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The reaction was not applicable to less reactive N-benzylic sulfonamides, such as N-benzyl-p-toluenesulfonamide. Furthermore, no alkenylation product was obtained from the reaction of alkene 2a with N-(2-cyclohexenyl)-p-toluenesulfonamide or N-(1-adamantyl)-p-toluenesulfonamide.
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The reaction was not applicable to less reactive N-benzylic sulfonamides, such as N-benzyl-p-toluenesulfonamide. Furthermore, no alkenylation product was obtained from the reaction of alkene 2a with N-(2-cyclohexenyl)-p-toluenesulfonamide or N-(1-adamantyl)-p-toluenesulfonamide.
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No alkenylation product was obtained from the reaction of N-benzylic sulfonamide 1a with a monosubstituted alkene, such as styrene.
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No alkenylation product was obtained from the reaction of N-benzylic sulfonamide 1a with a monosubstituted alkene, such as styrene.
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For details, see the Supporting Information. CCDC775871 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
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For details, see the Supporting Information. CCDC775871 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data%5frequest/cif.
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