Highly ordered alignment of a vinyl polymer by host-guest cross-polymerization

Nature Chemistry

Volumn 5, Issue 4, 2013, Pages 335-341

  Distefano, Gaetano ^a   Suzuki, Hirohito ^b   Tsujimoto, Masahiko ^c   Isoda, Seiji ^a   Bracco, Silvia ^a   Comotti, Angiolina ^a   Sozzani, Piero ^a   Uemura, Takashi ^b   Kitagawa, Susumu ^b,c  

^a UNIVERSITY OF MILANO BICOCCA   (Italy)

^b KYOTO UNIVERSITY   (Japan)

^c KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CROSS LINKING REAGENT; POLYVINYL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; POLYMERIZATION; POROSITY; POWDER DIFFRACTION; STEREOISOMERISM; SURFACE PROPERTY; SYNTHESIS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

CROSS-LINKING REAGENTS; MICROSCOPY, ELECTRON, TRANSMISSION; MOLECULAR STRUCTURE; POLYMERIZATION; POLYVINYLS; POROSITY; POWDER DIFFRACTION; STEREOISOMERISM; SURFACE PROPERTIES; X-RAY DIFFRACTION;

MLCS; MLOWN;

EID: 84875457197     PISSN: 17554330     EISSN: 17554349     Source Type: Journal    
DOI: 10.1038/nchem.1576     Document Type: Article

References (57)

