A Study of Epoxy-Amine Cure Kinetics by Combining Isoconversional Analysis with Temperature Modulated DSC and Dynamic Rheometry

Macromolecular Chemistry and Physics

Volumn 204, Issue 15, 2003, Pages 1815-1821

  Sbirrazzuoli, Nicolas ^a   Vyazovkin, Sergey ^b   Mititelu, Alice ^a,c   Sladic, Cyril ^a   Vincent, Luc ^a  

^a UNIVERSITÉ CÔTE D'AZUR   (France)

^b UNIVERSITY OF ALABAMA AT BIRMINGHAM   (United States)

^c PETRU PONI INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Romania)

Author keywords

Gelation; Kinetics (polym.); Rheometry; Temperature modulated DSC; Vitrification

Indexed keywords

ACTIVATION ENERGY; DIFFERENTIAL SCANNING CALORIMETRY; GELATION; ISOTHERMS; MOLECULAR DYNAMICS; REACTION KINETICS; RHEOMETERS; STOICHIOMETRY; VITRIFICATION;

MOLECULAR MOBILITY; NONISOTHERMAL CURES;

EPOXY RESINS;

1,3 PHENYLENEDIAMINE; 4,4' ISOPROPYLIDENEDIPHENOL; EPOXIDE; ETHER;

ARTICLE; CALORIMETRY; DIFFERENTIAL SCANNING CALORIMETRY; DIFFUSION; ENERGY; FLOW MEASUREMENT; GELATION; KINETICS; STOICHIOMETRY; TEMPERATURE; VITRIFICATION;

EID: 0242291977     PISSN: 10221352     EISSN: None     Source Type: Journal    
DOI: 10.1002/macp.200350051     Document Type: Article

References (33)

1. nd edition, E. A. Turi, Ed., Academic Press, New York 1997, p. 1380.
2. J. M. Barton, Adv. Polym. Sci. 1985, 72, 111.
3. M. Reading, Trends Polym. Sci. 1993, 8, 248.
4. J. E. K. Schawe, Thermochim. Acta 1995, 261, 183.
5. J. E. K. Schawe, Thermochim. Acta 1995, 260, 1.
6. J. K. Gillham, in: "Encyclopedia of Polymer Science and Engineering", Vol. 4, H. F. Mark, N. M. Bikales, C. G. Overberger, J. I. Kroschwitz, Eds., John Wiley and Sons, New York 1986, p. 519.
7. S. Vyazovkin, N. Sbirrazzuoli, Macromolecules 1996, 29, 1867.
8. S. Vyazovkin, N. Sbirrazzuoli, Macromol. Rapid Commun. 1999, 20, 387.
9. S. Vyazovkin, N. Sbirrazzuoli, Macromol. Chem. Phys. 1999, 200, 2294.
10. S. Vyazovkin, N. Sbirrazzuoli, Macromol. Chem. Phys. 2000, 201, 199.
11. B. Bilyeu, W. Brostow, Polym. Compos. 2002, 23, 1111.
12. J. H. Flynn, "Thermal Analysis", in: Encyclopedia of Polymer Science and Engineering, Suppl. Vol., H. F. Mark, N. M. Bikales, C. V. Overberger, J. I. Kroschwitz, Eds., John Wiley & Sons, New York 1989, p. 690.
13. M. R. Kamal, Polym. Eng. Sci. 1974, 14, 231.
14. N. Sbirrazzuoli, Y. Girault, L. Elégant, Thermochim. Acta 1997, 293, 25.
15. N. Sbirrazzuoli, S. Vyazovkin, Thermochim. Acta 2002, 388, 289.
16. S. Vyazovkin, J. Comput. Chem. 1997, 18, 393.
17. S. Vyazovkin, J. Comput. Chem. 2001, 22, 178.
18. V. L. Zvetkov, Polymer 2001, 42, 6687.
19. S. Vyazovkin, N. Sbirrazzuoli, Macromol. Rapid Commun. 2000, 21, 85.
20. S. Glasstone, K. J. Laidler, H. Eyring, "The Theory of Rate Processes", McGraw-Hill, New York and London 1941.
21. P. D. Flory, "Principles of Polymer Chemistry", Cornell University Press, Ithaca 1953, p. 127.
22. H. Stutz, J. Mertes, K. Neubecker, J. Polym. Sci. A 1993, 31, 1879.
23. G. van Assche, A. van Hemelrijck, H. Rahier, B. van Mele, Thermochim. Acta 1995, 268, 121.
24. G. van Assche, A. van Hemelrijck, H. Rahier, B. van Mele, Thermochim. Acta 1996, 286, 209.
25. S. Montserrat, J. C. Martin, Thermochim. Acta 2002, 388, 343.
26. S. Montserrat, I. Cima, Thermochim. Acta 1999, 330, 189.
27. G. van Assche, A. van Hemelrijck, H. Rahier, B. van Mele, Thermochim. Acta 1997, 304/305, 317.
28. S. Sourour, M. R. Kamal, Thermochim. Acta 1976, 14, 41.
29. M. Finzel, J. Delong, M. C. Hawley, J. Polym. Sci. Part A 1995, 33, 673.
30. P. Punchaipetch, V. Ambrogi, M. Giamberini, W. Brostow, C. Carfagna, N. A. Souza, Polymer 2001, 42, 2067.
31. nd edition, Springer, Berlin 1997, p. 439.
32. J. M. Hutchinson, S. Montserrat, Thermochim. Acta 1997, 304/305, 257.
33. Z. Jiang, J. M. Hutchinson, C. T. Imrie, Polym. Int. 1998, 47, 72.