The water-hydrophobic interface: Neutral and charged solute adsorption at fluorocarbon and hydrocarbon self-assembled monolayers (SAMs)

Applied Spectroscopy

Volumn 67, Issue 3, 2013, Pages 261-273

  Hopkins, Adam J ^a,b   Richmond, Geraldine L ^a  

^a UNIVERSITY OF OREGON   (United States)

^b Alakai Defense Systems   (United States)

Author keywords

Amine; Interface; Methanol; Sum frequency; Surfactant; Water

Indexed keywords

ADSORPTION PROCESS; COMPLEX STRUCTURE; HYDROPHOBIC SURFACES; INDUSTRIAL SYSTEMS; MOLECULAR SOLUTE; SUM FREQUENCY; SURFACE FUNCTIONALITIES; VIBRATIONAL SUM-FREQUENCY SPECTROSCOPIES;

AMINES; CHLORINE COMPOUNDS; HYDROCARBONS; HYDROPHOBICITY; INTERFACES (MATERIALS); METHANOL; SELF ASSEMBLED MONOLAYERS; SURFACE ACTIVE AGENTS; SURFACE CHEMISTRY; WATER;

ADSORPTION;

BUTYLAMINE; FLUOROCARBON; HYDROCARBON; METHANOL; N-BUTYLAMINE; WATER;

ADSORPTION; ARTICLE; CHEMICAL PHENOMENA; CHEMISTRY; INFRARED SPECTROPHOTOMETRY; SURFACE PROPERTY;

ADSORPTION; BUTYLAMINES; FLUOROCARBONS; HYDROCARBONS; HYDROPHOBIC AND HYDROPHILIC INTERACTIONS; METHANOL; SPECTROPHOTOMETRY, INFRARED; SURFACE PROPERTIES; WATER;

EID: 84875444715     PISSN: 00037028     EISSN: 19433530     Source Type: Journal    
DOI: 10.1366/12-06631     Document Type: Article

References (88)

