Molecular dynamics and ligand exchange in magnesium complexes: Evidence for both dissociative and associative ligand exchange

Angewandte Chemie - International Edition

Volumn 52, Issue 11, 2013, Pages 3264-3266

  Chisholm, Malcolm H ^a   Choojun, Kittisak ^a   Chow, Albert S ^a   Fraenkel, Gideon ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

lactide polymerization; ligand effects; magnesium; molecular dynamics; NMR spectroscopy

Indexed keywords

ASSOCIATIVE INTERCHANGE MECHANISM; LACTIDE POLYMERIZATION; LIGAND EFFECT; LIGAND EXCHANGES; MAGNESIUM COMPLEXES; RAC-LACTIDE; TETRA-HYDROFURAN;

DISSOCIATION; MAGNESIUM; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; REACTION KINETICS;

MOLECULAR DYNAMICS;

EID: 84874895276     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201209542     Document Type: Article

References (22)

1. R. E. Mulvey, Acc. Chem. Res. 2009, 42, 743-755.
2. A. Krasovskiy, P. Knochel, Angew. Chem. 2004, 116, 3396-3399
3. Angew. Chem. Int. Ed. 2004, 43, 3333-3336.
4. R. Campbell, D. Cannon, P. García-Álvarez, A. R. Kennedy, R. E. Mulvey, S. D. Robertson, J. Saßmannshausen, T. Tuttle, J. Am. Chem. Soc. 2011, 133, 13706-13717.
5. A. E. Jensen, W. Dohle, I. Sapountzis, D. M. Lindsay, V. A. Vu, P. Knochel, Synthesis 2002, 565-569.
6. H. Ren, A. Krasovskiy, P. Knochel, Chem. Commun. 2005, 543.
7. L. Boymond, M. Rottländer, G. Cahiez, P. Knochel, Angew. Chem. 1998, 110, 1801-1803
8. Angew. Chem. Int. Ed. 1998, 37, 1701-1703.
9. S. H. Wiedemann, A. Ramírez, D. B. Collum, J. Am. Chem. Soc. 2003, 125, 15893-15901.
10. X. Sun, D. B. Collum, J. Am. Chem. Soc. 2000, 122, 2459-2463.
11. X. Sun, D. B. Collum, J. Am. Chem. Soc. 2000, 122, 2452-2458.
12. P. Knochel, R. D. Singer, Chem. Rev. 1993, 93, 2117-2188.
13. E. Erdik, Ö. Ö. Pekel, J. Organomet. Chem. 2008, 693, 338-342.
14. W. Schlenk, W. J. Schlenk, Ber. Dtsch. Chem. Ges. B 1929, 62, 920-924.
15. M. H. Chisholm, K. Choojun, J. C. Gallucci, P. M. Wambua, Chem. Sci. 2012, 3, 3445-3457.
16. M. S. Hill, D. J. MacDougall, M. F. Mahon, Dalton Trans. 2010, 39, 11129-11131.
17. K. Pang, Y. Rong, G. Parkin, Polyhedron 2010, 29, 1881-1890.
18. R. D. Shannon, Acta Crystallogr. Sect. A 1976, 32, 751-767.
19. R. A. Collins, J. Unruangsri, P. Mountford, Dalton Trans. 2012, 42, 759-769.
20. A. L. Van Geet, Anal. Chem. 1970, 42, 679-680.
21. D. S. Raiford, C. L. Fisk, E. D. Becker, Anal. Chem. 1979, 51, 2050-2051.
22. J. I. Kaplan, G. Fraenkel, NMR of Chemically Exchanging Systems, Academic Press, New York, 1980.