Theoretical Descriptions of Spin-Transitions in Bulk Lattices

Spin-Crossover Materials: Properties and Applications

Volumn , Issue , 2013, Pages 455-474

  Enachescu, Cristian ^a   Nishino, Masamichi ^b   Miyashita, Seiji ^c,d  

^a ALEXANDRU IOAN CUZA UNIVERSITY OF IASI   (Romania)

^b NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

^c UNIVERSITY OF TOKYO   (Japan)

^d JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Bulk lattice; Elastic interaction models; Mechano elastic model; Molecular dynamic (MD) approach; Monte Carlo approach; Nanoparticles; Spin crossover (SC) systems; Spin transition

Indexed keywords

EID: 84880833670     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9781118519301.ch18     Document Type: Chapter

References (64)

1. Kahn, O., Martinez, C. J. (1998) Spin-transition polymers: From molecular materials toward memory devices. Science, 279: 44-48.
2. Létard, J.-F., Guionneau, P., Goux-Capes, L. (2004) Towards spin crossover applications, in: Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds III. Top. Curr. Chem., 235: 221-249.
3. Matsuda, T., Isozaki, H.,Tajima, H. (2008) Reproducible on-off switching of the light emission from the electroluminescent device containing a spin crossover complex. Thin Solid Films, 517: 1465-1467.
4. 2 spin-crossover system. Chem. Phys. Lett., 192: 65-70.
5. Gütlich, P., Hauser, A., Spiering, H. (1994) Thermal and optical switching of iron(II) complexes. Angew. Chem. Int. Ed., 33: 2024-2054.
6. 4)2 spin-crossover system-part two: hysteresis in the LIESST regime. Chem. Eur. J., 2: 1435-1439.
7. Desaix, A., Roubeau, O., Jeftic, J., Haasnoot, J. G., Boukheddaden, K., Codjovi, E., Linares, J., Nogues, M., Varret, F. (1998) Light-induced bistability in spin transition solids leading to thermal and optical hysteresis. Eur. Phys. J. B, 6: 183-193.
8. Varret, F., Boukheddaden, K., Codjovi, E., Enachescu, C., Linarès, J. (2004) On the competition between relaxation and photoexcitations in spin crossover solids under continuous irradiation, in: Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds II. Top. Curr. Chem., 234: 199-229.
9. + complexes. J. Phys. Coll. (France), Cl-91-Cl-92.
10. Boukheddaden, K., Shteto, I., Ĥoo, B., Varret, F. (2000) Dynamical model for spin-crossover solids. I. Relaxation effects in the mean-field approach. Phys. Rev. B, 62: 14796-14805.
11. Ĥoo, B., Boukheddaden, K., Varret, F. (2000) Two-variable macroscopic model for spin-crossover solids: Static and dynamic effects of the correlations. Eur. Phys. J. B, 17: 449-457.
12. Miyashita, S., Honishi, Y., Tokoro, H., Nishino, M., Boukheddaden, K., Varret, F. (2005) Structures of metastable states in phase transitions with a high-spin low-spin degree of freedom. Prog. Theor. Phys., 114: 719-735.
13. Bousseksou, A., Nasser, J., Linares, J., Boukheddaden, K., Varret, F. (1992) Ising-like model for the two-step spin-crossover. J. Phys. 1 (France), 2: 1381-1403.
14. 3]Cl2·EtOH. Z. Phys. B, 102: 455-459.
15. Varret, F., Salunke, S. A., Boukheddaden, K., Bousseksou, A., Codjovi, E., Enachescu, C., Linares, J. (2003) The Ising-like model applied to switchable inorganic solids: discussion of the static properties. C. R. Chimie, 6: 385-393.
16. Nishino, M., Boukheddaden, K., Miyashita, S., Varret, F. (2003) Arrhenius Monte Carlo study of two-step spin crossover: equilibrium and relaxation paths. Phys. Rev. B, 68: 224402/1-224402/10.
17. Spiering, H., Meissner, E., Köppen, H., Müller, E. W., Gütlich, P. (1982) The effect of the lattice expansion on high spin⇌ low spin transitions. Chem. Phys., 68: 65-71.
18. Spiering, H., Willenbacher, N. (1989) Elastic interaction of high-spin and low-spin complex molecules in spincrossover compounds. II. J. Phys. Condens. Matter, 1: 10089-10105.
19. Spiering, H. (2004) Elastic interaction in spin crossover compounds, in: Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds III. Top. Curr. Chem., 235: 171-195.
