Complexation thermodynamics and structural studies of trivalent actinide and lanthanide complexes with DTPA, MS-325 and HMDTPA

Radiochimica Acta

Volumn 101, Issue 4, 2013, Pages 221-232

  Thakur, P ^a,e   Conca, J L ^b   Dodge, C J ^c   Francis, A J ^c,d   Choppin, G R ^a  

^a FLORIDA STATE UNIVERSITY   (United States)

^b RJ LEE GROUP   (United States)

^c BROOKHAVEN NATIONAL LABORATORY   (United States)

^d Pohang University of Science and Technology (POSTECH)   (South Korea)

^e Horeshoe Cir Jett Hall   (United States)

Author keywords

Actinides; DTPA; HMDTPA; Lanthanides; MS 325

Indexed keywords

EID: 84875706974     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2013.2018     Document Type: Article

References (50)

1. Ketelle, B. H., Boyd, G. E.: The exchange adsorption of ions from aqueous solutions by organic zeolites. IV. The separation of the yttrium group rare earths. J. Am. Chem. Soc. 69, 2800-2812 (1947).
2. Mondry, A., Starynowicz, P.: Optical spectroscopy of neodymium( III) complexes with diethylenetriaminepentaacetic acid in solution and in [C(NH2)3]2[Nd(dtpa)(H2O)]7H2O single crystal. Polyhedron 19, 771-777 (2000).
3. Inomata, Y., Sunakawa, T., Howell, F. S.: The syntheses of lanthanide metal complexes with diethylenetriamine-N, N, N, N, N-pentaacetic acid and the comparison of their crystal structures. J. Mol. Struct. 648, 81-88 (2003). (Pubitemid 36254023)
4. Bryden, C. C., Reilley, C. N.: Europium luminescence lifetimes and spectra for evaluation of 11 europium complexes as aqueous shift reagents for nuclear magnetic resonance spectrometry. Anal. Chem. 54, 610-615 (1982).
5. Kimura, T., Choppin, G. R.: Luminescence study on determination of the hydration number of Cm(III). J. Alloys Compd. 213/214, 313-317 (1994).
6. Powell, J. E.: Handbook on Physics and Chemistry of Rare Earths. (Gschneidner, K. A., Eyring, L., eds.) North-Holland Publishing Company, Oxford (1979), Vol. 3, chap. 22.
7. Weaver, B., Kappelman, F. A.: ORNL-3559, August (1964).
8. Weaver, B., Kappelmann, F. A.: Preferential extraction of lanthanides over trivalent actinides by monacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids. Inorg. Nucl. Chem. 30, 263-272 (1968).
9. Kumar, K., Tweedle, M. F.: Macrocyclic polyaminocarboxylate complexes of lanthanides as magnetic resonance imaging contrast agents. Pure Appl. Chem. 65, 515-520 (1993).
10. Port, M., Idee, J. M., Madina, C. M., Robic, C., Sabatou, M., Corot, C.: Efficiency, thermodynamic and kinetic stability of marketed gadolinium chelates and their possible clinical consequences: a critical review. Biometals 21, 469-490 (2008).
11. Nelson, K. L., Gifford, L. M., Lauber-Hauber, C., Gross, C. A., Lasser, T. A.: Clinical safety of gadopentetate dimeglumine. Radiology 196, 439-443 (1995).
12. Murphy, K. J., Brunberg, J. A., Cohan, R. H.: Adverse reactions to gadolinium contrast media: a review of 36 cases. Am. J. Roentgenol. 167, 847-849(1996). (Pubitemid 26322229)
13. Kostromina, N. N., Tananaeva, N. N.: A spectrographic study of the complexing of europium with diethylenetriamine pentaacetate. J. Appl. Spectro. 14, 232-237 (1969).
14. Baybarz, R. D.: Dissociation constants of the transplutonium element chelates of diethylenetriaminepenta-acetic acid (DTPA) and the application of DTPA chelates to solvent extraction separations of transplutonium elements from the lanthanide elements. J. Inorg. Nucl. Chem. 27, 1831-1839 (1965).
