Thermodynamics and NMR studies of DTPA-bis(methoxyethylamide) and its derivatives. Protonation and complexation with Ln(III)

Inorganica Chimica Acta

Volumn 258, Issue 2, 1997, Pages 227-236

  Imura, H ^a,c   Choppin, G R ^a   Cacheris, W P ^b   De Learie, L A ^b   Dunn, T J ^b   White, D H ^b  

^a FLORIDA STATE UNIVERSITY   (United States)

^b MALLINCKRODT PHARMACEUTICALS   (United States)

^c IBARAKI UNIVERSITY   (Japan)

Author keywords

Amide complexes; Lanthanide complexes; Thermodynamics

Indexed keywords

AMIDES; CARBOXYLATION; COMPLEXATION; LIGANDS; MOLECULES; PROTONATION; THERMODYNAMICS;

AMIDE COMPLEXES; AQUEOUS COMPLEXES; CALORIMETRIC TITRATION; COMPLEXATION PARAMETERS; LANTHANIDE COMPLEX; LUMINESCENCE LIFETIME; PROTONATION ENTHALPIES; THERMODYNAMIC PARAMETER;

EUROPIUM COMPOUNDS;

EID: 0004834239     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(96)05522-3     Document Type: Article

References (32)

1. R.B. Lauffer, Chem. Rev., 87 (1987) 901.
2. W.P. Cacheris, S.C. Quay and S.M. Rocklage, Magn. Reson. Imaging, 8 (1990) 467.
3. R.W. Weber, Paramagnetic DTPA and EDTA Alkoxyalkylamide Complexes as MRI Agents, US Patent No. 5 130 120.
4. E.N. Rizkalla, G.R. Choppin and W.P. Cacheris, Inorg. Chem., 32 (1993) 582.
5. S.M. Rocklage, S.H. Sheffer, W.P. Cacheris, S.C. Quay, E.F. Hahn and K.N. Raymond, Inorg. Chem., 27 (1988) 3530.
6. A.E. Martell and R.M. Smith, Critical Stability Constants, Vol. 1, Plenum, New York, 1974.
7. M.S. Caceci and G.R. Choppin, Comput. Chem., 6 (1984) 161.
8. R.G. Bates, Determination of pH, Wiley, New York, 1964.
9. V.K. La Mer and J.P. Chittum, J. Chem. Soc., 58 (1936) 1642.
10. R. Gary, R.G. Bates and R.A. Robinson, J. Phys. Chem., 69 (1965) 2750.
11. P.P. Barthelemy and G.R. Choppin, Inorg. Chem., 28 (1989) 3354.
12. A.E. Martell and R.M. Smith, Critical Stability Constants, Vol. 6, Plenum, New York, 1989.
13. B.B. Wayland, R.S. Drago and H.F. Henneike, J. Am. Chem. Soc., 88 (1966) 2455.
14. A. Johansson, P. Kollman, S. Rothenberg and J. McKelvey, J. Am. Chem. Soc., 96 (1974) 3794.
15. J.N. Spencer, S.K. Berger, C.R. Powell, B.D. Henning, G.S. Furman, W.M. Loffredo, E.M. Ryberg, R.A. Neubert, C.E. Snoop and D.N. Blauch, J. Phys. Chem., 85 (1981) 1236.
16. J.L. Sudmeier and C.N. Reilly, Anal. Chem., 36 (1964) 1698.
17. G.R. Choppin, Thermochim. Acta, 227 (1993) 1.
18. G.R. Choppin, M.P. Goedken and T.F. Gritmon, J. Inorg. Nucl. Chem., 39 (1977) 2025.
19. H.G. Brittain and J.P. Jasinski, J. Coord. Chem., 18 (1988) 279.
20. H.G. Brittain, G.R. Choppin and P.P. Barthelemy, J. Coord. Chem., 26 (1992) 143.
21. C.F.G.C. Geraldes, A.M. Urbano, M.C. Alpoim, M.A. Hoefnagel and J.A. Peters, J. Chem. Soc., Chem. Commun., (1991) 656.
22. G.R. Choppin, P.A. Baisden and S.A. Khan, Inorg. Chem., 18 (1979) 1330.
23. L.A. deLearie, D.A. Moore, T.J. Dunn and D.H. White, unpublished data.
24. M.S. Konings, W.C. Dow, D.B. Love, K.N. Raymond, S.C. Quay and S.M. Rocklage, Inorg. Chem., 29 (1990) 1488.
25. J.A. Peters, Inorg. Chem., 27 (1988) 4686.
26. D.H. White, L.A. deLerie, T.J. Dunn, E.N. Rizkalla, H. Imura and G.R. Choppin, Invest. Radiol., 26 (1991) S229.
27. C.F.G.C. Geraldes, A.M. Urbano, M.A. Hoefnagel and J.A. Peters, Inorg. Chem., 32 (1993) 2426.
28. M.B. Robin, F.A. Bovey and H. Basch, Molecular and Electronic Structure of the Amide Group, in J. Zabicky (ed.), The Chemistry of the Amides, Interscience, New York, 1970, p. 1.
29. C.F.G.C. Geraldes, A.M. Urbano, M.C. Alpoim, A.D. Sherry, K.T. Kuam, R. Rajagojslan, F. Maton and R.N. Muller, Mag. Reson. Imaging, 13 (1995) 401.
30. G.R. Choppin, P.A. Bertrand, Y. Hasegawa and E.N. Rizkalla, Inorg. Chem., 21 (1982) 3922.
31. A.E. Martell and R.M. Smith, Critical Stability Constants, Vol. 3, Plenum, New York, 1977.
32. G. Degisher and G.R. Choppin, J. Inorg. Nucl. Chem., 34 (1972) 2823.