A case of intermittent C-H×××F-C hydrogen-bond interaction in solution

Chemistry - A European Journal

Volumn 19, Issue 11, 2013, Pages 3702-3709

  Bartolomé, Camino ^a   Villafañe, Fernando ^a   Martín Alvarez, Jose M ^a   Martínez Ilarduya, Jesús M ^a   Espinet, Pablo ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

fluxionality; hydrogen bonds; palladium; steric hindrance; trifluoromethyl groups

Indexed keywords

LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PALLADIUM; TEMPERATURE;

CONFORMATIONAL CHANGE; FLUXIONALITY; HYDROGEN BOND INTERACTION; RESTRICTED ROTATIONS; STERIC HINDRANCES; TETRAMETHYLETHYLENEDIAMINE; TRIFLUOROMETHYL GROUP; VERY LOW TEMPERATURES;

HYDROGEN BONDS;

COORDINATION COMPOUND; ORGANOMETALLIC COMPOUND; PALLADIUM(2,4,6 TRIS(TRIFLUOROMETHYL)2) (N,N,N',N' TETRAMETHYLETHYLENEDIAMINE); PALLADIUM(2,4,6-TRIS(TRIFLUOROMETHYL)2)-(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE);

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLUTION AND SOLUBILITY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

COORDINATION COMPLEXES; CRYSTALLOGRAPHY, X-RAY; HYDROGEN BONDING; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; SOLUTIONS;

EID: 84874606757     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201203512     Document Type: Article

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