Diastereoselective syntheses of highly substituted methylenecyclopropanes via copper- or iron-catalyzed reactions of 1,2-disubstituted 3-(hydroxymethyl)cyclopropenes with grignard reagents

Synthesis (Germany)

Volumn 45, Issue 13, 2013, Pages 1807-1814

  Xie, Xiaocong ^a   Fox, Joseph M ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

cyclopropene; dianion; diastereoselective; methylenecyclopropane; substitution

Indexed keywords

ALLYLIC ETHERS; CYCLOPROPENES; DIANIONS; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE; DIASTEREOSELECTIVE SYNTHESIS; GRIGNARD REAGENT; METHYLENECYCLOPROPANES;

CATALYSIS; COPPER; IRON COMPOUNDS; METHANOL; PROPANE; SUBSTITUTION REACTIONS;

STEREOSELECTIVITY;

COPPER; CYCLOPROPANE DERIVATIVE; GRIGNARD REAGENT; IRON; METHYLENECYCLOPROPANE; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHIRALITY; CHROMATOGRAPHY; CONCENTRATION (PARAMETERS); ENANTIOSELECTIVITY; NUCLEOPHILICITY; STEREOCHEMISTRY; SUBSTITUTION REACTION;

EID: 84879499490     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0033-1338876     Document Type: Article

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