Synergistic effect between a novel char forming agent and ammonium polyphosphate on flame retardancy and thermal properties of polypropylene

Industrial and Engineering Chemistry Research

Volumn 52, Issue 32, 2013, Pages 10905-10915

  Tian, Nana ^a   Wen, Xin ^a   Jiang, Zhiwei ^a,b   Gong, Jiang ^a,b   Wang, Yanhui ^a   Xue, Jian ^a   Tang, Tao ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIUM POLYPHOSPHATES; APPARENT ACTIVATION ENERGY; FLAME RETARDANCY; FLAME RETARDANT PROPERTIES; KISSINGER METHODS; LIMITING OXYGEN INDEX; SYNERGISTIC EFFECT; THERMAL DEGRADATION KINETICS;

DEGRADATION; FLAME RETARDANTS; POLYMER BLENDS;

POLYPROPYLENES;

EID: 84882350155     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie401058u     Document Type: Article

References (42)

1. Uotila, R.; Hippi, U.; Paavola, S.; Seppala, J. Compatibilization of PP/elastomer/microsilica composites with functionalized polyolefins: effect on microstructure and mechanical properties Polymer 2005, 46, 7923
2. Phan, V. T.; Choqueuse, D.; Cognard, J. Y.; Sohier, L. Experimental analysis and modelling of the long term thermo-mechanical behaviour of glass/polypropylene syntactic used on thermally insulated offshore pipeline Prog. Org. Coat. 2013, 76, 341
3. Li, Q.; Jiang, P.; Su, Z.; Wei, P.; Wang, G.; Tang, X. Synergistic effect of phosphorus, nitrogen, and silicon on flame-retardant properties and char yield in polypropylene J. Appl. Polym. Sci. 2005, 96, 854
4. Yu, H. O.; Jiang, Z. W.; Gilman, J. W.; Kashiwagi, T.; Liu, J.; Song, R. J.; Tang, T. Promoting carbonization of polypropylene during combustion through synergistic catalysis of a trace of halogenated compounds and Ni2O3 for improving flame retardancy Polymer 2009, 50, 6252
5. Montezin, F.; Cuesta, J. M. L.; Crespy, A.; Georlette, P. Flame retardant and mechanical properties of a copolymer PP/PE containing brominated compounds/antimony trioxide blends and magnesium hydroxide or talc Fire Mater. 1997, 21, 245
6. Toure, B.; Cuesta, J. M. L.; Gaudon, P.; Benhassaine, A.; Crespy, A. Fire resistance and mechanical properties of a huntite/hydromagnesite/ antimonytrioxide/decabromodiphenyl oxide filled PP-PE copolymer Polym. Degrad. Stab. 1996, 53, 371
7. Gardelle, B.; Duquesne, S.; Rerat, V.; Bourbigot, S. Thermal degradation and fire performance of intumescent silicone-based coatings Polym. Adv. Technol. 2013, 24, 62
8. Chen, M. J.; Shao, Z. B.; Wang, X. L.; Chen, L.; Wang, Y. Z. Halogen-free flame-retardant flexible polyurethane foam with a novel nitrogen-phosphorus flame retardant Ind. Eng. Chem. Res. 2012, 51, 9769
9. Liu, Y.; Yi, J. S.; Cai, X. F. Application of a novel halogen-free intumescent flame retardant for acrylonitrile-butadiene-styrene J. Appl. Polym. Sci. 2012, 124, 1475
10. Liu, Y.; Wang, J. S.; Deng, C. L.; Wang, D. Y.; Song, Y. P.; Wang, Y. Z. The synergistic flame-retardant effect of OMMT on theintumescent flame-retardant PP/CA/APP systems Polym. Adv. Technol. 2010, 21, 789
11. Zuo, J. D.; Su, Y. K.; Liu, S. M.; Sheng, Q. Preparation and properties of FR-PP with phosphorus-containing intumescent flame retardant J. Polym. Res. 2011, 18, 1125
12. Cao, K.; Wu, S. L.; Wang, K. L.; Yao, Z. Kinetic study on surface modification of ammonium polyphosphate with melamine Ind. Eng. Chem. Res. 2011, 50, 8402
13. Camino, G.; Costa, L.; Martinasso, G. Intumescent fire-retardant systems Polym. Degrad. Stab. 1989, 23, 359
14. Wang, J.; Cai, X. F. Synergistic effect of a novel charring agent with ammonium polyphosphate on flame retardancy and thermal degradation of acrylonitrile-butadiene-styrene copolymer Polym. Int. 2012, 61, 703
15. Li, J.; Ke, C. H.; Xu, L.; Wang, Y. Z. Synergistic effect between a hyperbranched charring agent and ammonium polyphosphate on the intumescent flame retardance of acrylonitrile-butadiene-styrene polymer Polym. Degrad. Stab. 2012, 97, 1107
16. Feng, C. M.; Zhang, Y.; Liu, S. W.; Chi, Z. G.; Xu, J. R. Synthesis of novel triazine charring agent and its effect in intumescent flame-retardant polypropylene J. Appl. Polym. Sci. 2012, 123, 3208
17. Song, P. G.; Fang, Z. P.; Tong, L. F.; Xu, Z. B. Synthesis of a novel oligomeric intumescent flame retardant and its application in polypropylene Polym. Eng. Sci. 2009, 49, 1326
18. Chen, L.; Wang, Y. Z. A review on flame retardant technology in China. Part I: Development of flame retardants Polym. Adv. Technol. 2010, 21, 1
