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See EPAPS document No. E-APPLAB-93-064827 for detailed information of Rietveld structural analysis, dielectric constant and optical resonance measured by spectroscopic ellipsometry, IR spectra before and after blue-light irradiation, and the estimation by extrapolating for the thermodynamical parameters. For more information on EPAPS, see.
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See EPAPS document No. E-APPLAB-93-064827 for detailed information of Rietveld structural analysis, dielectric constant and optical resonance measured by spectroscopic ellipsometry, IR spectra before and after blue-light irradiation, and the estimation by extrapolating for the thermodynamical parameters. For more information on EPAPS, see http://www.aip.org/pubservs/ epaps.html.
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4043059166
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Such a LIPC phenomenon from a thermodynamically metastable phase to a hidden stable phase was discovered in this work, although, in rubidium manganese hexacyanoferrates exhibiting a thermal phase transition [, 0020-1669 10.1021/ic030332f, (), Chem. Mater. 0897-4756 10.1021/cm048461x 17, 81 (2005);, Eur. J. Inorg. Chem. 1434-1948 10.1002/ejic.200601023 11, 1549 (2007)], x-ray or light-induced phase transitions (Ref.) [, Angew. Chem., Int. Ed. 1433-7851 10.1002/anie.200460603 43, 6316 (2004), Chem. Mater. 0897-4756 10.1021/cm701873s 20, 423 (2008);, Chem. Mater. 20, 1236 (2008)] have been observed.
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Such a LIPC phenomenon from a thermodynamically metastable phase to a hidden stable phase was discovered in this work, although, in rubidium manganese hexacyanoferrates exhibiting a thermal phase transition [H. Tokoro, S. Ohkoshi, T. Matsuda, and K. Hashimoto, Inorg. Chem. 0020-1669 10.1021/ic030332f 43, 5231 (2004), S. Ohkoshi, T. Matsuda, H. Tokoro, and K. Hashimoto, Chem. Mater. 0897-4756 10.1021/cm048461x 17, 81 (2005); S. Cobo, R. Fernández, L. Salmon, G. Molnár, and A. Bousseksou, Eur. J. Inorg. Chem. 1434-1948 10.1002/ejic.200601023 11, 1549 (2007)], x-ray or light-induced phase transitions (Ref.) [S. Margadonna, K. Prassides, and A. N. Fitch, Angew. Chem., Int. Ed. 1433-7851 10.1002/anie.200460603 43, 6316 (2004), H. Tokoro, T. Matsuda, T. Nuida, Y. Moritomo, K. Ohoyama, E. D. Loutete-Dangui, K. Boukheddaden, and S. Ohkoshi, Chem. Mater. 0897-4756 10.1021/cm701873s 20, 423 (2008); E. J. M. Vertelman, T. T. A. Lummem, A. Meetsma, M. V. Bouwkamp, G. Molnár, P. H. M. V. Loosdrecht, and P. J. V. Koningsbruggen, Chem. Mater. 20, 1236 (2008)] have been observed.
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