Glycerol acetals, kinetic study of the reaction between glycerol and formaldehyde

Biomass and Bioenergy

Volumn 35, Issue 8, 2011, Pages 3636-3642

  Agirre, I ^a   Garcia I ^a   Requies, J ^a   Barrio, V L ^a   Guemez M B ^a   Cambra, J F ^a   Arias, P L ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Acetal; Amberlyst; Formaldehyde; Glycerol; Kinetics

Indexed keywords

ACETAL; ACETALIZATION REACTION; AMBERLYST; BATCH STIRRED TANK REACTORS; DIFFERENT PROCESS; FEED COMPOSITIONS; FEED RATIOS; KINETIC MODELS; KINETIC STUDY; ORDER OF REACTION; REACTION MECHANISM; RENEWABLE SOURCES; STIRRING SPEED;

FORMALDEHYDE; GLYCEROL; ION EXCHANGE; ION EXCHANGE RESINS; ISOMERS; KINETIC THEORY; KINETICS; METHANOL; POSITIVE IONS;

REACTION KINETICS;

BIOREACTOR; EXPERIMENTAL STUDY; FORMALDEHYDE; HOMOGENEITY; ION EXCHANGE; REACTION KINETICS; THERMODYNAMICS;

EID: 79960359074     PISSN: 09619534     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biombioe.2011.05.008     Document Type: Article

References (23)

1. Moser B.R., Erhan S.Z. Branched chain derivatives of alkyl oleates: tribological, rheological, oxidation, and low temperature properties. Fuel 2008, 87(10-11):2253-2257.
2. Umbarkar S.B., Kotbagi T.V., Biradar A.V., Pasricha R., Chanale J., Dongare M.K., et al. Acetalization of glycerol using mesoporous MoO3/SiO2 solid acid catalyst. J Mol Catal A: Chem 2009, 310(1-2):150-158.
3. Silva P.H.R., Gonτalves V.L.C., Mota C.J.A. Glycerol acetals as anti-freezing additives for biodiesel. Bioresour Technol 2010, 101(15):6225-6229.
4. Burtscher H., Matter U., Skillas G. The effect of fuel additives on diesel engine particulate emissions. J Aerosol Sci 1999, 30(Supplement 1):S851-S852.
5. Capeletti M.R., Balzano L., de la Puente G., Laborde M., Sedran U. Synthesis of acetal (1,1-diethoxyethane) from ethanol and acetaldehyde over acidic catalysts. Appl Catal A 2000, 198(1-2):L1-L4.
6. Hu J., Wang Y., Cao C., Elliott D.C., Stevens D.J., White J.F. Conversion of biomass-derived syngas to alcohols and C2 oxygenates using supported Rh catalysts in a microchannel reactor. Catal Today 2007, 120(1):90-95.
7. Munasinghe P.C., Khanal S.K. Biomass-derived syngas fermentation into biofuels: opportunities and challenges. Bioresour Technol 2010, 101(13):5013-5022.
8. Yang S., Wang M., Liang Y., Sun J. Eco-friendly one-pot synthesis of acetals and ketals by heterogeneously catalyzed liquid-solid phase reaction. Rare Met. (Beijing, China) 2006, 25(6):625-629.
9. Frusteri F., Spadaro L., Beatrice C., Guido C. Oxygenated additives production for diesel engine emission improvement. Chem Eng J 2007, 134(1-3):239-245.
10. Kaufhold M., El-Chahawi M., inventors. Huels Aktiengesellschaft, assignee. Process for preparing acetaldehyde diethyl acetal. Germany Patent 5527969. 1996 Jun 1996.
11. Green T.W. Protective groups in organic synthesis 1981, Willey, New York.
12. Chopade S.P., Sharma M.M. Acetalization of ethylene glycol with formaldehyde using cation-exchange resins as catalysts: batch versus reactive distillation. React Funct Polym 1997, 34(1):37-45.
13. da Silva Ferreira Antonio Cesar, Barbe J., Bertrand A. Heterocyclic acetals from glycerol and acetaldehyde in port wines: evolution with aging. J Agric Food Chem 2002, 50(9):2560-2564.
14. Agirre I., Barrio V.L., Güemez B., Cambra J.F., Arias P.L. The development of a reactive distillation process for the production of 1,1 Diethoxy Butane from bioalcohol: kinetic study and Simulation model. Int J Chem React Eng 2010, 8:A86.
15. Abad B. Identificación de la presencia de hemiacetal en una mezcla etanol:butanal (2:1 en moles). Servicio general de análisis UPV/EHU, editor. 4-21-2008. SGIKER. General Analysis Department of the University of the Basque Country.
16. Yadav G.D., Pujari A.A. Kinetics of acetalization of perfumery aldehydes with alkanols over solid acid catalysts. Can J Chem Eng 1999, 77(3):489-496.
17. Camara J.S., Marques J.C., Alves A., Ferreira A.C.S. Heterocyclic acetals in Madeira wines. Anal Bioanal Chem 2003, 375(8):1221-1224.
18. Aksnes G., Albriktsen P., Juvvik P. Cyclic acetal and ketal isomers of glycerol. Acta Chem Scand 1965, 19(4):920-930. 1947-1973.
19. Ruiz V.R., Velty A., Santos L.L., Leyva-Pθrez A., Sabater M.J., Iborra S., et al. Gold catalysts and solid catalysts for biomass transformations: valorization of glycerol and glycerol-water mixtures through formation of cyclic acetals. J Catal 2010, 271(2):351-357.
20. Froment G.F., Bischoff K.B. Chemical reactor analysis and design 1979, John Wiley & Sons.
21. Chopade S.P., Sharma M.M. Reaction of ethanol and formaldehyde: use of versatile cation-exchange resins as catalyst in batch reactors and reactive distillation columns. React Funct Polym 1997, 32(1):53-65.
22. Dhale A.D., Myrant L.K., Chopade S.P., Jackson J.E., Miller D.J. Propylene glycol and ethylene glycol recovery from aqueous solution via reactive distillation. Chem Eng Sci 2004, 59(14):2881-2890.
23. Silva M.T.M., Rodrigues A.E. Synthesis of diethylacetal: thermodynamic and kinetic studies. Chem Eng Sci 2001, 56(4):1255-1263.