Advanced integral isoconversional analysis for evaluating and predicting the kinetic parameters of the curing reaction of epoxy prepreg

Thermochimica Acta

Volumn 557, Issue , 2013, Pages 37-43

  Vafayan, Mehdy ^a   Hosain Beheshty, Mohammad ^a   Ghoreishy, Mir Hamid Reza ^a   Abedini, Hossein ^a  

^a IRAN POLYMER AND PETROCHEMICAL INSTITUTE   (Iran)

Author keywords

Advanced integral isoconversional; Cure kinetics; Differential scanning calorimetry; Epoxy prepreg; Non isothermal

Indexed keywords

CURE KINETICS; ISO-CONVERSIONAL METHOD; ISOCONVERSIONAL; ISOCONVERSIONAL ANALYSIS; MINIMIZATION PROCEDURES; NONISOTHERMAL; PREEXPONENTIAL FACTOR; PREPREGS;

ACTIVATION ENERGY; CURING; DIFFERENTIAL SCANNING CALORIMETRY; ISOTHERMS;

KINETIC PARAMETERS;

EID: 84874931296     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2013.01.035     Document Type: Article

References (37)

1. T.E. Twardowski, S.E. Lin, and P.H. Geil Curing in thick composite laminates: experiment and simulation J. Compos. Mater. 27 1993 216 250
2. N. Rai, and R. Pitchumani Optimal cure cycles for the fabrication of thermosetting-matrix composites Polym. Compos. 18 1997 566 581
3. J.H. Oh, and D.G. Lee Cure cycle for thick glass/epoxy composite laminates J. Compos. Mater. 36 2002 19 45
4. H.C. Park, N.S. Goo, K.J. Min, and K.J. Yoon Three dimensional cure simulation of composite structures by the finite element method Compos. Struct. 62 2003 51 57
5. R.A. Fava Differentioal scanning calorimetry of epoxy resins Polymer 9 1968 137 151
6. R.B. Prime Differential scanning calorimetry of the epoxy cure reaction Polym. Eng. Sci. 13 1973 365 371
7. M. Opaličkl, J.M. Kenny, and L. Nicolais Cure kinetics of neat and carbon-fiber-reinforced TGDDM/DDS epoxy systems J. Appl. Polym. Sci. 61 1996 1025 1037
8. H. Ng, and I. Manas-Zloczower A non-isothermal differential scanning calorimetry study of the curing kinetics of an unsaturated polyester system Polym. Eng. Sci. 29 1989 1097 1102
9. S. Vyazovkin, and C.A. Wight Model-free and model-fitting approaches to kinetic analysis of isothermal and non-isothermal data Thermochim. Acta 340-341 1999 53 68
10. J. Šestàk, and G. Berggren Study of the kinetics of the mechanism of solid-state reactions at increasing temperatures Thermochim. Acta 3 1971 1 12
11. S. Sourour, and M.R. Kamal Differential scanning calorimetry of epoxy cure: isothermal cure kinetics Thermochim. Acta 14 1976 41 59
12. R.B. Prime, and E. Sacher Kinetics of epoxy cure: 2. The system bisphenol-A diglycidyl ether/polyamide Polymer 13 1972 455 458
13. M.R. Keenan Autocatalytic cure kinetics from DSC measurements: zero initial cure rate J. Appl. Polym. Sci. 33 1987 1725 1734
14. F.Y.C. Boey, and W. Qiang Experimental modeling of the cure kinetics of an epoxy-hexaanhydro-4-methylphthalicanhydride (MHHPA) system Polymer 41 2000 2081 2094
15. C. Jubsilp, K. Punson, T. Takeichi, and S. Rimdusit Curing kinetics of benzoxazine-epoxy copolymer investigated by non-isothermal differential scanning calorimetry Polym. Degrad. Stab. 95 2010 918 924
16. L.F. Yang, K.D. Yao, and W. Koh Kinetics analysis of the curing reaction of fast cure epoxy prepregs J. Appl. Polym. Sci. 73 1999 1501 1508
17. D.D. Shin, and H.T. Hahn A consistent cure kinetic model for AS4/3502 graphite/epoxy Compos. A 31 2000 991 999
