Porous materials with pre-designed single-molecule traps for CO 2 selective adsorption

Nature Communications

Volumn 4, Issue , 2013, Pages

  Li, Jian Rong ^a,b   Yu, Jiamei ^b,c   Lu, Weigang ^b   Sun, Lin Bing ^b   Sculley, Julian ^b   Balbuena, Perla B ^b,c   Zhou, Hong Cai ^b  

^a BEIJING UNIVERSITY OF TECHNOLOGY   (China)

^b TEXAS A AND M UNIVERSITY   (United States)

^c Texas AandM University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; METAL ORGANIC FRAMEWORK; METHANE; NITROGEN;

ADSORPTION; CARBON DIOXIDE; CARBON SEQUESTRATION; CHEMICAL BONDING; INDUSTRIAL TECHNOLOGY; MASS TRANSFER; METHANE; MOLECULAR ANALYSIS; NITROGEN; ORGANOMETALLIC COMPOUND; PORE SPACE; POROUS MEDIUM; PRECISION;

ADSORPTION; ARTICLE; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; MASS; SYNTHESIS;

EID: 84874598396     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms2552     Document Type: Article

References (44)

1. Keith, D. W. Why Capture CO2 from the atmosphere? Science 325, 1654-1655 (2009)
2. Kramer, G. J. & Haigh, M. No quick switch to low-carbon energy. Nature 462, 568-569 (2009)
3. Rochelle, G. T. Amine scrubbing for CO2 capture. Science 325, 1652-1654 (2009)
4. Choi, S., Drese, J. H. & Jones, C. W. Adsorbent materials for carbon dioxide capture from large anthropogenic point sources. ChemSusChem 2, 796-854 (2009)
5. Sumida, K. et al. Carbon dioxide capture in metal-organic frameworks. Chem. Rev. 112, 724-781 (2012)
6. Li, J.-R., Sculley, J. & Zhou, H.-C. Metal-organic frameworks for separations. Chem. Rev. 112, 869-932 (2012)
7. Li, J.-R. & Zhou, H.-C. Bridging-ligand-substitution strategy for the preparation of metal-organic polyhedra. Nat. Chem. 2, 893-898 (2010)
8. Seo, J. S. et al. A homochiral metal-organic porous material for enantioselective separation and catalysis. Nature 404, 982-986 (2000) (Pubitemid 30243589)
9. Kosal, M. E., Chou, J.-H., Wilson, S. R. & Suslick, K. S. A functional zeolite analogue assembled from metalloporphyrins. Nat. Mater. 1, 118-121 (2002)
10. Matsuda, R. et al. Highly controlled acetylene accommodation in a metal-organic microporous material. Nature 436, 238-241 (2005) (Pubitemid 41021271)
11. Hurd, J. A. et al. Anhydrous proton conduction at 150 -C in a crystalline metal-organic framework. Nat. Chem. 1, 705-710 (2009)
12. Xiao, B. et al. Chemically blockable transformation and ultraselective low-pressure gas adsorption in a non-porous metal organic framework Nat. Chem. 1, 289-294 (2009)
13. Clever, G. H., Tashiro, S. & Shionoya, M. Inclusion of snionic guests inside a molecular cage with palladium(II) centers as electrostatic anchors. Angew. Chem. Int. Ed. Engl. 48, 7010-7012 (2009)
14. Kawamichi, T., Haneda, T., Kawano, M. & Fujita, M. X-ray observation of a transient hemiaminal trapped in a porous network. Nature 461, 633-635 (2009)
15. Farha, O. K., Yazaydin, A. O ., Eryazici, I., Malliakas, C. D., Hauser, B. G. & Kanatzidis, M. G. et al. De novo synthesis of a metal-organic framework material featuring ultrahigh surface area and gas storage capacities. Nat. Chem. 2, 944-948 (2010)
16. Rabone, J. et al. An adaptable peptide-based porous material. Science 329, 1053-1057 (2010)
17. Vaidhyanathan, R. et al. Direct observation and quantification of CO2 binding within an amine-functionalized nanoporous solid. Science 330, 650-653 (2010)
18. Blake, A. J. et al. Photoreactivity examined through incorporation in metal-organic frameworks. Nat. Chem. 2, 688-694 (2010)
19. Horcajada, P. et al. Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging. Nat. Mater. 9, 172-178 (2010)