15. Moeller, T., Thompson, L. C.: Observations on the rare earths-LXXV: the stabilities of diethylenetriaminepentaacetic acid chelates. J. Inorg. Nucl. Chem. 24, 499-510 (1962).
16. Gritmon, T. F., Goedken, M. P., Choppin, G. R.: The complexation of lanthanides by aminocarboxylate ligands-I: Stability constants. J. Inorg. Nucl. Chem. 39, 2021-2023 (1977).
17. Ensor, D. D., Shah, A. H.: Progress Report, DOE/ER/10489-08, Oak RidgeNational Laboratory, Oak Ridge, TN, December (1982).
18. Vogel, A. I.: A Text Book in Quantitative Inorganic Analysis. Longmans, London (1966).
19. Hummel, W., Anderegg, G., Puigdomenech, I., Rao, L., Tochiyama, O.: Chemical Thermodynamics of Compounds and Complexes of: U, Np, Pu, Am, Tc, Zr, Ni and Se With Selected Organic Ligands. (Mompean, F. J., Illemassene, M., Perrone, J., eds.) Elsevier, B. V., Amsterdam (2005).
20. Smith, R. M., Martell, A. E., Motekaitis, R. J.: NIST Critically Selected Stability Constants of Metal Complexes Database, Version 6.0.
21. Smith, R. M., Martell, A. E.: Critical Stability Constants. Plenum, New York (1974, 1975, 1976, 1977), Vols. 1-4.
22. Arnek, R.: High-speed computers as a supplement to graphical methods. II. Application of LETAGROP to calorimetric titrations. Arkiv Kemi. 32, 81-88 (1970).
23. Cernochova, K., Mathur, J. N., Choppin, G. R.: Chemical speciation of Am, Cm and Eu with EDTA at high ionic strength: thermodynamic and laser fluorescence spectroscopy studies. Radiochim. Acta 93, 733-738 (2005).
24. Barthelemy, P. P., Choppin, G. R.: Luminescence study of complexation of europium and dicarboxylic acids. Inorg. Chem. 28, 3354-3357 (1989).
25. Newville, M.: EXAFS analysis using FEFF and FEFFIT. J. Synchrotron Rad. 8, 96-100 (2001). (Pubitemid 33661316)
26. Ankudinov, A. L., Rehr, J. J.: Relativistic calculations of spindependent X-ray-absorption spectra. J. Phys. Rev. B 56, R1712-R1715 (1997).
27. Serre, C., Millange, F., Marrot, J., Ferey, G.: Hydrothermal synthesis, structure determination, and thermal behavior of new three-dimensional europium terephthalates:MIL-51LT, HT and MIL-52 or Eu2 n(OH)x(H2O)y(O2C-C6H4?CO2)z (n = III, III, II, x = 4, 0, 0, y = 2, 0, 0, z =1, 1, 2). Chem. Mater. 14, 2409-2415 (2002).
28. Caravan, P., Comuzzi, C., Crooks, W., McMurry, T. J., Choppin, G. R., Woulfe, S. R.: Thermodyanmic stability and kinetic inertness of MS-325, a new blood pool agent for magnetic resonance imaging. Inorg. Chem. 40, 2170 (2001).
29. Tian, G., Martin, L. R., Zhang, Z., Rao, L.: Thermodynamic, spectroscopic, and computational studies of lanthanide complexation with diethylenetriaminepentaacetic acid: Temperature effect and coordination modes. Inorg. Chem. 50, 3087-3096 (2011).
30. Choppin, G. R., Rizkalla, E. N.: In: Handbook on the Physics and Chemistry of Rare Earths. Vol. 18. (Gschneidner Jr., K. A., Eyring, L., Choppin, G. R., Lander, G. H., eds.) Elsevier Science, North-Holland (1994).
31. Tse, P.-K., Powell, J. E.: Study of structural influence on the formation constants of lanthanide-polyamino-polycarboxylate complexes. Inorg. Chem. 24, 2121-2130 (1985).
32. Choppin, G. R., Brock, J. L.: Thermodynamics of lanthanides TMEDTA complexation. Inorg. Chim. Acta 109, 99-104 (1985).
33. Sarka, L., Banyai, I., Brücher, E., Kiraly, R., Platzek, J., Radüchel, B., Willich, H. S.: Synthesis, equilibrium and NMR studies of lanthanide(III) complexes of the N-mono(methylamide) and N-mono-(methylamide) derivatives of diethylenetriamine-N, N, N, N, N pentaacetic acid. J. Chem. Soc. Dalton Trans. 3699-3703 (2000).
