Electronically nonadiabatic processes in the interaction of H with a Au surface revealed using MIM junctions: The temperature dependence

Journal of Physical Chemistry C

Volumn 117, Issue 12, 2013, Pages 6337-6345

  Schindler, Beate ^a,b   Diesing, Detlef ^a   Hasselbrink, Eckart ^a  

^a UNIVERSITY OF DUISBURG ESSEN   (Germany)

^b Oxford Instruments ^*  (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGING/DISCHARGING; DEVICE TEMPERATURE; METAL INSULATOR METALS; NON-ADIABATIC PROCESS; RECOMBINATION REACTIONS; STEADY-STATE CURRENTS; SUBSURFACE HYDROGENS; TEMPERATURE DEPENDENCE;

ATOMS; RATE CONSTANTS; REACTION KINETICS; TANTALUM; TANTALUM COMPOUNDS;

MIM DEVICES;

EID: 84875723627     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4009459     Document Type: Article

References (30)

1. Nienhaus, H.; Bergh, H. S.; Gergen, B.; Majumdar, A.; Weinberg, W. H.; McFarland, E. W. Electron-Hole Pair Creation at Ag and Cu Surfaces by Adsorption of Atomic Hydrogen and Deuterium Phys. Rev. Lett. 1999, 82, 446-449
2. Mildner, B.; Hasselbrink, E.; Diesing, D. Electronic Excitations Induced by Surface Reactions of H and D on Gold Chem. Phys. Lett. 2006, 432, 133-138
3. Park, J. Y.; Somorjai, G. A. The Catalytic Nanodiode: Detecting Continous Electron Flow at Oxide Metal Interfaces Generated by a Gas-Phase Exothermic Reaction ChemPhysChem 2006, 7, 1409-1413
4. Nienhaus, H. Electronic Excitations by Chemical Reactions on Metal Surfaces Surf. Sci. Rep. 2002, 45, 1-78
5. Wodtke, A. M.; Tully, J. C.; Auerbach, D. J. Electronically Non-Adiabatic Interactions of Molecules at Metal Surfaces: Can We Trust the Born-Oppenheimer Approximation for Surface Chemistry? Int. Rev. Phys. Chem. 2004, 23, 513-539
6. Hasselbrink, E. How Non-Adiabatic Are Surface Dynamical Processes? Curr. Opin. Solid State Mater. Sci. 2007, 10, 192-204
7. Karpov, E. G.; Nedrygailov, I. I. Solid-State Electric Generator Based on Chemically Induced Internal Electron Emission in Metal-Semiconductor Heterojunction Nanostructures Appl. Phys. Lett. 2009, 94, 214101
8. Karpov, E. G.; Nedrygailov, I. Nonadiabatic Chemical-to-Electrical Energy Conversion in Heterojunction Nanostructures Phys. Rev. B 2010, 81, 205443
9. Hervier, A.; Renzas, J. R.; Park, J. Y.; Somorjai, G. A. Hydrogen Oxidation-Driven Hot Electron Flow Detected by Catalytic Nanodiodes Nano Lett. 2009, 9, 3930-3933
10. 2 on Silver Surfaces Surf. Sci. 1996, 351, 24-42
11. Thissen, P.; Schindler, B.; Diesing, D.; Hasselbrink, E. Optical Characterization of Metal-Insulator-Metal Heterostructures for the Detection of Chemicurrents New. J. Phys. 2010, 12, 113014
12. Gadzuk, J. W. On the Detection of Chemically-Induced Hot Electrons in Surface Processes: From X-Ray Edges to Schottky Barriers J. Phys. Chem. B 2002, 106, 8265-8270
13. Lindenblatt, M.; Pehlke, E. Time-Dependent Density-Functional Molecular-Dynamics Study of the Isotope Effect in Chemicurrents Surf. Sci. 2006, 600, 5068-5073
14. Trail, J. R.; Bird, D. M.; Persson, M.; Holloway, S. Electron-Hole Pair Creation by Atoms Incident on a Metal Surface J. Chem. Phys. 2003, 119, 4539-4549
15. Mizielinski, M. S.; Bird, D. M.; Persson, M.; Holloway, S. Spectrum of Electronic Excitations Due to the Adsorption of Atoms on Metal Surfaces J. Chem. Phys. 2007, 126, 034705
16. Ertl, G.; Hasselbrink, E. Reactions at Metal Surfaces Involving Valence Electron Excitations Mol. Phys. 1992, 76, 777-786
17. Hasselbrink, E. Non-Adiabaticity in Surface Chemical Reactions Surf. Sci. 2009, 603, 1564-1570
18. Huang, Y.; Rettner, C. T.; Auerbach, D. J.; Wodtke, A. M. Vibrational Promotion of Electron Transfer Science 2000, 290, 111-114
19. White, J. D.; Chen, J.; Matsiev, D.; Auerbach, D. J.; Wodtke, A. M. Vibrationally Promoted Electron Emission from Low Work-Function Metal Surfaces J. Chem. Phys. 2006, 124, 064702
20. Shenvi, N.; Roy, S.; Tully, J. C. Dynamical Steering and Electronic Excitation in NO Scattering from a Gold Surface Science 2009, 326, 829-832
21. Monturet, S.; Saalfrank, P. Role of Electronic Friction during the Scattering of Vibrationally Excited Nitric Oxide Molecules From Au(111) Phys. Rev. B 2010, 82, 075404
22. Schindler, B.; Diesing, D.; Hasselbrink, E. Electronic Excitations Induced by Hydrogen Surface Chemical Reactions on Gold J. Chem. Phys. 2011, 134, 034705
23. Jeliazova, Y.; Kayser, M.; Mildner, B.; Hassel, A. W.; Diesing, D. Temperature Stability of Thin Anodic Oxide Films in Metal/Insulator/Metal Structures: A Comparison between Tantalum and Aluminium Oxide Thin Solid Films 2006, 500, 330-335
24. Tschersich, K. G.; Fleischhauer, J. P.; Schuler, H. Design and Characterization of a Thermal Hydrogen Atom Source J. Appl. Phys. 2008, 104, 034908
25. Kammler, T.; Wehner, S.; Küppers, J. The Role of Sticking and Reaction Probabilities in Hot-Atom Mediated Abstraction Reactions of D on Metal Surfaces by Gaseous H Atoms J. Chem. Phys. 1998, 109, 4071-4077
26. Eibl, C.; Lackner, G.; Winkler, A. Quantitative Characterization of a Highly Effective Atomic Hydrogen Doser J. Vac. Sci. Technol., A 1998, 16, 2979-2989
27. Stobiński, L.; Duś, R. Model of Atomic Hydrogen Adsorption on Thin Gold Film Surface Vacuum 1994, 45, 299-301
28. Stobiński, L.; Duś, R. Atomic Hydrogen Adsorption on Thin Gold Films Surf. Sci. 1992, 269/70, 383-388
29. Strömquist, J.; Bengtsson, L.; Persson, M.; Hammer, B. The Dynamics of H Absorption in and Adsorption on Cu(111) Surf. Sci. 1998, 397, 382-394
30. Ferrin, P.; Kandoi, S.; Nilekar, A. U.; Mavrikakis, M. Hydrogen Adsorption, Absorption and Diffusion on and in Transition Metal Surfaces: A DFT Study Surf. Sci. 2012, 606, 679-68