1. E. Pierstorff, R. Lam, D. Ho. "Nanoscale Architectural Tuning of Parylene Patch Devices to Control Therapeutic Release Rates". Nanotechnology. 2008. 19(44): 445104.
2. K.C. Wood, J.Q. Boedicker, D.M. Lynn, P.T. Hammon. "Tunable Drug Release from Hydrolytically Degradable Layer-By-Layer Thin Films". Langmuir. 2005. 21(4): 1603-1609. (Pubitemid 40275101)
3. S. Takeuchi, D. Ziegler, Y. Yoshida, K. Mabuchi, T. Suzuki. "Parylene Flexible Neural Probes Integrated with Microfluidic Channels". Lab Chip. 2005. 5(5): 519-523. (Pubitemid 40676818)
4. A.B. Fontaine, K. Koelling, S. DosPassos, J. Cearlock, R. Hoffman, D.G. Spigos. "Polymeric Surface Modifications of Tantalum Stents". J. Endovasc. Surg. 1996. 3(3): 276-283. (Pubitemid 26303989)
5. M. Szycher, A. Armini. "Microporous Coating Provides Superior Stent". Membrane Separation Technol. News. 2003. 21(10): 12.
6. R. Maboudian, C. Carraro. "Surface Chemistry and Tribology of MEMS". Annu. Rev. Phys. Chem. 2004. 55: 35-54.
7. R.P. Ambekar, D.B. Bogy, C.S. Bhatia. "Lubricant Depletion and Disk-to-Head Lubricant Transfer at the Head-Disk Interface in Hard Disk Drives". J. Tribol. 2009. 131(3): 1519-1526.
8. x Overcoat". Langmuir. 2001. 17(20): 6240-6247. (Pubitemid 35330700)
9. Q. Du, E. Freysz, Y.R. Shen. "Vibrational Spectra of Water Molecules at Quartz-Water Interfaces". Phys. Rev. Lett. 1994. 72(2): 238-241. (Pubitemid 24975352)
10. S. Ye, S. Nihonyanagi, K. Uosaki. "Sum Frequency Generation (SFG) Study of the pH-Dependent Water Structure on a Fused Quartz Surface Modified by an Octadecyltrichlorosilane (OTS) Monolayer". Phys. Chem. Chem. Phys. 2001. 3(16): 3463-3469. (Pubitemid 32881491)
11. V. Ostroverkhov, G.A. Waychunas, Y.R. Shen. "Vibrational Spectra of Water at Water-α-Quartz (0 0 0 1) Interface". Chem. Phys. Lett. 2004. 386(1-3): 144-148.
12. V. Ostroverkhov, G.A. Waychunas, Y.R. Shen. "New Information on Water Interfacial Structure Revealed by Phase-Sensitive Surface Spectros-copy". Phys. Rev. Lett. 2005. 94(4): 046102/1-046102/4.
13. K.C. Jena, D.K. Hore. "Variation of Ionic Strength Reveals The Interfacial Water Structure at a Charged Mineral Surface". J. Phys. Chem. C. 2009. 113(34): 15364-15372.
14. H. Noguchi, M. Hiroshi, T. Tominaga, J.P. Gong, Y. Osada, K. Uosaki. "Interfacial Water Structure at Polymer Gel-Quartz Interfaces Investigated by Sum Frequency Generation Spectroscopy". Phys. Chem. Chem. Phys. 2008. 10(32): 4987-4993.
15. J. Kim, G. Kim, P.S. Cremer. "Investigations of Polyelectrolyte Adsorption at The Solid-Liquid Interface by Sum Frequency Spectroscopy: Evidence for Long-Range Macromolecular Alignment at Highly Charged Quartz-Water Interfaces". J. Am. Chem. Soc. 2002. 124(29): 8751-8756. (Pubitemid 34791046)
16. A.J. Hopkins, C.L. McFearin, G.L. Richmond. "SAMs Under Water: The Impact of Ions on the Behavior of Water at Soft Hydrophobic Surfaces". J. Phys. Chem. C. 2011. 115(22): 11192-11203.
17. R.N. Ward, P.B. Davies, C.D. Bain. "Orientation of Surfactants Adsorbed on a Hydrophobic Surface". J. Phys. Chem. 1993. 97(28): 7141-7143.
18. C.D. Bain, P.B. Davies, R.N. Ward. "In Situ Sum Frequency Spectroscopy of Sodium Dodecyl Sulfate and Dodecanol Co-adsorbed at a Hydrophobic Surface". Langmuir. 1994. 10(7): 2060-2063.
19. R.N. Ward, P.B. Davies, C.D. Bain. "Co-adsorption of Sodium Dodecyl Sulfate and Dodecanol at a Hydrophobic Surface". J. Phys. Chem. B. 1997. 101(9): 1594-1601. (Pubitemid 127628032)
