Hydrocarbons in Hydrothermal Vent Fluids: The Role of Chromium-Bearing Catalysts

Science

Volumn 304, Issue 5673, 2004, Pages 1002-1005

  Foustoukos, Dionysis I ^a   Seyfried Jr , William E ^a  

^a UNIVERSITY OF MINNESOTA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; CHROMIUM; FISCHER-TROPSCH SYNTHESIS; HYDROCARBONS; HYDROTHERMAL SYNTHESIS; METHANE; ROCKS; VENTS;

HYDROTHERMAL FLUIDS; MICROBIAL COMMUNITIES;

FLUID MECHANICS;

CHROMIUM; ETHANE; HYDROCARBON; IRON; METHANE; MINERAL; PROPANE; WATER; CARBON DIOXIDE; CHROMIC OXIDE; CHROMIUM DERIVATIVE; FERRIC ION; FERRIC OXIDE; HYDROGEN;

CATALYSIS; CHROMIUM; HYDROCARBON; HYDROTHERMAL FLUID; HYDROTHERMAL VENT;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL COMPOSITION; CHEMICAL INTERACTION; CHEMICAL REACTION; DEEP SEA; FISCHER TROPSCH SYNTHESIS; GEOLOGY; HYDROTHERMAL VENT; LIQUID; MICROFLORA; PRIORITY JOURNAL; REACTION ANALYSIS; ROCK; TEMPERATURE DEPENDENCE; ARCHAEBACTERIUM; BACTERIUM; CHEMISTRY; ECOSYSTEM; ENVIRONMENT; GROWTH, DEVELOPMENT AND AGING; MICROBIOLOGY; PH; PRESSURE; SEDIMENT; SYNTHESIS; TEMPERATURE;

ARCHAEA; BACTERIA; CARBON DIOXIDE; CATALYSIS; CHROMIUM; CHROMIUM COMPOUNDS; ECOSYSTEM; ENVIRONMENT; ETHANE; FERRIC COMPOUNDS; GEOLOGIC SEDIMENTS; HYDROCARBONS; HYDROGEN; HYDROGEN-ION CONCENTRATION; METHANE; PRESSURE; PROPANE; TEMPERATURE;

EID: 2342561890     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1096033     Document Type: Article

References (34)

1. J. L. Charlou et al., Chem. Geol. 171, 49 (2000).
2. J. L. Charlou, J. P. Donval, Y. Fouquet, P. Jean-Baptiste, N. Holm, Chem. Geol. 191, 345 (2002).
3. M. E. Berndt, D. E. Allen, W. E. Seyfried Jr, Geology 24, 351 (1996).
4. T. M. McCollom, J. S. Seewald, Geochim. Cosmochim. Acta 65, 3769 (2001).
5. T. M. McCollom, J. S. Seewald, Geochim. Cosmochim. Acta 67, 3625 (2003).
6. J. Horita, M. E. Berndt, Science 285, 1055 (1990).
7. N. G. Holm, J. L. Charlou, Earth Planet. Sci. Lett. 191, 1 (2001).
8. P. G. Coleman, Minerals and Rocks, Vol. 12: Ophlolites. Ancient Oceanic Lithosphere (Springer-Verlag, Berlin, 1977).
9. E. Bonatti, P. P. Hamlyn, In The Sea, Vol. 7, The Oceanic Lithosphere, C. Emiliani, Ed. (Wiley-Interscience, New York, 1981), pp. 241-283.
10. P. A. Rona, L. Widenfalk, K. Bostroem, J. Geophys. Res. 92, 1417 (1987).
11. B. Orberger, N. Metrich, M. Mosbah, C. Mevel, Y. Fouquet, Nucl. Instrum. Methods B 158, 575 (1999).
12. M. Cannat, D. Bideau, H. Boughriet, Earth Planet. Sci. Lett. 109, 87 (1992).
13. D. E. Allen, W. E. Seyfried Jr., Geochim. Cosmochim. Acta 67, 1531 (2003).
14. W. E. Seyfried Jr., D. R. Janecky, M. E. Berndt, in Hydrothermal Experimental Techniques, H. Barnes, G. Ulmer, Eds. (Wiley-Interscience, New York, 1987). vol. 9. pp. 216-239.
15. K. Ding, W. E. Seyfried Jr., Geochim. Cosmochim. Acta 56, 3681 (1992).
16. Q. Fu. W. E. Seyfried Jr., J. Horita, paper presented at the 11th International Symposium on Water-Rock Interaction, Saratoga Springs, NY, 27 June 2004.
17. R. A. Roble, B. S. Hemingway, U.S. Geol. Surv. Bull. 2131, 462 (1995).
18. See supporting data on Science Online.
19. 2aq.
20. S. Novak, R. J. Madon, Ind. Eng. Chem. Fundam. 23, 274 (1984).
21. 12C pool, respectively; and i varies from 0 to n.
22. R. C. Brady III, R. Pettit, J. Am. Chem. Soc. 102, 6181 (1980).
23. T. M. McCollom, J. S. Seewald, Geochim. Cosmochim. Acta 67, 3645 (2003).
24. J. S. Seewald, Geochim. Cosmochim. Acta 65, 1641 (2001).
25. R. F. Dias, thesis, Pennsylvania State University (2000).
26. R. F. Dias, K. H. Freeman, M. D. Lewan, S. G. Franks, Geochim. Cosmochim. Acta 66, 2755 (2002).
27. J. S. Seewald, personal communication.
28. B. M. Weckhuysen, I. E. Wachs, R. A. Schoonheydt, Chem. Rev. 96, 3327 (1996).
29. R. L. Burwell Jr., G. L. Haller, K. C. Taylor, J. F. Read, Adv. Catal. 20, 1 (1969).
30. R. Sugisaki, K. Mimura, Geochim. Cosmochim. Acta 58, 2527 (1994).
31. D. S. Kelley et al., Nature 412, 145 (2001).
32. J. J. Brocks, R. Buick, R. E. Summons, G. A. Logan, Geochim. Cosmochim. Acta 67, 4321 (2003).
33. S. Stein, A. Levitsky, O. Fateev, G. Mallard, The NIST Mass Spectral Search Program for the NIST/EPA/ NIH Mass Spectral Library (National Institute of Standards and Technology, Washington, DC, 1998).
34. We thank M. Berndt, D. Allen, and J. Horita for constructive discussions and R. Knurr for analytical support. Supported by NSF grants 9818908 and 9911471.