19. Li, X.; Ou, Y. X.; Shi, Y. S. Combustion behavior and thermal degradation properties of epoxy resins with a curing agent containing a caged bicyclic phosphate Polym. Degrad. Stab. 2002, 77, 383
20. Liu, W.; Chen, D. Q.; Wang, Y. Z.; Wang, D. Y.; Qu, M. H. Char-forming mechanism of a novel polymeric flame retardant with char agent Polym. Degrad. Stab. 2007, 92, 1046
21. Chen, G. H.; Yang, B.; Wang, Y. Z. A novel flame retardant of spirocyclic pentaerythritol bisphosphorate for epoxy resins J. Appl. Polym. Sci. 2006, 102, 4978
22. Ma, H. Y.; Tong, L. F.; Xu, Z. B.; Fang, Z. P.; Jin, Y. M.; Lu, F. Z. A novel intumescent flame retardant: synthesis and application in ABS copolymer Polym. Degrad. Stab. 2007, 92, 720
23. Chen, J.; Liu, S. M.; Zhao, J, Q. Synthesis, application and flame retardancy mechanism of a novel flame retardant containing silicon and caged bicyclic phosphate for polyamide 6 Polym. Degrad. Stab. 2011, 96, 1508
24. Peng, H. Q.; Zhou, Q.; Wang, D. Y.; Chen, L.; Wang, Y. Z. A novel charring agent containing caged bicyclic phosphate and its application in intumescent flame retardant polypropylene systems J. Ind. Eng. Chem. 2008, 14, 589
25. Zhang, L. L.; An, H.; Zeng, X. R. Flame-Retardant Epoxy Resin from a Caged Bicyclic Phosphate Quadridentate Silicon Complex J. Appl. Polym. Sci. 2009, 111, 168
26. Tian, N. N.; Wen, X.; Gong, J.; Ma, L.; Xue, J.; Tang, T. Synthesis and characterization of a novel organophosphorus flame retardant and its application in polypropylene Polym. Adv. Technol. 2013, 24, 653
27. Vannier, A.; Duquesne, S.; Bourbigot, S.; Castrovinci, A.; Camino, G.; Delobel, R. The use of POSS as synergist in intumescent recycled poly(ethylene terephthalate) Polym. Degrad. Stab. 2008, 93, 818
28. Huang, J. Q.; Zhang, Y. Q.; Yang, Q.; Liao, X.; Li, G. G. Synthesis and characterization of a novel charring agent and its application in intumescent flame retardant polypropylene system J. Appl. Polym. Sci. 2010, 123, 1636
29. Bourbigot, S.; Le, B. M.; Duquesne, S.; Rochery, M. Recent advances for intumescent polymers Macromol. Mater. Eng. 2004, 289, 499
30. Zhou, S.; Song, L.; Wang, Z. Z.; Hu, Y.; Xing, W. Y. Flame retardation and char formation mechanism of intumescent flame retarded polypropylene composites containing melamine phosphate and pentaerythritol phosphate Polym. Degrad. Stab. 2008, 93, 1799
31. Wang, Z. Z.; Lv, P.; Hu, Y.; Hu, K. L. Thermal degradation study of intumescent flame retardants by TG and FTIR: melamine phosphate and its mixture with pentaerythritol J. Anal. Appl. Pyrolysis 2009, 86, 207
32. Balabanovich, A. I. Thermal decomposition study of intumescent additives: pentaerythritol phosphate and its blend with melamine phosphate Thermochim. Acta 2005, 435, 188
33. Wang, X.; Hu, Y.; Song, L.; Xing, W. Y.; Lu, H. D.; Lv, P.; Jie, G. X. Flame retardancy and thermal degradation mechanism of epoxy resin composites based on a DOPO substituted organophosphorus oligomer Polymer 2010, 51, 2435
34. Jiang, W. Z.; Hao, J. W.; Han, Z. D. Study on the thermal degradation of mixtures of ammonium polyphosphate and a novel caged bicyclic phosphate and their flame retardant effect in polypropylene Polym. Degrad. Stab. 2012, 97, 632
35. Lewin, M. Synergistic and catalytic effects in flame retardancy of polymeric materials-an overview J. Fire Sci. 1999, 17, 3
36. Lewin, M.; Endo, M. Intumescent systems for flame retarding of polypropylene. Fire and Polymers II; Nelson, G. L., Ed.; ACS Symposium Series 599; American Chemical Society: Washington, DC, 1995; p 91.
37. Chen, Y. H.; Liu, Y.; Wang, Q.; Yin, H.; Aelmans, N.; Kierkels, R. Performance of intumescent flame retardant master batch synthesized through twin-screw reactively extruding technology: effect of component ratio Polym. Degrad. Stab. 2003, 81, 215
38. Kissinger, H. E. Reaction kinetics in differential thermal analysis Anal. Chem. 1957, 29, 1702
39. Flynn, J. H.; Wall, L. A. General treatment of thermogravimetry of polymers J. Res. Natl. Bur. Stand., Sect. A 1966, 70, 487
40. Friedman, H. L. Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to phenolic plastic J. Polym. Sci., Part C 1964, 6, 183
41. Coats, A. W.; Redfern, J. P. Kinetic parameters from thermogravimetric data Nature 1964, 201, 68
42. Chen, X. L.; Yu, J.; Guo, S. Y.; Luo, Z.; He, M. Flammability and thermal oxidative degradation kinetics of magnesium hydroxide and expandable graphite flame retarded polypropylene composites J. Macromol. Sci., Part A: Pure Appl. Chem. 2008, 45, 712