DFT study of chiral-phosphoric-acid-catalyzed enantioselective friedel-crafts reaction of indole with nitroalkene: Bifunctionality and substituent effect of phosphoric acid

Chemistry - An Asian Journal

Volumn 6, Issue 2, 2011, Pages 510-516

  Hirata, Takashi ^a   Yamanaka, Masahiro ^a  

^a RIKKYO UNIVERSITY   (Japan)

Author keywords

density functional calculations; Friedel Crafts reactions; indoles; nitroalkenes; phosphoric acid

Indexed keywords

ACID CATALYST; BINAPHTHYL; CYCLIC TRANSITIONS; DENSITY-FUNCTIONAL CALCULATIONS; DFT CALCULATION; DFT STUDY; DIASTEREOMERIC; DOUBLE ACTIVATION; ENANTIOSELECTIVE; ENERGY DIFFERENCES; FRIEDEL-CRAFTS; HIGH ENANTIOSELECTIVITY; HIGH YIELD; INDOLE RINGS; INDOLES; NITROALKENES; PHOSPHORYL OXYGEN; REACTION MECHANISM; STERIC EFFECT; STERICALLY DEMANDING; SUBSTITUENT EFFECT; TRANSITION STATE; TWO-POINT;

BINDING SITES; CATALYSIS; CATALYSTS; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; FRIEDEL-CRAFTS REACTION; GROUP TECHNOLOGY; ORGANIC POLYMERS; OXYGEN; PROTONS;

PHOSPHORIC ACID;

EID: 79251482773     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.201000596     Document Type: Article

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