Synthesis, application and flame retardancy mechanism of a novel flame retardant containing silicon and caged bicyclic phosphate for polyamide 6

Polymer Degradation and Stability

Volumn 96, Issue 8, 2011, Pages 1508-1515

  Chen, Jun ^a   Liu, Shumei ^a   Zhao, Jianqing ^a  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Application; Flame retardancy; Mechanism; Phosphorus; Silicon; Synthesis

Indexed keywords

BARRIER EFFECTS; CONDENSED PHASE; CONE CALORIMETER; DECOMPOSITION PATHWAY; EXTERNAL HEAT FLUX; FLAME RETARDANCY; FTIR; FTIR ANALYSIS; FUEL REDUCTION; HIGH TEMPERATURE; HIGH TOUGHNESS; PHOSPHATE GROUP; POLYAMIDE 6; SEM-EDX; SMOKE RELEASE; SMOKE SUPPRESSION; TG-FT-IR;

FLAME RETARDANTS; METHANOL; PHOSPHORUS;

FLAME SYNTHESIS;

EID: 79959721123     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2011.05.002     Document Type: Article

References (33)

1. nd ed. 1990 Hanser Munchen, Germany
2. F. Laoutid, L. Bonnaud, and M. Alexandre New prospects in flame retardant polymer materials: from fundamentals to nanocomposites Materials Science and Engineering R 63 2009 100 125
3. S.Y. Lu, and I. Hamerton Recent developments in the chemistry of halogen-free flameretardant polymers Progress in Polymer Science 27 2002 1661 1712 (Pubitemid 34811634)
4. I. Ravadits, A. Toth, G. Marosi, A. Marton, and A. Szep Organosilicon surface layer on polyolefins to achieve improved flame retardancy through an oxygen barrier effect Polymer Degradation and Stability 74 3 2001 419 422 (Pubitemid 33050927)
5. Masatoshi Iji, and S. Serizawa Silicone derivatives as new flame retardants for aromatic thermoplastics used in electronic devices Polymers for Advanced Technologies 9 1998 593 600
6. W.J. Wang, L.H. Perng, G.H. Hsiue, and F.C. Chang Characterization and properties of new silicone-containing epoxy resin Polymer 41 16 2000 6113 6122 (Pubitemid 30316231)
7. C.S. Wu, Y.L. Liu, and Y.S. Chiu Epoxy resins possessing flame retardant elements from silicon incorporated epoxy compounds cured with phosphorus or nitrogen containing curing agents Polymer 41 15 2002 4277 4284 (Pubitemid 34591911)
8. S. Zhang, and A.R. Horrocks A review of flame retardant polypropylene fibres Progress in Polymer Science 28 2003 1517 1538
9. Q. Li, P.K. Jiang, and P. Wei Synthesis, characteristic, and application of new flame retardant containing phosphorus, nitrogen, and silicon Polymer Engineering and Science 46 3 2006 344 350
10. M. Lewin, and E.D. Weil Mechanism and modes of action in flame retardancy of polymers A.R. Horrocks, D. Price, Fire retardant materials 2001 Woodhead Publishing Cambridge 31 68
11. U. Braun, B. Schartel, M.A. Fichera, and C. Jäger Flame retardancy mechanisms of aluminium phosphinate in combination with melamine polyphosphate and zinc borate in glass-fibre reinforced polyamide 6,6 Polymer Degradation and Stability 92 8 2007 1528 1545 (Pubitemid 47176673)
12. B. Schartel, R. Kunze, and D. Neubert Red phosphorus-controlled decomposition for fire retardant PA 66 Journal of Applied Polymer Science 83 10 2002 2060 2071 (Pubitemid 34125043)
13. M. Le Bras, M. Bugajny, J. Lefebvre, and S. Bourbigot Use of polyurethanes as char-forming agents in polypropylene intumescent formulations Polymer International 49 10 2000 1115 1124
14. Q. Li, P.K. Jiang, and P. Wei Thermal degradation behavior of poly(propylene) with a novel silicon-containing intumescent flame retardant Macromolecular Materials and Engineering 290 2005 912 919 (Pubitemid 41352654)