20. R. Windsor, D.J. Neivandt, P.B. Davies. "Adsorption of Sodium Dodecyl Sulfate in the Presence of Poly(ethylenimine) and Sodium Chloride Studied Using Sum Frequency Vibrational Spectroscopy". Langmuir. 2001. 17(23): 7306-7312. (Pubitemid 35338211)
21. M.T.L. Casford, P.B. Davies, D.J. Neivandt. "Study of the Co-adsorption of an Anionic Surfactant and an Uncharged Polymer at the Aqueous Solution-Hydrophobic Surface Interface by Sum Frequency Spectroscopy". Langmuir. 2003. 19(18): 7386-7391.
22. R. Windsor, D.J. Neivandt, P.B. Davies. "Temperature and pH Effects on the Co-adsorption of Sodium Dodecyl Sulfate and Poly(ethylenimine)". Langmuir. 2002. 18(6): 2199-2204. (Pubitemid 35383908)
23. J. Kim, T.S. Koffas, C.C. Lawrence, G.A. Somorjai. "Surface Structural Characterization of Protein- and Polymer-Modified Polystyrene Micro-spheres by Infrared-Visible Sum Frequency Generation Vibrational Spectroscopy and Scanning Force Microscopy". Langmuir. 2004. 20(11): 4640-4646.
24. M.T.L. Casford, P.B. Davies, N.J. Neivandt. "Adsorption of Sodium Dodecyl Sulfate at the Hydrophobic Solid-Aqueous Solution Interface in the Presence of Poly(ethylene glycol): Dependence upon Polymer Molecular Weight". Langmuir. 2006. 22(7): 3105-3111.
25. Z. Chen, R. Ward, Y. Tian, F. Malizia, D.H. Gracias, Y.R. Shen, G.A. Somorjai. "Interaction of Fibrinogen with Surfaces of End-Group-Modified Polyurethanes: A Surface-Specific Sum Frequency-Generation Vibrational Spectroscopy Study". J Biomed. Mater. Res. 2002. 62(2): 254-264. (Pubitemid 34988503)
26. J. Kim, G.A. Somorjai. "Molecular Packing of Lysozyme, Fibrinogen, and Bovine Serum Albumin on Hydrophilic and Hydrophobic Surfaces Studied by Infrared-Visible Sum Frequency Generation and Fluorescence Microscopy". J. Am. Chem. Soc. 2003. 125(10): 3150-3158. (Pubitemid 36512540)
27. J. Wang, M.A. Even, X. Chen, A.H. Schmaier, J.H. Waite, Z. Chen. "Detection of Amide I Signals of Interfacial Proteins In Situ Using SFG". J. Am. Chem. Soc. 2003. 125(33): 9914-9915. (Pubitemid 36994908)
28. X. Chen, M.L. Clarke, J. Wang, Z. Chen. "Sum Frequency Generation Vibrational Spectroscopy Studies on Molecular Conformation and Orientation of Biological Molecules at Interfaces". Int. J. Mod. Phys. B. 2005. 19(4): 691-713. (Pubitemid 40546365)
29. X.Y. Chen, J. Wang, J.J. Sniadecki, M.A. Even, Z. Chen. "Probing Alpha-Helical and Beta-Sheet Structures of Peptides at Solid-Liquid Interfaces with SFG". Langmuir. 2005. 21(7): 2662-2664. (Pubitemid 40448923)
30. J. Wang, M.L. Clarke, X. Chen, M.A. Even, W.C. Johnson, Z. Chen. "Molecular Studies on Protein Conformations at Polymer-Liquid Interfaces Using Sum Frequency Generation Vibrational Spectroscopy". Surf. Sci. 2005. 587(1-2): 1-11. (Pubitemid 41013867)
31. D.C. Phillips, R.L. York, O. Mermut, K.R. McCrea, R.S. Ward, G.A. Somorjai. "Side Chain, Chain Length, and Sequence Effects on Amphiphilic Peptide Adsorption at Hydrophobic and Hydrophilic Surfaces Studied by Sum Frequency Generation Vibrational Spectroscopy and Quartz Crystal Microbalance". J. Phys. Chem. C. 2007. 111(1): 255-261. (Pubitemid 46353220)
32. D. Wang, R.D. Oleschuk, J.H. Horton. "Surface Modification of Poly(Dimethylsiloxane) with a Perfluorinated Alkoxysilane For Selectivity Toward Fluorous Tagged Peptides". Langmuir. 2008. 24(3): 1080-1086. (Pubitemid 351270985)
