Sulfonated styrene-divinybenzene resins: Optimizing synthesis and estimating characteristics of the base copolymers and the resins

Industrial and Engineering Chemistry Research

Volumn 49, Issue 6, 2010, Pages 2608-2612

  Malik, Muhammad Arif ^a,b   Ali, Syed Wasim ^a   Ahmed, Imtiaz ^a  

^a PAKISTAN INSTITUTE OF NUCLEAR SCIENCE AND TECHNOLOGY   (Pakistan)

^b OLD DOMINION UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATION EXCHANGE RESINS; OPTIMUM CONDITIONS; PORE VOLUME; POROGENS; STATISTICAL ANALYSIS; STYRENE-DIVINYLBENZENE;

CARBOXYLATION; COPOLYMERIZATION; COPOLYMERS; OPTIMIZATION; POROSITY; STYRENE; SULFONATION;

RESINS;

EID: 77949348994     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie902057x     Document Type: Article

References (28)

1. Kun, K. A.; Kunin, R. Macroreticular resins. III. Formation of macroreticular styrene-divinylbenzene copolymers. J. Polym. Sci., Part A: Polym. Chem. 1968, 6 (10), 2689.
2. Seidl, J.; Malinský, J.; Dušek, K.; Heitz, W. Makroporöse Styrol- Divinylbenzol- Copolymere und ihre Verwendung in der Chromatographie und zur Darstellung von Ionenaustauschern. Adv. Polym. Sci. 1967, 5, 113.
3. Sederel, W. L.; De Jong, G. J. Styrene-divinylbenzene copolymers. Construction of porosity in styrene divinylbenzene matrices. J. Appl. Polym. Sci. 1973, 17, 2835.
4. Jacobelli, H.; Bartholin, M.; Guyot, A. Styrene divinylbenzene copolymers. 1. Texture of macroporous copolymers with ethyl-2-hexanoic acid in diluent. J. Appl. Polym. Sci. 1979, 23, 927.
5. Dorfner, K. Ion Exchangers; Walter de Gruyter: New York, 1991.
6. Alexandratos, S. D. Ion-Exchange Resins: A Retrospective from Industrial and Engineering Chemistry Research. Ind. Eng. Chem. Res. 2009, 48, 388. 388.
7. Barbaro, P.; Liguori, F. Ion Exchange Resins: Catalyst Recovery and Recycle. Chem. Rev. 2009, 109, 515.
8. Guyot, A.; Bartholin, M. Design and properties of polymers as materials for fine chemistry. Prog. Polym. Sci. 1982, 8, 277.
9. Arshady, R. Beaded polymer supports and gels: I. Manufacturing techniques. J. Chromatogr. 1991, 586, 181.
10. Arshady, R. Beaded polymer supports and gels: II. Physico-chemical criteria and functionalization. J. Chromatogr. 1991, 586, 199.
11. Svec, F.; Frechet, J. M. J. New designs of macroporous polymers and supports: Form separation to biocatalysis. Science 1996, 273, 205.
12. Okay, O. Macroporous copolymer networks. Prog. Polym. Sci. 2000, 25, 711.
13. Liu, Q.; Wang, L.; Xiao, A. Research progress in macroporous styrene-divinylbenzene co-polymer microspheres. Des. Monomers Polym. 2007, 10, 405.
14. Garcia-Diego, C.; Cuellar, J. Synthesis of Macroporous Poly(styreneco- divinylbenzene) Microparticles Using n-Heptane as the Porogen: Quantitative Effects of the DVB Concentration and the Monomeric Fraction on Their Structural Characteristics. Ind. Eng. Chem. Res. 2005, 44, 8237.
15. Garcia-Diego, C.; Cuellar, J. Determination of the Quantitative Relationships between the Synthesis Conditions of Macroporous Poly(styreneco- divinylbenzene) Microparticles and the Characteristics of Their Behavior as Adsorbents Using Bovine Serum Albumin as a Model Macromolecule. Ind. Eng. Chem. Res. 2006, 45, 3624.
16. Dragan, E. S.; Avram, E.; Dinu, M. V. Organic ion exchangers as beads. Synthesis, characterization and applications. Polym. Adv. Technol. 2006, 17, 571.
17. Malik, M. A.; Ali, S. W.; Waseem, S. A Simple Method for Estimating Parameters Representing Macroporosity of Porous Styrene- Divinylbenzene Copolymers. J. Appl. Polym. Sci. 2006, 99, 3565.
18. Scheler, S. A Novel Approach to the Interpretation and Prediction of Solvent Effects in the Synthesis of Macroporous Polymers. J. Appl. Polym. Sci. 2007, 105, 3121.
19. Garcia-Diego, C.; Cuellar, J. Design of polymeric microparticles with improved structural properties: Influence of ethylstyrene monomer and of high proportions of crosslinker. Eur. Polym. J. 2008, 44, 1487.
20. Topp, N. E.; Pepper, K. W. Properties of ion-exchange resins in relation to their structure. Part I. Titration curves. J. Chem. Soc. 1949, 3299.
21. Holboke, A. E.; Pinnell, R. P. Sulfonation of polystyrene: Preparation and characterization of an ion exchange resin in organic laboratory. J. Chem. Educ. 1989, 66 (7), 613.
22. Ahmed, M.; Malik, M. A.; Pervez, S.; Raffiq, M. Effect of porosity on sulfonation of macroporous styrene-divinylbenzene beads. Eur. Polym. J. 2004, 40, 1609.
23. Oliveira, A. J. B.; Aguiar, A. P.; Aguiar, M. R. M. P.; Santa Maria, L. C. How to maintain the morphology of styrene-divinylbenzene copolymer beads during the sulfonation reaction. Mater. Lett. 2005, 59, 1089.
24. Toro, C. A.; Rodrigo, R.; Cuellar, J. Sulfonation of macroporous poly(styrene-co-divinylbenzene) beads: Effect of the proportion of isomers on their cation exchange capacity. React. Funct. Polym. 2008, 68, 1325.
25. Malik, M. A. Carbonyl Groups in Sulfonated Styrene-Divinylbenzene Macroporous Resins. Ind. Eng. Chem. Res. 2009, 48, 6961.
26. Malik, M. A.; Naheed, R. Porous 4-Vinylpyridine-Divinylbenzene CopolymerssVarying Porosity in Different Bead Sizes of a Single Batch. e-Polym. 2007, no.135.
27. Malik, M. A.; Ahmed, M.; Ikram, M. A new method to estimate pore volume of porous styrenesdivinylbenzene copolymers. Polym. Test. 2004, 23, 835.
28. Malik, M. A.; Rehman, E.; Naheed, R.; Alam, N. M. Pore volume determination by density of porous copolymer beads in dry state. React Funct. Polym. 2002, 50, 125.