18. Q. Wang, T. He, P. Xia, T. Chen, and B. Huang Cure processing modeling and cure cycle simulation of epoxy-terminated poly(phenylene ether ketone). I. DSC characterization of curing reaction J. Appl. Polym. 66 1997 789 797
19. M. Hayaty, M.H. Beheshty, and M. Esfandeh Isothermal differential scanning calorimetry study of a glass/epoxy prepreg Polym. Adv. Technol. 22 2011 1001 1006
20. M. Hayaty, M.H. Beheshty, and M. Esfandeh Cure kinetics of a glass/epoxy prepreg by dynamic differential scanning calorimetry J. Appl. Polym. Sci. 120 2011 62 69
21. S. Vyazovkin, A.K. Burnham, J.M. Criado, L.A. Perez-Maqueda, C. Popescu, and N. Sbirrazzuoli ICTAC kinetics committee recommendations for performing kinetic computations on thermal analysis data Thermochim. Acta 520 2011 1 19
22. H.L. Friedman Kinetics of thermal degradation of char-forming plastics from thermogravimetry, application to a phenolic plastic J. Polym. Sci. C 6 1964 183 195
23. T. Ozawa Estimation of activation energy by isoconversion methods Thermochim. Acta 203 1992 159 165
24. M.J. Starink The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods Thermochim. Acta 404 2003 163 176
25. S. Vyazovkin, and D. Dollimore Linear and nonlinear procedures in isoconversional computations of the activation energy on nonisothermal reactions in solids J. Chem. Inf. Comput. Sci. 36 1996 42 45
26. S. Vyazovkin Evaluation of activation energy of thermally stimulated solid-state reactions under arbitrary variation of temperature J. Comput. Chem. 18 1997 393 402
27. S. Vyazovkin Model-free kinetics: staying free of multiplying entities without necessity J. Therm. Anal. Calorim. 83 2006 45 51
28. S. Vyazovkin, and A.I. Lesnikovich Estimation of the pre-exponentioal factor in the isoconversional calculation of effective kinetic parameters Thermochim. Acta 128 1988 297 300
29. S. Vyazovkin A unified approach to kinetic processing of non-isothermal data Int. J. Chem. Kinet. 28 1996 95 101
30. C. Alzina, N. Sbirrazzuoli, and A. Mija Hybrid nanocomposites: advanced nonlinear method for calculating key kinetic parameters of complex cure kinetics J. Phys. Chem. B 114 2010 12480 12487
31. S. Vyazovkin, and N. Sbirrazzuoli Mechanism and kinetics of epoxy-amine cure studied by differential scanning calorimetry Macromolecules 29 1996 1867 1873
32. N. Sbirrazzuoli, A. Mija, L. Vincent, and C. Alzina Isoconversional kinetic analysis of stoichiometric and off-stoichiometric epoxy-amine cures Thermochim. Acta 447 2006 167 177
33. C. Mathieu, M. Feve, G. Seytre, and G. Boiteux Kinetics analysis of the curing of a diepoxy-diamine system Angew. Makromol. Chem. 206 1993 39 52
34. S. Vyazovkin, and N. Sbirrazzuoli Kinetic methods to study isothermal and non-isothermal epoxy-anhydride cure Macromol. Chem. Phys. 200 1999 2294 2303
35. C. Daniel, F.S. Wood, Fitting Equations to Data, 2nd ed., John Wiley & Sons Inc., 1980 (Chapter 4).
36. N. Sbirrazzuoli, S. Vyazovkin, A. Mititelu, C. Sladic, and L. Vincent A study of epoxy-amine cure kinetics by combining isoconversional analysis with temperature modulated DSC and dynamic rheometry Macromol. Chem. Phys. 204 2003 1815 1821
37. S. Vyazovkin, and C.A. Wight Isothermal and non-isothermal reaction kinetics in solids: in search of ways toward consensus J. Phys. Chem. A 101 1997 8279 8284