Precipitation of Magnesium Carbonates as a Function of Temperature, Solution Composition, and Presence of a Silicate Mineral Substrate

Environmental Engineering Science

Volumn 28, Issue 12, 2011, Pages 881-889

  Case, David H ^a,b   Wang, Fei ^a   Giammar, Daniel E ^a  

^a WASHINGTON UNIVERSITY IN ST LOUIS   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Carbon sequestration; Forsterite; Hydromagnesite; Magnesium carbonate; Nesquehonite

Indexed keywords

CARBON SEQUESTRATION; FORSTERITE; HYDROMAGNESITE; MAGNESIUM CARBONATE; NESQUEHONITE;

CARBON; CARBONATE MINERALS; CARBONATION; CRYSTALLOGRAPHY; INDUCTIVELY COUPLED PLASMA; INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; IONIC STRENGTH; MAGNESITE; METASTABLE PHASES; MINERALOGY; OLIVINE; SILICATES; X RAY DIFFRACTION ANALYSIS;

MAGNESIUM;

MAGNESIUM CARBONATE; MAGNESIUM HYDROXIDE; SILICATE;

AQUEOUS SOLUTION; ARTICLE; ATOMIC EMISSION SPECTROMETRY; EQUILIBRIUM CONSTANT; IONIC STRENGTH; MINERALIZATION; MINERALOGY; PRECIPITATION; SOLID; TEMPERATURE; THERMODYNAMICS; X RAY DIFFRACTION;

EID: 82555183080     PISSN: 10928758     EISSN: 15579018     Source Type: Journal    
DOI: 10.1089/ees.2010.0341     Document Type: Article

References (29)

1. 2-rich brine through peridotites. Environ. Sci. Technol. 43, 1226.
2. 2 in geological media: criteria and approach for site selection in response to climate change. Energy Convers. Manage. 41, 953.
3. Bachu, S., Gunter W.D., and Perkins, E.H. (1996). Carbon dioxide disposal. In B. Hitchon, Ed., Aquifer Disposal of Carbon Dioxide. Hydrodynamic and Mineral Trapping-Proof of Concept. Sherwood Park, Alberta, Canada: Geoscience Publishing Ltd., pp. 11-22.
4. 2 sequestration within minerals. J. Hazard. Mater. 178, 522.
5. Bender, M., and Sprague, R. (1965). The preparation and structure of magnesium carbonate trihydrate. J. Inorg. Nucl. Chem. 27, 1872.
6. 2 in deep saline aquifers. Environ. Sci. Technol. 36, 240A.
7. Davies, C.W. (1962). Ion Association. Washington, DC: Butterworths.
8. Davies, P.J., and Bubela, B. (1973). Transformation of nesquehonite into hydromagnesite. Chem. Geol. 12, 289.
9. Deelman, J.C. (2001). Breaking Ostwald's rule. Chemie. Der. Erde. Geochem. 61, 224.
10. 2 with Mg chloride solution: its potential role in the sequestration of carbon dioxide. J. Hazard. Mater. 168, 832.
11. Gerdemann, S.J., O'Connor, W.K., Dahlin, D.C., Penner, L.R., and Rush, H. (2007). Ex situ aqueous mineral carbonation. Environ. Sci. Technol. 41, 2587.
12. Giammar, D.E., Bruant, R.G., Jr., and Peters, C.A. (2005). Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide. Chem. Geol. 217, 257.
13. Goff, F., and Lackner, K.S. (1998). Carbon dioxide sequestering using ultramafic rocks. Environ. Geosci. 5, 89.
14. 2 pressure. Chem. Eng. Sci. 63, 1012.
15. IPCC. (2005). IPCC Special Report on Carbon Dioxide Capture and Storage. Cambridge, United Kingdom: Cambridge University Press.
16. Johnson, J.W., Oelkers, E.H., and Helgeson, H.C. (1992). SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bar and 0 to 1000°C. Comput. Geosci. 18, 899.
17. Kaszuba, J.P., Janecky, D.R., and Snow, M.G. (2005). Experimental evaluation of mixed fluid reactions between supercritical carbon dioxide and NaCl brine: relevance to the integrity of a geologic carbon repository. Chem. Geol. 217, 277.
18. Lide, D. (2000). CRC Handbook of Chemistry and Physics, 3rd Electronic Edition. Norwich, NY: Knovel.
19. Marini, L. (2007). Geological Sequestration of Carbon Dioxide: Thermodynamics, Kinetics, and Reaction Path Modeling. Oxford, United Kingdom: Elsevier.
20. O'Connor, W.K., Dahlin, D.C., Rush, G.E., Gerdemann, S.J., Penner, L.R., and Nilsen, H. (2005). Final Report: Aqueous Mineral Carbonation: Mineral Availability, Pretreatment, Reaction Parametrics, and Process Studies. Albany, OR: National Energy Technology Laboratory, Albany Research Center, DOE/ARCTR-04-002.
21. Pokrovsky, O.S. (1998). Precipitation of calcium and magnesium carbonates from homogeneous supersaturated solutions. J. Cryst. Growth 186, 233.
22. 2 sequestration. Chem. Geol. 260, 286.
23. 2 and salinity on olivine dissolution kinetics at 120 degrees C. Chem. Eng. Sci. 64, 3510.
24. Saldi, G.D., Jordan, G., Schott, J., and Oelkers, E.H. (2009). Magnesite growth rates as a function of temperature and saturation state. Geochim. Cosmochim. Acta 73, 5646.
25. Sayles, F.L., and Fyfe, W.S. (1973). The crystallization of magnesite from aqueous solution. Geochim. Cosmochim. Acta 37, 87.
26. Schecher, W.D., and McAvoy, D.C. (2007). MINEQL +: A Chemical Equilibrium Modeling System, Version 4.6. Hallowell, ME: Environmental Research Software.
27. Stumm, W., and Morgan, J.J. (1996). Aquatic Chemistry. New York: John Wiley & Sons, Inc.
28. 2 disposal by mineral trapping in deep aquifers. Appl. Geochem. 19, 917.
29. 2 sequestration. Environ. Sci. Technol. 44, 406.