33. A.M. Gaudin, D.W. Fuerstenau. "Streaming Potential Studies - Quartz Flotation with Anionic Collectors". T. Am. I. Min. Met. Eng. 1955. 202: 66-72.
34. D.W. Fuerstenau. "Correlation of Contact Angles, Adsorption Density, Zeta Potentials, and Flotation Rate". T. Am. I. Min. Met. Eng. 1957. 208:(7): 1365-1367.
35. D.W. Fuerstenau. "Streaming Potential Studies on Quartz in Solutions of Ammonium Acetates in Relation to the Formation of Hemi-micelles at the Quartz-Solution Interface". J. Phys. Chem. 1956. 60981-985.
36. M.C. Fuerstenau, K.N. Han. "Metal-Surfactant Precipitation and Adsorption in Froth Flotation". J. Colloid Interface Sci. 2002. 256(1): 175-182. (Pubitemid 36164589)
37. D.W. Fuerstenau, R.H. Jia. "The Adsorption of Alkylpyridinium Chlorides and Their Effect on the Interfacial Behavior of Quartz". Colloids Surf., A. 2004. 250(1-3): 223-231. (Pubitemid 39610802)
38. D.W. Fuerstenau, Pradip "Zeta Potentials in the Flotation of Oxide and Silicate Minerals". Adv. Colloid Interface Sci. 2005. 114-115: 9-26. (Pubitemid 40744100)
39. I.V. Chernyshova, K.H. Rao, A. Vidyadhar, A.V. Shchukarev. "Mechanism of Adsorption of Long-Chain Alkylamines on Silicates: A Spectroscopic Study. 1. Quartz". Langmuir. 2000. 16(21): 8071-8084.
40. I.V. Chernyshova, K.H. Rao, A. Vidyadhar, A.V. Shchukarev. "Mechanism of Adsorption of Long-Chain Alkylamines on Silicates: A Spectroscopic Study. 2. Albite". Langmuir. 2001. 17(3): 775-785. (Pubitemid 32873092)
41. A. Vidyadhar, K.H. Rao, I.V.P. Chernyshova, K.S.E. Forssberg. "Mechanisms of Amine-Quartz Interaction in the Absence and Presence of Alcohols Studied by Spectroscopic Methods". J. Colloid Interface Sci. 2002. 256(1): 59-72. (Pubitemid 36164577)
42. E. Tyrode, M.W. Rutland, C.D. Bain. "Adsorption of CTAB on Hydrophilic Silica Studied by Linear and Nonlinear Optical Spectroscopy". J. Am. Chem. Soc. 2008. 130(51): 17434-17445.
43. X.M. Wang, J. Liu, H. Du, J.D. Miller. "States of Adsorbed Dodecyl Amine and Water at a Silica Surface as Revealed by Vibrational Spectroscopy". Langmuir. 2010. 26(5): 3407-3414.
44. W.T. Liu, L. Zhang, Y. Shen. "Interfacial Layer Structure at Alcohol- Silica Interfaces Probed by Sum Frequency Vibrational Spectroscopy". Chem. Phys. Lett. 2005. 412(1-3): 206-209. (Pubitemid 41085111)
45. P. Guyot-Sionnest, J.H. Hunt, Y.R. Shen. "Sum Frequency Vibrational Spectroscopy of a Langmuir Film: Study of Molecular Orientation of a Two-Dimensional System". Phys. Rev. Lett. 1987. 59(14): 1597-1560.
46. Q. Du, E. Freysz, Y.R. Shen. "Surface Vibrational Spectroscopic Studies of Hydrogen-Bonding and Hydrophobicity". Science. 1994. 264(5160): 826-828. (Pubitemid 24194330)
47. P.B. Miranda, Y.R. Shen. "Liquid Interfaces: A Study by Sum Frequency Vibrational Spectroscopy". J. Phys. Chem. B. 1999. 103(17): 3292-3307. (Pubitemid 129701968)
48. L.F. Scatena, G.L. Richmond. "Orientation, Hydrogen Bonding, and Penetration of Water at the Organic-Water Interface". J. Phys. Chem. B. 2001. 105(45): 11240-11250. (Pubitemid 35338475)
49. V. Buch, T. Tarbuck, G.L. Richmond, H. Groenzin, I. Li, M.J. Shultz. "Sum Frequency Generation Surface Spectra of Ice, Water, and Acid Solution Investigated by an Exciton Model". J. Chem. Phys. 2007. 127(20): 204710.
50. Y.R. Shen. the Principles of Nonlinear Optics. New York: John Wiley, 1984.
51. C.D. Bain. "Sum Frequency Vibrational Spectroscopy of the Solid-Liquid Interface". J. Chem. Soc., Faraday Trans. 1995. 91(9): 1281-96.