20. Onishi, S., Sugano, S. (1981) Strain interaction effects on the high-spin-low-spin transition of transition-metal compounds. J. Phys. C, 14: 39-55.
21. 2bpym, with bt = 2,2⇌-bi-2-thiazoline and bpym = 2,2⇌-bipyrimidine: experimental investigation and theoretical approach. J. Am. Chem. Soc., 114: 4650-4658.
22. 2O. Phys. Rev. B, 73: 172415/1-172415/4.
23. Letard, J.-F. (2006) Photomagnetism of iron(II) spin crossover complexes-the T(LIESST) approach. J. Mater. Chem., 16: 2550-2559.
24. Tokoro, H., Ohkoshi, S. (2008) Phase collapse caused by blue-light irradiation in a cyanobridged coordination polymer. Appl. Phys. Lett., 93: 021906/1-021906/3.
25. Muraoka, A., Boukheddaden, K., Linarès, J., Varret, F. (2011) Two-dimensional Ising-like model with specific edge effects for spin-crossover nanoparticles: A Monte Carlo study. Phys. Rev. B, 84: 054119/1-054119/7.
26. Dobrinescu, A., Enachescu, C., Stancu, A. (2009) Ising-like model study of size dependence relaxation in spin crossover complexes. J. Magn. Magn. Mater., 321: 4132-4138.
27. Atitoaie, A., Enachescu, C., Tanasa, R. (2012) Size dependent thermal hysteresis in spin crossover nanoparticles reflected within a Monte Carlo based Ising-like model. J. Magn. Magn. Mater., 324: 1596-1600.
28. Slichter, C. P., Drickamer, H. G. (1972) Pressure-induced electronic changes in compounds of iron. J. Chem. Phys., 56: 2142-2160.
29. 2: II. Structural properties and calculation of the elastic interaction. Z. Phys. B, 100: 523-534.
30. Kambara, T. (1981) Theory of high-spin⇌low-spin transitions in transition metal compounds induced by cooperative molecular distortions and lattice strains. J. Chem. Phys., 74: 4557-4565.
31. Nasser, J. A., Topcç, S., Chassagne, L., Wakim, M., Bennali, B., Linares, J., Alayli, Y. (2011) Two-dimensional atom-phonon coupling model for spin conversion: role of metastable states. Eur. Phys. J. B, 83: 115-132.
32. Nishino, M., Boukheddaden, K., Konishi, Y., Miyashita, S. (2007) Simple two-dimensional model for the elastic origin of cooperativity among spin states of spin-crossover complexes. Phys. Rev. Lett., 98: 247203/1-247203/4.
33. Miyashita, S., Konishi, Y., Nishino, M., Tokoro, H., Rikvold, P. A. (2008) Realization of the mean-field universality class in spin-crossover materials. Phys. Rev. B, 77: 014105/1-014105/12.
34. Konishi, Y., Tokoro, H., Nishino, M., Miyashita, S. (2008) Monte Carlo simulation of pressure-induced phase transitions in spin-crossover materials. Phys. Rev. Lett., 100: 067206/1-067206/4.
35. Stoleriu, L., Enachecsu, C., Stancu, A., Hauser, A. (2008) Elastic model for complex hysteretic processes in molecular magnets. IEEE Trans. Magn., 44: 3052-3055.
36. Nicolazzi, W., Pillet, S., Lecomte, C. (2008) Two-variable anharmonic model for spin-crossover solids: a like-spin domains interpretation. Phys. Rev. B, 78: 174401/1-174401/12.
37. Nishino, M., Boukheddaden, K., Miyashita, S. (2009) Molecular dynamics study of thermal expansion and compression in spin-crossover solids using a microscopic model of elastic interactions. Phys. Rev. B, 79: 012409/1-012409/4.
38. Enachescu, C., Stoleriu, L., Stancu, A., Hauser, A. (2009) Model for elastic relaxation phenomena in finite 2D hexagonal molecular lattices. Phys. Rev. Lett., 102: 257204/1-257204/4.
39. Nishino, M., Enachescu, C., Miyashita, S., Boukheddaden, K., Varret, F. (2010) Intrinsic effects of the boundary condition on switching processes in effective long-range interactions originating from local structural change. Phys. Rev. B, 82: 020409/1-020409/4.
40. Enachescu, C., Stoleriu, L., Stancu, A., Hauser, A. (2010) Competition between photoexcitation and relaxation in spin-crossover complexes in the frame of a mechanoelastic model. Phys. Rev. B, 82: 104114/1-104114/8.
41. Enachescu, C., Nishino, M., Miyashita, S., Stoleriu, L., Stancu, A., Hauser, A. (2010) Cluster evolution in spin crossover systems observed in the frame of a mechano-elastic model. Europhys. Lett. 91, 27003/1-27003/6.
