Direct site-specific and highly enantioselective γ-functionalization of linear α,β-unsaturated ketones: Bifunctional catalytic strategy

Angewandte Chemie - International Edition

Volumn 52, Issue 26, 2013, Pages 6739-6742

  Yang, Dongxu ^a   Wang, Linqing ^a   Han, Fengxia ^a   Zhao, Depeng ^a   Zhang, Bangzhi ^a   Wang, Rui ^a,b  

^a LANZHOU UNIVERSITY   (China)

^b LANZHOU INSTITUTE OF CHEMICAL PHYSICS   (China)

Author keywords

chemoselectivity; cyclization; ligand design; magnesium; synthetic methods

Indexed keywords

CHEMO-SELECTIVITY; CYCLOHEXENE RING; ENANTIOSELECTIVE; FUNCTIONALIZATIONS; LIGAND DESIGN; OPTICALLY ACTIVE; SYNTHETIC METHODS; UNSATURATED KETONES;

CYCLIZATION; FUNCTIONAL GROUPS; MAGNESIUM;

KETONES;

AMINE; HYDROGEN; KETONE; LIGAND; MAGNESIUM;

ARTICLE; CATALYSIS; CHEMISTRY; DRUG DESIGN; ENZYME SPECIFICITY; HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM;

AMINES; CATALYSIS; DRUG DESIGN; HYDROGEN; HYDROGEN BONDING; KETONES; LIGANDS; MAGNESIUM; MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

EID: 84879361484     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201301146     Document Type: Article

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