1. Martin, C. R. Template synthesis of electronically conductive polymer nanostructures. Acc. Chem. Res. 28, 61-68 (1995).
2. Akagi, K. & Shirakawa, H. Morphological alignment of liquid crystalline conductive polyacetylene derivatives. Macromol. Symp. 104, 137-158 (1996).
3. Lee, J. I. et al. Highly aligned ultrahigh density arrays of conducting polymer nanorods using block copolymer templates. Nano Lett. 8, 2315-2320 (2008).
4. Natta, G., Corradini, P. & Bassi, I. B. Crystal structure of isotactic polystyrene. Il Nuovo Cimento 15, 68-82 (1960).
5. Farina, M. The stereochemistry of linear macromolecules. Top. Stereochem. 17, 1-111 (1987).
6. Kaminsky, W. Highly active metallocene catalysts for olefin polymerization. J. Chem. Soc. Dalton Trans. 1413-1418 (1998).
7. Toney, M. F. et al. Near-surface aligment of polymers in rubbed films. Nature 347, 709-711 (1995).
8. Rothemund, P. W. K. Folding DNA to create nanoscale shapes and patterns. Nature 440, 297-302 (2006).
9. Kubo, Y. et al. A supramolecular bundling approach toward the alignment of conjugated polymers. Angew. Chem. Int. Ed. 45, 1548-1553 (2006).
10. Sozzani, P., Bovey, F. A. & Schilling, F. C. Characterization of isolated polyethylene chains in the solid state. Macromolecules 24, 6764-6768 (1991).
11. Lauher, J. W., Fowler, F. W. & Goroff, N. S. Single-crystal-to- single-crystal topochemical polymerizations by design. Acc. Chem. Res. 41, 1215-1229 (2008).
12. Matsumoto, A. Polymer structure control based on crystal engineering for material design. Polym. J. 35, 93-121 (2003).
13. Kissel, P. et al. A two-dimensional polymer prepared by organic synthesis. Nature Chem. 4, 287-291 (2012).
14. Grell, M., Bradley, D. D. C., Inbasekaran, M. & Woo, E. P. A glass-forming conjugated main-chain liquid crystal polymer for polarized electroluminescence applications. Adv. Mater. 9, 798-802 (1997).
15. Schmidt, B. V. K. J., Fechler, N., Falkenhagen, J. & Lutz, J-F. Controlled folding of synthetic polymer chains through the formation of positionable covalent bridges. Nature Chem. 3, 234-238 (2011).
16. Svec, F. & Fréchet, J. M. J. New design of macroporous polymers and supports: from separation to biocatalysis. Science 273, 205-211 (1996).
17. Malik, M. A., Ali, S. W. & Ahmed, I. Sulfonated styrene- divinylbenzene resins: optimizing synthesis and estimating characteristics of the base copolymers and the resins. Ind. Eng. Chem. Res. 49, 2608-2612 (2010).
18. O'Keeffe, M. & Yaghi, O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 112, 675-702 (2012).
19. Ferey, G. Hybrid porous solids: past, present, future. Chem. Soc. Rev. 37, 191-214 (2008).
20. Murray, L. J., Dinca, M. & Long, J. R. Hydrogen storage in metal-organic frameworks. Chem. Soc. Rev. 38, 1294-1314 (2009).
21. Kitagawa, S., Kitaura, R. & Noro, S. Functional porous coordination polymers. Angew. Chem. Int. Ed. 43, 2334-2375 (2004).
22. Li, J-R., Sculley, J. & Zhou, H. C. Metal-organic frameworks for separations. Chem. Rev. 112, 869-932 (2012).
23. Shimizu, G. K. H., Vaidhyanathan, R. & Taylor J. M. Phosphonate and sulfonate metal organic frameworks. Chem. Soc. Rev. 38, 1430-1449 (2009).
24. Cohen, S. Postsynthetic methods for the functionalization of metal-organic frameworks. Chem. Rev. 112, 970-1000 (2012).
25. Wang, Z., Chen, G. & Ding, K. Self-suported catalysts. Chem. Rev. 109, 322-359 (2009).
26. Corma, A., Garcia, H. & Llabrési Xamena, F. X. Engineering metal organic frameworks for heterogeneous catalysis. Chem. Rev. 110, 4606-4655 (2010).
27. Uemura, T., Yanai, N. & Kitagawa, S. Polymerization reactions in porous coordination polymers. Chem. Soc. Rev. 38, 1228-1236 (2009).
28. Lee, J. Y. et al. Metal-organic framework materials as catalysts. Chem. Soc. Rev. 38, 1450-1459 (2009).
29. Uemura, T., Ono, Y., Kitagawa, K. & Kitagawa, S. Radical polymerization of vinyl monomers in porous coordination polymers: nanochannel size effects on reactivity, molecular weight and stereostructure. Macromolecules 41, 87-94 (2008).
30. Uemura, T., Ono, Y., Hijikata, Y. & Kitagawa, S. Functionalization of coordination nanochannels for controlling tacticity in radical vinyl polymerization. J. Am. Chem. Soc. 132, 4917-4924 (2010).