52. K.B. Eisenthal. "Liquid Interfaces Probed by Second-Harmonic and Sum Frequency Spectroscopy". Chem. Rev. 1996. 96(4): 1343-1360. (Pubitemid 126639358)
53. G.L. Richmond. "Molecular Bonding and Interactions at Aqueous Surfaces as Probed by Vibrational Sum Frequency Spectroscopy". Chem. Rev. 2002. 102(8): 2693-2724. (Pubitemid 35381646)
54. A.J. Hopkins, C.L. McFearin, G.L. Richmond. "Investigations of the Solid-Aqueous Interface with Vibrational Sum Frequency Spectroscopy". Curr. Opin. Solid State Mater. Sci. 2005. 9(1-2): 19-27. (Pubitemid 43949074)
55. Y.R. Shen, V. Ostroverkhov. "Sum Frequency Vibrational Spectroscopy on Water Interfaces: Polar Orientation of Water Molecules at Interfaces". Chem. Rev. 2006. 106(4): 1140-1154.
56. A.J. Hopkins. In situ analysis of aqueous structure and adsorption at fluorocarbon, hydrocarbon and mineral surfaces. [Ph.D. Dissertation] Eugene, OR: University of Oregon, 2010.
57. C.D. Bain, P.B. Davies, T.H. Ong, R.N. Ward, M.A. Brown. "Quantitative Analysis of Monolayer Composition by Sum Frequency Vibrational Spectroscopy". Langmuir. 1991. 7(8): 1563-1566. (Pubitemid 21737622)
58. S.R. Goates, D.A. Schofield, C.D. Bain. "A Study of Nonionic Surfactants at the Air-Water Interface by Sum Frequency Spectroscopy and Ellipsometry". Langmuir. 1999. 15(4): 1400-1409.
59. R.L. Pizzolatto, Y.J. Yang, L.K. Wolf, M.C. Messmer. "Conformational Aspects of Model Chromatographic Surfaces Studied by Sum Frequency Generation". Anal. Chim. Acta. 1999. 397(1-3): 81-92. (Pubitemid 29443926)
60. E.A. Raymond, G.L. Richmond. "Probing the Molecular Structure and Bonding of the Surface of Aqueous Salt Solutions". J. Phys. Chem. B. 2004. 108(16): 5051-5059.
61. C.L. McFearin, G.L. Richmond. "Understanding How Organic, Solvent Polarity Affects Water Structure and Bonding at Halocarbon-Water Interfaces". J. Mol. Liq. 2007. 136(3): 221-226. (Pubitemid 350026096)
62. D.S. Walker, M. Brown, C.L. McFearin, G.L. Richmond. "Evidence for a Diffuse Interfacial Region at the Dichloroethane-Water Interface". J. Phys. Chem. B. 2004. 108(7): 2111-2114.
63. C.L. McFearin, G.L. Richmond. "The Unique Molecular Behavior of Water at the Chloroform-Water Interface". Appl. Spectrosc. 2010. 64(9): 986-994.
64. L.F. Scatena, M.G. Brown, G.L. Richmond. "Water at Hydrophobic Surfaces: Weak Hydrogen Bonding and Strong Orientation Effects". Science. 2001. 292(5518): 908-912. (Pubitemid 32422483)
65. P. Guyot-Sionnest, R. Superfine, J.H. Hunt, Y.R. Shen. "Vibrational Spectroscopy of a Silane Monolayer at Air Solid and Liquid Solid Interfaces Using Sum Frequency Generation". Chem. Phys. Lett. 1988. 144(1): 1-5.
66. C.S. Tian, Y.R. Shen. "Structure and Charging of Hydrophobic Material- Water Interfaces Studied by Phase-Sensitive Sum Frequency Vibrational Spectroscopy". Proc. Natl. Acad. Sci. U. S. A. 2009. 106(36): 15148-15153.
67. W.T. Liu, L. Zhang, Y.R. Shen. "Interfacial Structures of Methanol: Water Mixtures at a Hydrophobic Interface Probed by Sum Frequency Vibrational Spectroscopy". J. Chem. Phys. 2006. 125(14): 144711/1-144711/6.
68. M. Schwartz, A. Moradi-Araghi, W.H. Koehler. "Fermi Resonance in Aqueous Methanol". J. Mol. Struct. 1980. 63(2): 279-285.
69. M. Schwartz, A. Moradi-Araghi, W.H. Koehler. "Solvent and Temperature Dependence of the Fermi Resonance Parameters in Methanol". J. Mol. Struct. 1982. 81245-252.
70. 3 Deformation Vibrations". Spectrochim. Acta, Part A. 1972. 28(11): 2091-2101.