15. F. Xie, Y.Z. Wang, B. Yang, and Y. Liu A novel intumescent flame-retardant polyethylene system Macromolecular Materials and Engineering 291 2006 247 253 (Pubitemid 44933219)
16. US Patent 4341694, 1982.
17. US Patent 4480093, 1984.
18. W.A. David, C.A. Edwyn, B. Christopher, and E.S. Leslie Fire-retardant polymers. Polymerisation of 1-oxo-2,6,7-trioxa-1-phosphabicyclo[2,2,2]oct-4- ylmethyl methacrylate, and its copolymerisation with methyl methacrylate, styrene, and triallylcyanurate Polymer Degradation and Stability 47 1995 67 72
19. X. Li, Y.X. Ou, and Y.S. Shi Combustion behavior and thermal degradation properties of epoxy resins with a curing agent containing a caged bicyclic phosphate Polymer Degradation and Stability 77 2002 383 390 (Pubitemid 35382191)
20. H.Q. Peng, Q. Zhou, D.Y. Wang, L. Chen, and Y.Z. Wang A novel charring agent containing caged bicyclic phosphate and its application in intumescent flame retardant polypropylene systems Journal of Industrial and Engineering Chemistry 14 2008 589 595
21. Y. Zhang, K.L. Cheng, and J.R. Xu Thermal stability studies of polyamides and their block copolymers Thermochimica Acta 425 2005 137 141 (Pubitemid 40082680)
22. P. Gijsman, R. Steenbakkers, C. Fürst, and J. Kersjes Differences in the flame retardant mechanism of melamine cyanurate in polyamide 6 and polyamide 66 Polymer Degradation and Stability 78 2002 219 224
23. K.P. Pramoda, T.X. Liu, Z.H. Liu, C.B. He, and H.J. Sue Thermal degradation behavior of polyamide 6/clay nanocomposites Polymer Degradation and Stability 81 2003 47 56
24. B.J. Holland, and J.N. Hay Thermal degradation of nylon polymers Polymer International 49 2000 943
25. P.R. Hornsby, J. Wang, R. Rothon, G. Jackson, G. Wilkinson, and K. Cossick Thermal decomposition behaviour of polyamide fire-retardant compositions containing magnesium hydroxide filler Polymer Degradation and Stability 51 1996 235 249 (Pubitemid 126340860)
26. V. Babushok, and W. Tsang Inhibitor rankings for alkane combustion Combustion and Flame 123 2004 488 506 (Pubitemid 32449954)
27. K.H. Pawlowski, and B. Schartel Flame retardancy mechanisms of aryl phosphates in combination with boehmite in bisphenol A polycarbonate/ acrylonitrile-butadiene-styrene blends Polymer Degradation and Stability 93 1 2008 657 667
28. D.C.O. Marney, L.J. Russell, D.Y. Wu, T. Nguyen, D. Cramm, and N. Rigopoulos The suitability of halloysite nanotubes as a fire retardant for nylon 6 Polymer Degradation and Stability 93 10 2008 1971 1978
29. S. Bourbigot, S. Duquesne, and C. Jama Polymer nanocomposites: how to reach low flammability? Macromolecular Symposia 133 2006 180 190
30. U. Braun, A.I. Balabanovich, B. Schartel, U. Knoll, J. Artner, and M. Ciesielski Influence of the oxidation state of phosphorus on the decomposition and fire behaviour of flame-retarded epoxy resin composites Polymer 47 2006 8495 8508 (Pubitemid 44821259)
31. B. Schartel, and U. Braun Fire retardancy mechanisms of phosphorus in thermoplastics vol. 228 2004 228th National Meeting of the American-Chemical- Society427
32. K.H. Pawlowski, and B. Schartel Flame retardancy mechanisms of triphenyl phosphate, resorcinol bis(diphenyl phosphate) and bisphenol A bis(diphenylphosphate) in polycarbonate/acrylonitrile-butadiene-styrene blends Polymer International 56 2007 1404 1414 (Pubitemid 47593188)
33. U. Braun, and B. Schartel Flame retardant mechanisms of red phosphorus and magnesium hydroxide in high impact polystyrene Macromolecular Chemistry and Physics 205 2004 2185 2196