31. Uemura, T. et al. Conformation and molecular dynamics of single polystyrene chain confined in coordination nanospace. J. Am. Chem. Soc. 130, 6781-6788 (2008).
32. Fukushima, T. et al. Solid solution of soft porous coordination polymers: fine-tuning of gas adsorption properties. Angew. Chem. Int. Ed. 49, 4820-4824 (2010).
33. Deng, H. et al. Multiple functional groups of varying ratios in metal-organic frameworks. Science 327, 846-850 (2010).
34. Carson, C. G. et al. Synthesis and structure characterization of copper terephthalate metal-organic frameworks. Eur. J. Inorg. Chem. 16, 2338-2343 (2009).
35. Vinagradov, E., Madhu, P. K. & Vega, S. High-resolution proton solid-state NMR spectroscopy by phase-modulated Lee-Goldburg experiment. Chem. Phys. Lett. 314, 443-450 (1999).
36. Glans, J. H. & Turner, D. T. Glass transition elevation of polystyrene by crosslinks. Polymer 22, 1540-1543 (1981).
37. Li, Y., Fan, Y. & Ma, J. Thermal, physical and chemical stability of porous polystyrene-type beads with different degrees of crosslinking. Polym. Degrad. Stab. 73, 163-167 (2001).
38. Sozzani, P. et al. Complete shape retention in the transformation of silica to polymer micro-objects. Nature Mater. 5, 545-551 (2006).
39. Distefano, G., Comotti, A., Bracco, S., Beretta, M. & Sozzani, P. Porous dipeptide crystals as polymerization nanoreactors. Angew. Chem. Int. Ed. 51, 9258-9262 (2012).
40. Cepak, V. M. & Martin, C. R. Preparation of polymeric micro-and nanostructures using a template-based deposition method. Chem. Mater. 11, 1363-1367 (1999).
41. Moon, S. I. & McCarthy, T. J. Template synthesis and self-assembly of nanoscopic polymer 'pencils'. Macromolecules 36, 4253-4255 (2003).
42. Thomas, A., Goettmann, F. & Antonietti, M. Hard templates for soft materials: creating nanostructured organic materials. Chem. Mater. 20, 738-755 (2008).
43. Johnson, S. A., Brigham, E. S., Ollivier, P. J. & Mallouk, T. E. Effect of micropore topology on the structure and properties of zeolite polymer replicas. Chem. Mater. 9, 2448-2458 (1997).
44. Nyquist, R. A., Putzig, C. L., Leugers, M. A., McLachlan, R. D. & Thill, B. Comparison of the vibrational spectra and assignments for a-syndiotactic, b-syndiotactic, isotactic and atactic polystyrene and toluene. Appl. Spectrosc. 46, 981-987 (1992).
45. Reynolds, N. M., Savage, J. D. & Hsu, S. L. A spectroscopic study of syndiotactic polystyrene. Macromolecules 22, 2867-2869 (1989).
46. Kobayashi, M., Nakaoki, T. & Ishihara, N. Molecular conformation in glasses and gels of syndiotactic and isotactic polystyrenes. Macromolecules 23, 78-83 (1990).
47. Krimm, S. & Tobolsky, A. V. Quantitative X-ray studies of order in amorphous and crystalline polymers: scattering from various polymers and a study of the glass transition in polystyrene and polymethyl methacrylate. Text. Res. J. 21, 805-822 (1951).
48. White, D. M. Stereospecific polymerization in urea canal complexes. J. Am. Chem. Soc. 82, 5678-5685 (1960).
49. Di Silvestro, G. & Sozzani, P. Polymerization in clathrates. Comprehensive Polymer Science 4, 303-315 (1989).
50. Allcock, H. R., Silverberger, E. N. & Dudley, G. K. Stereocontrolled polymerization within a cyclophosphazene clathrate tunnel system. Macromolecules 27, 1033-1038 (1994).
51. Ishihara, N., Seimiya, T., Kuramoto, M. & Uoi, M. Crystalline syndiotactic polystyrene. Macromolecules 19, 2464-2465 (1986).
52. Wang, L-H., Choy, C. L. & Porter, R. S. Thermal expansion of ultradrawn polystyrene. J. Polym. Sci. 20, 633-640 (1982).
53. Brandrup, J. & Immergut, E. H. Polymer Handbook 3rd edn (Wiley-Interscience, 1989).
54. Boyer, R. F. in Encyclopedia of Polymer Science and Technology Vol. 13 (ed. Mark, H. F.) 251-326 (Wiley, 1970).
55. Hay, J. N. Crystallization kinetics of high polymers: isotactic polystyrene. J. Polym. Sci. A 3, 433-447 (1965).
56. Levchik, G. F., Si, K., Levchik, S. V., Camino, G. & Wilkie, C. A. The correlation between cross-linking and thermal stability: cross-linked polystyrenes and polymethacrylates. Polym. Degrad. Stab. 65, 395-403 (1999).
57. Bonifacio, M. C., Robertson, C. R., Jung, J. Y. & King, B. T. Polycyclic aromatic hydrocarbons by ring-closing metathesis. J. Org. Chem. 70, 8522-8526 (2005).