Highly enantioselective construction of 3-hydroxy oxindoles through a decarboxylative aldol addition of trifluoromethyl α-fluorinated gem-diols to n-benzyl isatins

Angewandte Chemie - International Edition

Volumn 52, Issue 21, 2013, Pages 5566-5570

  Saidalimu, Ibrayim ^a   Fang, Xiang ^a   He, Xiao Peng ^a   Liang, Jing ^a   Yang, Xueyan ^a   Wu, Fanhong ^b  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b SHANGHAI INSTITUTE OF TECHNOLOGY   (China)

Author keywords

aldol reaction; carbon carbon bond cleavage; organocatalysis; reaction mechanisms; trifluoroacetate release

Indexed keywords

ALDOL REACTIONS; CARBON-CARBON BOND CLEAVAGE; ORGANOCATALYSIS; REACTION MECHANISM; TRIFLUOROACETATES;

ADDITION REACTIONS; CONDENSATION REACTIONS; ENANTIOSELECTIVITY; REACTION KINETICS;

KETONES;

EID: 84877704730     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201301443     Document Type: Article

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