σ-Donor/acceptor-confused ligands: The case of a chlorostibine

Inorganic Chemistry

Volumn 52, Issue 12, 2013, Pages 7145-7151

  Ke, Iou Sheng ^a   Gabbaï, François P ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84879201499     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic400736b     Document Type: Article

References (49)

1. Champness, N. R.; Levason, W. Coord. Chem. Rev. 1994, 133, 115-217
2. Jimenez-Tenorio, M.; Puerta, M. C.; Salcedo, I.; Valerga, P.; Rios, I. D.; Mereiter, K. Dalton Trans. 2009, 1842-1852
3. Levason, W.; Reid, G. Coord. Chem. Rev. 2006, 250, 2565-2594
4. Levason, W.; McAuliffe, C. A. Acc. Chem. Res. 1978, 11, 363-368
5. Werner, H. Angew. Chem., Int. Ed. 2004, 43, 938-954
6. Wade, C. R.; Gabbaï, F. P. Angew. Chem., Int. Ed. 2011, 50, 7369-7372
7. Parkin, G. Organometallics 2006, 25, 4744-4747
8. Hill, A. F. Organometallics 2006, 25, 4741-4743
9. Fontaine, F. G.; Boudreau, J.; Thibault, M. H. Eur. J. Inorg. Chem. 2008, 5439-5454
10. Braunschweig, H.; Dewhurst, R. D.; Schneider, A. Chem. Rev. 2010, 110, 3924-3957
11. Bouhadir, G.; Amgoune, A.; Bourissou, D. Adv. Organomet. Chem. 2010, 58, 1-107
12. Amgoune, A.; Bourissou, D. Chem. Commun. 2011, 47, 859-871
13. Braunschweig, H.; Dewhurst, R. D. Dalton Trans. 2011, 40, 549-558
14. Rudd, P. A.; Liu, S.; Gagliardi, L.; Young, V. G.; Lu, C. C. J. Am. Chem. Soc. 2011, 133, 20724-20727
15. Bauer, J.; Braunschweig, H.; Dewhurst, R. D. Chem. Rev. 2012, 112, 4329-4346
16. Anderson, J. S.; Moret, M.-E.; Peters, J. C. J. Am. Chem. Soc. 2013, 135, 534-537
17. Lin, T.-P.; Wade, C. R.; Pérez, L. M.; Gabbaï, F. P. Angew. Chem., Int. Ed. 2010, 49, 6357-6360
18. Wade, C. R.; Lin, T.-P.; Nelson, R. C.; Mader, E. A.; Miller, J. T.; Gabbaï, F. P. J. Am. Chem. Soc. 2011, 133, 8948-8955
19. Wade, C. R.; Ke, I.-S.; Gabbaï, F. P. Angew. Chem., Int. Ed. 2012, 51, 478-481
20. Lin, T.-P.; Nelson, R. C.; Wu, T.; Miller, J. T.; Gabbaï, F. P. Chem. Sci. 2012, 3, 1128-1136
21. Ohkata, K.; Takemoto, S.; Ohnishi, M.; Akiba, K.-y. Tetrahedron Lett. 1989, 30, 4841-4844
22. Yi, W.; Tan, N. Acta Crystallogr., Sect. E: Struct. Rep. Online 2011, 67, m917
23. Benjamin, S. L.; Levason, W.; Reid, G.; Warr, R. P. Organometallics 2012, 31, 1025-1034
24. Tschersich, C.; Limberg, C.; Roggan, S.; Herwig, C.; Ernsting, N.; Kovalenko, S.; Mebs, S. Angew. Chem., Int. Ed. 2012, 51, 4989-4992
25. Lin, T.-P.; Ke, I.-S.; Gabbaï, F. P. Angew. Chem., Int. Ed. 2012, 51, 4985-4988
26. Cordero, B.; Gomez, V.; Platero-Prats, A. E.; Reves, M.; Echeverria, J.; Cremades, E.; Barragan, F.; Alvarez, S. Dalton Trans. 2008, 2832-2838
27. Pyykkö, P.; Atsumi, M. Chem.-Eur. J. 2009, 15, 186-197
28. Jones, P. G. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1992, 48, 1487-1488
29. Becker, G.; Mundt, O.; Sachs, M.; Breunig, H. J.; Lork, E.; Probst, J.; Silvestru, A. Z. Anorg. Allg. Chem. 2001, 627, 699-714
30. Hall, M.; Sowerby, D. B. J. Organomet. Chem. 1988, 347, 59-70
31. Milicćev, S.; Hadzi, D. Inorg. Chim. Acta 1977, 21, 201-207
32. Sircoglou, M.; Bontemps, S.; Mercy, M.; Saffon, N.; Takahashi, M.; Bouhadir, G.; Maron, L.; Bourissou, D. Angew. Chem., Int. Ed. 2007, 46, 8583-8586
33. N. Gibbons, M.; J. Begley, M.; J. Blake, A.; Bryan Sowerby, D. J. Chem. Soc., Dalton Trans. 1997, 2419-2426
34. The notion of valence refers to the number of electrons that an atom involves in bonding. Here, the structure of 5 suggests that the gold atom involves three of its valence electron in bonding. Additional clarification on the notion of valence is provided in the following reference. Parkin, G. J. Chem. Educ. 2006, 83, 791-799
35. Uson, R.; Laguna, A.; Laguna, M. Inorg. Synth. 1989, 26, 85-91
36. Korshin, E. E.; Leitus, G.; Shimon, L. J. W.; Konstantinovski, L.; Milstein, D. Inorg. Chem. 2008, 47, 7177-7189
37. Chan, K. H.; Leong, W. K.; Mak, K. H. G. Organometallics 2006, 25, 250-259
38. Nunn, M.; Sowerby, D. B.; Wesolek, D. M. J. Organomet. Chem. 1983, 251, C45-C46
39. SAINTPlus, Data Reduction and Correction Program, v. 6.2; Bruker AXS: Madison, WI, 2001.
40. Sheldrick, G. M. SHELXTL, Version 6.1; Bruker Analytical X-ray Systems, Inc.: Madison, WI.
41. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J., J. A.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, Ö.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian 09, Revision B.01; Gaussian, Inc.: Wallingford, CT, 2009.
42. Becke, A. D. Phys. Rev. A 1988, 38, 3098-3100
43. Perdew, J. P. Phys. Rev. B 1986, 33, 8822-8824
44. Figgen, D.; Rauhut, G.; Dolg, M.; Stoll, H. Chem. Phys. 2005, 311, 227-244
45. Bergner, A.; Dolg, M.; Küchle, W.; Stoll, H.; Preuß, H. Mol. Phys. 1993, 80, 1431-1441
46. Metz, B.; Stoll, H.; Dolg, M. J. Chem. Phys. 2000, 113, 2563-2569
47. Stoll, H.; Metz, B.; Dolg, M. J. Comput. Chem. 2002, 23, 767-778
48. Glendening, E. D.; Badenhoop, J. K.; Reed, A. E.; Carpenter, J. E.; Bohmann, J. A.; Morales, C. M.; Weinhold, F. NBO 5.9; Theoretical Chemistry Institute, University of Wisconsin: Madison, WI, 2011.
49. Manson, J.; Webster, C. E.; Pérez, L. M.; Hall, M. B., http://www.chem.tamu.edu/jimp2/index.html.