Glycerol acetals as diesel additives: Kinetic study of the reaction between glycerol and acetaldehyde

Fuel Processing Technology

Volumn 116, Issue , 2013, Pages 182-188

  Agirre, I ^a   Guemez M B ^a   Ugarte, A ^a   Requies, J ^a   Barrio, V L ^a   Cambra, J F ^a   Arias, P L ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Acetaldehyde; Acetals; Amberlyst; Glycerol; Kinetics

Indexed keywords

ACETALIZATION REACTION; ACETALS; AMBERLYST; BATCH STIRRED TANK REACTORS; GLYCEROL CONCENTRATION; PROCESS PARAMETERS; REACTION CONDITIONS; RENEWABLE RESOURCE;

ENZYME KINETICS; GLYCEROL; KINETIC THEORY; KINETICS; REACTION KINETICS;

ACETALDEHYDE;

EID: 84879215039     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2013.05.014     Document Type: Article

References (30)

1. B.R. Moser, and S.Z. Erhan Branched chain derivatives of alkyl oleates: tribological, rheological, oxidation, and low temperature properties Fuel 87 2008 2253 2257
2. S.B. Umbarkar, T.V. Kotbagi, A.V. Biradar, R. Pasricha, J. Chanale, M.K. Dongare, A.S. Mamede, C. Lancelot, and E. Payen Acetalization of glycerol using mesoporous MoO3/SiO2 solid acid catalyst Journal of Molecular Catalysis A: Chemical 310 2009 150 158
3. P.H.R. Silva, V.L.C. Gonçalves, and C.J.A. Mota Glycerol acetals as anti-freezing additives for biodiesel Bioresource Technology 101 2010 6225 6229
4. H. Burtscher, U. Matter, and G. Skillas The effect of fuel additives on diesel engine particulate emissions Journal of Aerosol Science 30 1999 S851 S852
5. D. Naegeli, and L. Dodge Combustion Characterization of Methylal in Reciprocating Engines Final Report No. SwRI 03-130 1992 Southwest Research Institute San Antonio, TX
6. F. Frusteri, L. Spadaro, C. Beatrice, and C. Guido Oxygenated additives production for diesel engine emission improvement Chemical Engineering Journal 134 2007 239 245 (l)
7. M.R. Capeletti, L. Balzano, G. de la Puente, M. Laborde, and U. Sedran Synthesis of acetal (1,1-diethoxyethane) from ethanol and acetaldehyde over acidic catalysts Applied Catalysis A: General 198 2000 L1 L4
8. N. Rahmat, A.Z. Abdullah, and A.R. Mohamed Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: a critical review Renewable & Sustainable Energy Reviews 14 2010 987 1000
9. S. Yang, M. Wang, Y. Liang, and J. Sun Eco-friendly one-pot synthesis of acetals and ketals by heterogeneously catalyzed liquid-solid phase reaction Rare Metals (Beijing, China) 25 2006 625 629
10. J. Requies, M.B. Güemez, P. Maireles, A. Iriondo, V.L. Barrio, J.F. Cambra, and P.L. Arias Zirconia supported Cu systems as catalysts for n-butanol conversion to butyraldehyde Applied Catalysis A: General 423-424 2012 185 191
11. J. Requies, M.B. Güemez, A. Iriondo, V.L. Barrio, J.F. Cambra, and P.L. Arias Bio n-butanol partial oxidation to butyraldehyde in gas phase on supported Ru and Cu catalysts Catalysis Letters 142 2012 417 426
12. G. Aksnes, P. Albriktsen, and P. Juvvik Cyclic acetal and ketal isomers of glycerol Acta Chemica Scandinavica 19 1965 920 930 (1947-1973)
13. G. Aksnes, and P. Albriktsen Intramolecular H bonding in cyclic acetal isomers of glycerol Acta Chemica Scandinavica 20 1966 1330 1334
14. J.S. Camara, J.C. Marques, A. Alves, and A.C.S. Ferreira Heterocyclic acetals in Madeira wines Analytical and Bioanalytical Chemistry 375 2003 1221 1224
15. A.C. da Silva Ferreira, J. Barbe, and A. Bertrand Heterocyclic acetals from glycerol and acetaldehyde in Port wines: evolution with aging Journal of Agricultural and Food Chemistry 50 2002 2560 2564
16. M. Kaufhold, and M. El-Chahawi Process for Preparing Acetaldehyde Diethyl Acetal, 5527969 1996 (Germany)
17. T.W. Green Protective Groups in Organic Synthesis 1981 Willey New York
18. J. Deutsch, A. Martin, and H. Lieske Investigations on heterogeneously catalysed condensations of glycerol to cyclic acetals Journal of Catalysis 245 2007 428 435
19. I. Agirre, V.L. Barrio, B. Güemez, J.F. Cambra, and P.L. Arias The development of a reactive distillation process for the production of 1,1 diethoxy butane from bioalcohol: kinetic study and simulation model International Journal of Chemical Reactor Engineering 8 2010 A86
20. A.D. Dhale, L.K. Myrant, S.P. Chopade, J.E. Jackson, and D.J. Miller Propylene glycol and ethylene glycol recovery from aqueous solution via reactive distillation Chemical Engineering Science 59 2004 2881 2890
21. I. Agirre, V.L. Barrio, B. Güemez, J.F. Cambra, and P.L. Arias Catalytic reactive distillation process development for 1,1 diethoxy butane production from renewable sources Bioresource Technology 102 2011 1289 1297
22. I. Agirre, I. García, J. Requies, V.L. Barrio, M.B. Güemez, J.F. Cambra, and P.L. Arias Glycerol acetals, kinetic study of the reaction between glycerol and formaldehyde Biomass and Bioenergy 35 2011 3636 3642
23. S.P. Chopade, and M.M. Sharma Acetalization of ethylene glycol with formaldehyde using cation-exchange resins as catalysts: batch versus reactive distillation Reactive and Functional Polymers 34 1997 37 45
24. S.P. Chopade, and M.M. Sharma Reaction of ethanol and formaldehyde: use of versatile cation-exchange resins as catalyst in batch reactors and reactive distillation columns Reactive and Functional Polymers 32 1997 53 65
25. B. Abad Identificación de la presencia de hemiacetal en una mezcla etanol:butanal (2:1 en moles), Servicio general de análisis UPV/EHU, SGIKER 2008 General Analysis Department of the University of the Basque Country
26. G.D. Yadav, and A.A. Pujari Kinetics of acetalization of perfumery aldehydes with alkanols over solid acid catalysts Canadian Journal of Chemical Engineering 77 1999 489 496
27. V.R. Ruiz, A. Velty, L.L. Santos, A. Leyva-Pérez, M.J. Sabater, S. Iborra, and A. Corma Gold catalysts and solid catalysts for biomass transformations: valorization of glycerol and glycerol-water mixtures through formation of cyclic acetals Journal of Catalysis 271 2010 351 357
28. B. Güemez, J.M. Requies, I. Agirre, V.L. Barrio, J.F. Cambra, and P.L. Arias Acetalization reaction between glycerol and n-butyraldehyde using an acidic ion exchange resin. Kinetic modelling Chemical Engineering Journal 228 2013 300 307
29. M.R. Dintzner, Y.A. Mondjinou, and D.J. Pileggi Montmorillonite clay-catalyzed cyclotrimerization and oxidation of aliphatic aldehydes Tetrahedron Letters 51 2010 826 827
30. J. Augé, and R. Gil A convenient solvent-free preparation of 1,3,5-trioxanes Tetrahedron Letters 43 2002 7919 7920