20. Gascon, J. & Kapteijn, F. Metal-organic framework membranes-high potential, bright future? Angew. Chem. Int. Ed. Engl. 49, 1530-1532 (2010)
21. An, J. et al. Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework. Nat. Commun. 3, 604 (2012)
22. Zhang, Y.-B. et al. Geometry analysis and systematic synthesis of highly porous isoreticular frameworks with a unique topology. Nat. Commun. 3, 642 (2012)
23. Bloch, E. D. et al. Hydrocarbon separations in a metal-organic framework with open iron(II) coordination sites. Science 335, 1606-1610 (2012)
24. Suh, M. P., Park, H. J., Prasad, T. K. & Lim, D.-W. Hydrogen storage in metalorganic frameworks. Chem. Rev. 112, 782-835 (2012)
25. Eddaoudi, M. et al. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science 295, 469-472 (2002) (Pubitemid 34101630)
26. Perry, J. J., Perman, J. A. & Zaworotko, M. J. Design and synthesis of metalorganic frameworks using metal-organic polyhedra as supermolecular building blocks. Chem. Soc. Rev. 38, 1400-1417 (2009)
27. O'Keeffe, M. Design of MOFs and intellectual content in reticular chemistry: a personal view. Chem. Soc. Rev. 38, 1215-1217 (2009)
28. Ma, L., Falkowski, J. M., Abney, C. & Lin, W. A series of isoreticular chiral metal-organic frameworks as a tunable platform for asymmetric catalysis. Nat. Chem. 2, 838-846 (2010)
29. Morris, R. E. & Bu, X. Induction of chiral porous solids containing only achiral building blocks. Nat. Chem. 2, 353-361 (2010)
30. Zhao, D., Timmons, D. J., Yuan, D. & Zhou, H.-C. Tuning the topology and functionality of metal-organic frameworks by ligand design. Acc. Chem. Res. 44, 123-133 (2010)
31. Henke, S. & Fischer, R. A. Gated channels in a honeycomb-like zinc-dicarboxylate-bipyridine framework with flexible alkyl ether side chains. J. Am. Chem. Soc. 133, 2064-2067 (2011)
32. Xiang, S.-C. et al. Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene. Nat. Commun. 2, 204 (2011)
33. Wilmer, C. E. et al. Large-scale screening of hypothetical metal-organic frameworks. Nat. Chem. 4, 83-89 (2012)
34. Otsubo, K. et al. Bottom-up realization of a porous metal-organic nanotubular assembly. Nat. Mater. 10, 291-295 (2011)
35. Vukotic, V. N., Harris, K. J., Zhu, K., Schurko, R. W. & Loeb, S. J. Metal-organic frameworks with dynamic interlocked components. Nat. Chem. 4, 456-460 (2012)
36. Cohen, S. M. Postsynthetic methods for the functionalization of metal-organic frameworks. Chem. Rev. 112, 970-1000 (2012)
37. Li, J.-R. et al. Ligand bridging-angle-driven assembly of molecular architectures based on quadruply bonded Mo-Mo dimers. J. Am. Chem. Soc. 132, 17599-17610 (2010)
38. Li, J.-R. et al. Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coord. Chem. Rev. 255, 1791-1823 (2011)
39. Sun, D., Ke, Y., Mattox, T. M., Ooro, B. A. & Zhou, H.-C. Temperaturedependent supramolecular stereoisomerism in porous copper coordination networks based on a designed carboxylate ligand. Chem. Commun. 5447-5449 (2005) (Pubitemid 41689383)
40. Spek, A. L. Single-crystal structure validation with the program PLATON. J. Appl. Crystallogr. 36, 7-13 (2003)
41. Myers, A. L. & Prausnitz, J. M. Thermodynamics of mixed-gas adsorption. AIChE J. 11, 121-127 (1965)
42. Zheng, S.-T. et al. Pore space partition and charge separation in cage-withincage indium-organic frameworks with high CO2 uptake. J. Am. Chem. Soc. 132, 17062-17064 (2010)
43. Frisch, M. J. et al. GAUSSIAN 09 Program (Gaussian, Inc., Wallingford, CT, 2009)
44. Gupta, A., Chempath, S., Sanborn, M. J., Clark, L. A. & Snurr, R. Q. Objectorientated programming paradigms for molecular modeling. Mol. Simul. 29, 29-46 (2003). (Pubitemid 44121109)