42. Enachescu, C., Stoleriu, L., Stancu, A., Hauser, A. (2011) Study of the relaxation in diluted spin crossover molecular magnets in the framework of the mechano-elastic model. J. Appl. Phys., 109: 07B111/1-07B111/3.
43. Nishino, M., Enachescu, C., Miyashita, S., Rikvold, P. A., Boukheddaden, K., Varret, F. (2011) Macroscopic nucleation phenomena in continuum media with long-range interactions. Sci. Rep., 1: 162/1-162/5.
44. Stoleriu, L., Chakraborty, P., Hauser, A., Stancu, A., Enachescu, C. (2011) Thermal hysteresis in spin-crossover compounds studied within the mechanoelastic model and its potential application to nanoparticles. Phys. Rev. B, 84: 134102/1-134102/9.
45. Miyashita, S., Rikvold, P. A., Mori, T., Konishi, Y., Nishino, M., Tokoro, H. (2009) Threshold phenomena under photoexcitation of spin-crossover materials with cooperativity due to elastic interactions. Phys. Rev. B, 80: 064414/1-064414/6.
46. Boukheddaden, K., Miyashita, S., Nishino, M. (2007) Elastic interaction among transition metals in one-dimensional spin-crossover solids. Phys. Rev. B, 75: 094112/1-094112/10.
47. Sakai, O., Ogawa, T., Koshino, K. (2002) Monte Carlo simulation for the photo-induced low-spin to high-spin state transitions-difference and similarity with the thermal transition. J. Phys. Soc. Jpn., 71: 978-988.
48. Sakai, O., Ishii, M., Ogawa, T., Koshino, K. (2002) Monte Carlo simulation for the macroscopic phase separation in photoinduced low-spin to high-spin state transitions. J. Phys. Soc. Jpn., 71: 2052-2060.
49. Tuchagues, J.-P., Bousseksou, A., Molnar, G., McGarvey, J. J., Varret, F. (2004) The role of molecular vibrations in the spin crossover phenomenon, in:Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds III. Top. Curr. Chem., 235: 85-103.
50. Meissner, E., Köppen, H., Spiering, H., Gütlich, P. (1983) The effect of low pressure on a high-spin-low-spin transition. Chem. Phys. Lett., 95: 163-166.
51. 2·EtOH. Inorg. Chem., 25: 1565-1571.
52. Nosé, S. (1984) A unified formulation of the constant temperature molecular dynamics methods. J. Chem. Phys., 81: 511-519.
53. Hoover, W. G. (1985) Canonical dynamics: equilibrium phase-space distributions. Phys. Rev. A, 31: 1695-1697.
54. Andersen, H. C. (1980) Molecular dynamics simulations at constant pressure and/or temperature. J. Chem. Phys., 72: 2384-2393.
55. Matsuda, T., Tokoro, H., Hashimoto, K., Ohkoshi, S. (2006) Charge-transfer phase transition and zero thermal expansion in caesium manganese hexacyanoferrates. Dalton Trans., 5046-5050.
56. Slimani, A., Varret, F., Boukheddaden, K., Chong, C., Mishra, H., Haasnoot, J., Pillet, S. (2011) Visualization and quantitative analysis of spatiotemporal behavior in a first-order thermal spin transition: a stress-driven multiscale process. Phys. Rev. B, 84: 094442/1-094442/8.
57. Enachescu, C., Nishino, M., Miyashita, S., Stancu, A., Stoleriu, L. (2012) Monte Carlo Metropolis study of cluster evolution in spin-crossover solids within the framework of a mechanoelastic model. Phys. Rev. B, 86: 054114/1-054114/7.
58. Decurtins, S., Gütlich, P., Köhler, C. P., Spiering, H., Hauser, A. (1984) Light-induced excited spin state trapping in a transition-metal complex: the hexa-1-propyltetrazole-iron (II) tetrafluoroborate spin-crossover system. Chem. Phys. Lett., 105: 1-4.
59. Buhks, E., Navon, G., Bixon, M., Jortner, J. (1980) Spin conversion processes in solutions. J. Am. Chem. Soc., 102: 2918-2923.
60. Hauser, A. (2004) Light-induced spin crossover and the high-spin→low-spin relaxation, in: Gütlich, P., Goodwin, H. A. (Eds) Spin Crossover in Transition Metal Compounds II. Top. Curr. Chem., 234: 155-198.
61. 4)2. J. Phys. Chem. B, 114: 1975-1984.
62. 4)2 single crystals explained by optical microscopy in terms of inhomogeneous stresses. Chem. Phys. Lett., 504: 29-33.
63. Englman, R. (1972) The Jahn-Teller Effect in Molecules and Crystals. Wiley-Blackwell, Oxford, UK, p. 350.
64. Porter, D. A., Easterling, K. E., Sherif, M. (2009) Phase Transformations in Metals and Alloys, 3rd edn. CRC Press, Boca Raton FL, USA, p. 520.