A radical cascade cyclization to prepare dihydrothiophenes induced by thiyl radicals as sulfur biradical equivalents

Journal of Organic Chemistry

Volumn 78, Issue 16, 2013, Pages 7816-7822

  Kamimura, Akio ^a   Miyazaki, Koichiro ^a   Yamane, Yu ^a   Yo, Ryuichiro ^a   Ishikawa, Shingo ^a   Uno, Hidemitsu ^b   Sumimoto, Michinori ^c  

^a YAMAGUCHI UNIVERSITY GRADUATE SCHOOL OF MEDICINE   (Japan)

^b EHIME UNIVERSITY   (Japan)

^c YAMAGUCHI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CASCADE CYCLIZATION; DONOR UNITS; PHOTO-IRRADIATION; RADICAL ATTACKS; REACTION UNDER; SULFUR ATOMS; SYNTHETIC EQUIVALENTS; THIYL RADICALS;

CYCLIZATION;

SULFUR;

DIHYDROTHIOPHENE; RADICAL; SULFUR; TERT BUTYL 3 [(METHYLTHIO)METHYL] 4 [(METHYLTHIO)METHYLENE] 2 PHENYL 1 TOSYLPYRROLIDINE 3 CARBOXYLATE; TERT BUTYL 6 (O TOLYL) 5 TOSYL 4,5,6,6A TETRAHYDRO 1H THIENO[3,4 C]PYRROLE 6A CARBOXYLATE; TERT BUTYL 6 PHENYL 5 TOSYL 4,5,6,6A TETRAHYDRO 1H THIENO[3,4 C]PYRROLE 6A CARBOXYLATE; TERT BUTYL 6 PROPYL 5 TOSYL 4,5,6,6A TETRAHYDRO 1H THIENO[3,4 C]PYRROLE 6A CARBOXYLATE; THIOL DERIVATIVE; THIOPHENE DERIVATIVE; THIYL RADICAL; UNCLASSIFIED DRUG; VINYL DERIVATIVE; VINYLSULFIDE;

ARTICLE; CHIRALITY; CIS ISOMER; CYCLIZATION; DIASTEREOISOMER; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; NUCLEAR OVERHAUSER EFFECT; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REACTION TIME; ROOM TEMPERATURE; STEREOCHEMISTRY; SYNTHESIS; TRANS ISOMER; ULTRAVIOLET IRRADIATION; X RAY CRYSTALLOGRAPHY;

CYCLIZATION; FREE RADICALS; MOLECULAR STRUCTURE; SULFUR; THIOPHENES;

EID: 84882427938     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo400975t     Document Type: Article

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