34. Imura, H., Choppin, G. R., Cacheris, W. P., de Learie, L. A., Dunn, T. J., White, D. H.: Thermodynamics and NMR studies of DTPA-bis (methoxyethylamide) and its derivatives. Protonation and complexation with Ln(III). Inorg. Chim. Acta 258, 227-236 (1997).
35. Wang, Y.-M., Cheng, T.-H., Liu, G.-C., Sheu, R.-S.: Synthesis of some N, N-bis(amide) derivatives of diethylenetriaminepentaacetic acid and the stabilities of their complexes with Gd3+, Ca2+, Cu2+ and Zn2+. J. Chem. Soc. Dalton Trans. 833-837 (1997). (Pubitemid 127780557)
36. Schaab, K. M.: Ph.D. Dissertation Thesis, The Florida State University (1998).
37. Cheng, T.-H., Wang, Y.-M., Lee, W.-T., Liu, G.-C.: Synthesis of two N-2-pyridylmethyl and N-2-hydroxypropyl derivatives of diethylenetriaminepentaacetic acid and the stabilities of their complexes with Ln3+, Ca2+, Cu2+ and Zn2+. Polyhedron 19, 2027-2037 (2000).
38. Beitz, J. V., Hessler, J. P.: Oxidation state specific detection of transuranic ions in solution, Nucl. Technol. 51, 169-177 (1980).
39. Brittain, H. G., Choppin, G. R., Barthelemy, P. P.: pH-dependence of the metal ion hydration state in lanthanide complexes of polyaminopolycarboxylate ligands. J. Coord. Chem. 26, 143-153 (1992).
40. Liu, B., Wang, Y. F., Wang, J., Gao, J., Xu, R., Kong, Y. M., Zhang, L. Q., Zhang, X. D.: Synthesis and crystal structures of nine coordinate K2[Eu(dtpa)(H2O)]5H2O and Na2 [Tb(httha)] 6H2O complexes. J. Struct. Chem. 50, 880-886 (2009).
41. Kostromina, N. N., Tananaeva, N. N.: A spectrographic study of the complexing of europium with diethylenetriamine pentaacetate. J. Appl. Spectro. 14, 232-237 (1969).
42. Tomasi, J., Persico, M.: Molecular interactions in solution: an overview of methods based on continuous distributions of the solvent. Chem. Rev. 94, 2027-2094 (1994). (Pubitemid 124000195)
43. Nakamura, K., Kurisaki, T., Wakita, H., Yamaguchi, T.: Sodium Triaqua (ethylenediaminetetraacetato) lanthanate(III) pentahydrate and the isomorphous neodymium(III) and europium(III) salts. Acta Cryst. C51, 1559-1563 (1995).
44. Inomata, Y., Sunakawa, T., Howell, F. S.: The syntheses of lanthanide metal complexes with diethylenetriamine-N, N, N, N, N-pentaacetic acid and the comparison of their crystal structures. J. Mol. Struc. 648, 81-88 (2003). (Pubitemid 36254023)
45. Wright, D. L., Holloway, J. H., Reilley, C. N.: Heat and entropies of formation of metal chelates of polyamine and polyaminocarboxylate ligands. Anal. Chem. 37, 884-892 (1965).
46. Rizkalla, E. N., Sullivan, J. C., Choppin, G. R.: Calorimeter studies of americium(III) complexation by amino carboxylates. Inorg. Chem 28, 909-911(1989).
47. Harder, R., Chaberek, S.: The interaction of rare earth ions with diethylenetriamine-pentaacetic acid. J. Inorg. Nucl. Chem. 11, 197-209 (1959).
48. Bryden, C. C., Reilley, C. N.: Europium luminescence lifetimes and spectra for evaluation of 11 europium complexes as aqueous shift reagents for nuclear magnetic resonance spectrometry. Anal. Chem. 54, 610-615 (1982).
49. Kimura, T., Choppin, G. R., Kato, Y., Yoshida, Z.: Determination of the hydration number of Cm(III) in various aqueous solutions. Radiochim Acta 72, 61-64 (1996). (Pubitemid 126458460)
50. Latva, M., Kankare, J.: The 7F0-5D0 excitation spectra of europium( III) complexes of aminocarboxylic acids. J. Cood. Chem. 43, 121-142 (1998).