic Geology 2004, 22:159-177.
50. Mao N.-H., Ito J., Hays J.F., Drake J., Birch F. Composition and elastic constants of hortonolite dunite. Journal of Geophysical Research 1970, 75:4071-4076.
51. 2 degassing during serpentinization at 300°C/300bar. Earth and Planetary Science Letters 2011, 303:281-290.
52. Martin B., Fyfe W.S. Some experimental and theoretical observations on the kinetics of hydration reactions with particular reference to serpentinization. Chemical Geology 1970, 6:185-202.
53. Martin W., Russell M.J. On the origin of biochemistry at an alkaline hydrothermal vent. Philosophical Transactions of the Royal Society B 2006, 10.1098/rstb.2006.1881.
54. McCollom T.M. Geochemical constraints on primary productivity in submarine hydrothermal vent plumes. Deep-Sea Research Ietters 2000, 47:85-101.
55. McCollom T.M., Bach W. Thermodynamic constraints on hydrogen generation during serpentinization of ultramafic rocks. Geochimica et Cosmochimica Acta 2009, 73:856-875.
56. 2 to hydrocarbons during serpentinization of olivine. Geochimica et Cosmochimica Acta 2001, 65:3769-3778.
57. Moody J.B. An experimental study on the serpentinization of iron-bearing olivines. American Mineralogist 1976, 14:462-478.
58. Mottl M.J. Highest pH?. Geochemical News 2009, 141.
59. Mottl M.J., Wheat C.G., Fryer P., Gharib J., Martin J.B. Chemistry of springs across the Mariana forearc shows progressive devolatilization of the subducting plate. Geochimica et Cosmochimica Acta 2004, 68:4915-4933.
60. Noack Y., Decarreau A., Manceau A. Spectroscopic and oxygen isotopic evidence for low and high temperature origin of talc. Bulletin de Mineralogie 1986, 109:253-263.
61. 2 in planetary surfaces. Icarus 2007, 186:557-561.
62. Pasteris J.D. Occurrence of graphite in serpentinized olivines in kimberlite. Geology 1981, 9:356-359.
63. Perner M., Kuever J., Seifert R., Pape T., Koschinsky A., Schmidt K., Strauss H., Imhoff J.F. The influence of ultramafic rocks on microbial communities at the Logatchev hydrothermal field, located 15 °N on the Mid-Atlantic Ridge. FEMS Microbiology Ecology 2007, 61:97-109.
64. Petersen J.M., Zielinski F.U., Pape T., Seifert R., Moraru C., Amann R., Hourdez S., Girguis P.R., Wankel S.D., Barbe V., Pelletier E., Fink D., Borowski C., Bach W., Dubilier N. Hydrogen is an energy source for hydrothermal vent symbioses. Nature 2011, 476:176-180.
65. Proskurowski G., Lilley M.D., Seewald J.S., Früh-Green G., Olson E.J., Lupton J.E., Sylva S.P., Kelley D.S. Abiogenic hydrocarbon production at Lost City hydrothermal field. Science 2008, 319:604-607.
66. Ramdohr P. Über Josephinite, Awaruite, Souesite, ihre Eigenschaften, Enstehung und Paragensis. Mineralogical Magazine 1950, 29:374-394.
67. 2O. The Canadian Mineralogist 1998, 36:147-162.
68. Seyfried W.E., Foustoukos D.I., Fu Q. Redox evolution and mass transfer during serpentinization; an experimental and theoretical study at 200°C, 500bar with implications for ultramafic-hosted hydrothermal systems at mid-ocean ridges. Geochimica et Cosmochimica Acta 2007, 71:3872-3886.
69. Shock E.L., Helgeson H.C. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: correlation algorithms for ionic species and equation of state predictions to 5kb and 1000°C. Geochimica et Cosmochimica Acta 1988, 52:2009-2036.
70. Shock E.L., Helgeson H.C., Sverjensky D.A. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: standard partial molal properties of inorganic neutral species. Geochimica et Consmochimica Acta 1989, 53:2157-2183.
71. Shock E.L., Sassani D.C., Willis M., Sverjensky D.A. Inorganic species in geologic fluids: correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes. Geochimica et Cosmochimica Acta 1997, 61:907-950.
72. 2-rich fluids from serpentinization: geochemical and biotic implications. Proceeding of the National Academy of Sciences 2004, 104:12818-12823.
73. Tagirov B., Schott J. Aluminum speciation in crustal fluids revisited. Geochimica et Cosmochimica Acta 2001, 65:3965-3992.
74. Takai K., Moyer C.L., Miyazaki M., Nogi Y., Hirayama H., Nealson K.H., Horikoshi K. Marinobacter alkaliphilus sp. nov., a novel alkaliphilic bacterium isolated from subseafloor alkaline serpentine mud from Ocean Drilling Program Site 1200 at South Chamorro Seamount, Mariana Forearc. Extremophiles 2005, 9:17-27.
75. Toft P.B., Arkani-Hamed J., Haggerty S.E. The effects of serpentinization on density and magnetic susceptibility: a petrophysical model. Physics of the Earth and Planetary Interiors 1990, 65:137-157.
76. Wetzel L.R., Shock E.L. Distinguishing ultramafic- from basalt-hosted submarine hydrothermal systems by comparing calculated vent fluid compositions. Journal of Geophysical Research 2000, 105:8319-8340.
77. Wicks F.J., Whittaker E.J.W. A reappraisal of the structures of the serpentine minerals. The Canadian Mineralogist 1975, 13:227-243.
78. Wicks F.J., Whittaker E.J.W. Serpentinite textures and serpentinization. The Canadian Mineralogist 1977, 15:459-488.
79. Wolery T.J. EQ3/6, A Software Package for Geochemical Modeling of Aqueous Systems: Package Overview and Installation Guide (Version 7.0) 1992, Lawrence Livermore National Laboratory, Livermore, Ca.
80. Wolery T.J. EQ3NR, A Computer Program for Geochemical Aqueous Speciation-Solubility Calculations: Theoretical Manual, User's Guide, and Related Documentation (Version 7.0) 1992, Lawrence Livermore National Laboratory.
81. Wolery T.J., Daveler S.A. EQ6, A Computer Program for Reaction Path Modelling of Aqueous Geochemical Systems: Theoretical Manual, User's Guide, and Related Documents 1992, Lawrence Livermore National Lab.
82. Wolery T.J., Jove-Colon C.F. Qualification of Thermodynamic Data for Geochemical Modeling of Mineral-Water Interactions in Dilute Systems 2004.