71. C.J. Gruenloh, G.M. Florio, J.R. Carney, F.C. Hagemeister, T.S. Zwier. "C-H Stretch Modes as a Probe of H-Bonding in Methanol-Containing Clusters". J. Phys. Chem. A. 1999. 103(4): 496-502. (Pubitemid 129590578)
72. S. Dixit, W.C.K. Poon, J. Crain. "Hydration of Methanol in Aqueous Solutions: A Raman Spectroscopic Study". J. Phys. Condens. Matter. 2000. 12(21): L323-L328.
73. G. Ma, H.C. Allen. "Surface Studies of Aqueous Methanol Solutions by Vibrational Broad Bandwidth Sum Frequency Generation Spectroscopy". J. Phys. Chem. B. 2003. 107(26): 6343-6349.
74. C.Y. Chen, M.L. Clarke, J. Wang, Z. Chen. "Comparison of Surface Structures of Poly(ethyl methacrylate) and Poly(ethyl acrylate) in Different Chemical Environments". Phys. Chem. Chem. Phys. 2005. 7(11): 2357-2363. (Pubitemid 40855583)
75. U. Buck, F. Huisken. "Infrared Spectroscopy of Size-Selected Water and Methanol Clusters". Chem. Rev. 2000. 100(11): 3863-3890. (Pubitemid 32067781)
76. 2 Trimer". J. Chem. Phys. 1998. 109(1): 139-150. (Pubitemid 128678809)
77. F. Huisken, S. Mohammad-Pooran, O. Werhahn. "Vibrational Spectros-copy of Single Methanol Molecules Attached to Liquid Water Clusters". Chem. Phys. 1998. 239(1-3): 11-22. (Pubitemid 128352062)
78. R.N. Ward, D.C. Duffy, P.B. Davies, C.D. Bain. "Sum Frequency Spectroscopy of Surfactants Adsorbed at a Flat Hydrophobic Surface". J. Phys. Chem. 1994. 98(34): 8536-8542.
79. Y. Liu, L.K. Wolf, M.C. Messmer. "A Study of Alkyl Chain Conformational Changes in Self-assembled N-Octadecyltrichlorosilane Monolayers on Fused Silica Surfaces". Langmuir. 2001. 17(14): 4329-4335. (Pubitemid 35330301)
80. E.A. Raymond, T.L. Tarbuck, G.L. Richmond. "Isotopic Dilution Studies of the Vapor-Water Interface as Investigated by Vibrational Sum Frequency Spectroscopy". J. Phys. Chem. B. 2002. 106(11): 2817-2820. (Pubitemid 35290289)
81. H. Chen, W. Gan, R. Lu, Y. Guo, H.F. Wang. "Determination of Structure and Energetics for Gibbs Surface Adsorption Layers of Binary Liquid Mixture. 2. Methanol + Water". J. Phys. Chem. B. 2005. 109(16): 8064-8075.
82. S. Ong, X. Zhao, K.B. Eisenthal. "Polarization of Water Molecules at a Charged Interface: Second Harmonic Studies of the Silica-Water Interface". Chem. Phys. Lett. 1992. 191(3-4): 327-335.
83. P.M. Dove, J.D. Rimstidt. "Silica-Water Interactions". In: P.J. Heany, C.T. Prewitt, G.V. Gibbs, editors. Silica: Physical Behavior, Geochemistry, and Materials Applications. Washington, D.C: Mineralogical Society of America, 1994. Pp. 259.
84. 2-Electrolyte Interfacial Regions". J. Phys. Chem. 1995. 99(10): 3240-3250.
85. J.C. Conboy, M.C. Messmer, G.L. Richmond. "Dependence of Alkyl Chain Conformation of Simple Ionic Surfactants on Head Group Functionality as Studied by Vibrational Sum Frequency Spectroscopy". J. Phys. Chem. B. 1997. 101(34): 6724-6733. (Pubitemid 127617343)
86. B.C. Chow, T.T. Ehler, T.E. Furtak. "High-Resolution Sum Frequency Generation from Alkylsiloxane Monolayers". Appl. Phys. B: Lasers Opt. 2002. 74(4-5): 395-399. (Pubitemid 34300699)
87. 2O-SDS Interface as Studied by Vibrational Sum Frequency Spectroscopy". J. Phys. Chem. B. 2003. 107(16): 3675-3678. (Pubitemid 43677155)
88. K.A. Becraft, G.L. Richmond. "Surfactant Adsorption at the Salt-Water Interface: Comparing the Conformation and Interfacial Water Structure for Selected Surfactants". J. Phys. Chem. B. 2005. 109(11): 5108-5117.