Janus graphene from asymmetric two-dimensional chemistry

Nature Communications

Volumn 4, Issue , 2013, Pages

  Zhang, Liming ^a   Yu, Jingwen ^a   Yang, Mingmei ^a   Xie, Qin ^a   Peng, Hailin ^a   Liu, Zhongfan ^a  

^a PEKING UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

GRAPHENE; HALOGEN; JANUS GRAPHENE; NITROGEN; OXYGEN; POLY(METHYL METHACRYLATE); UNCLASSIFIED DRUG;

ALKENE; EXPERIMENTAL STUDY; HALOGEN; OXYGEN; TWO-DIMENSIONAL MODELING; WETTABILITY;

ARTICLE; FLUORINATION; OXYGENATION; PHOTOOXIDATION; RAMAN SPECTROMETRY; WETTABILITY;

EID: 84874594462     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms2464     Document Type: Article

References (52)

1. Hirsemann, D. et al. Large-scale, low-cost fabrication of Janus-type emulsifiers by selective decoration of natural kaolinite platelets. Angew. Chem. Int. Ed. 51, 1348-1352 (2012)
2. Walther, A., Andre, X., Drechsler, M., Abetz, V. & Muller, A. H. E. Janus discs. J. Am. Chem. Soc. 129, 6187-6198 (2007) (Pubitemid 46786809)
3. Roh, K. H., Martin, D. C. & Lahann, J. Biphasic Janus particles with nanoscale anisotropy. Nat. Mater 4, 759-763 (2005) (Pubitemid 41397023)
4. Nonomura, Y., Komura, S. & Tsujii, K. Adsorption of disk-shaped Janus beads at liquid-liquid interfaces. Langmuir 20, 11821-11823 (2004) (Pubitemid 40049660)
5. Geim, A. K. & Novoselov, K. S. The rise of graphene. Nat. Mater. 6, 183-191 (2007) (Pubitemid 46353764)
6. Avouris, P., Chen, Z. H. & Perebeinos, V. Carbon-based electronics. Nat. Nanotech. 2, 605-615 (2007) (Pubitemid 47525190)
7. Bonaccorso, F., Sun, Z., Hasan, T. & Ferrari, A. C. Graphene photonics and optoelectronics. Nat. Photon. 4, 611-622 (2010)
8. Wei, D. & Liu, Y. Controllable synthesis of graphene and its applications. Adv. Mater. 22, 3225-3241 (2010)
9. Niyogi, S. et al. Covalent chemistry for graphene electronics. J. Phys. Chem. Lett. 2, 2487-2498 (2011)
10. Sun, Z., James, D. K. & Tour, J. M. Graphene Chemistry: Synthesis and Manipulation. J. Phys. Chem. Lett. 2, 2425-2432 (2011)
11. Yan, L. et al. Chemistry and physics of a single atomic layer: strategies and challenges for functionalization of graphene and graphene-based materials. Chem. Soc. Rev. 41, 97-114 (2012)
12. Park, J. et al. Single-gate bandgap opening of bilayer graphene by dual molecular doping. Adv. Mater. 24, 407-411 (2012)
13. Schedin, F. et al. Detection of individual gas molecules adsorbed on graphene. Nat. Mater. 6, 652-655 (2007) (Pubitemid 47359547)
14. Elias, D. C. et al. Control of graphene's properties by reversible hydrogenation: evidence for graphane. Science 323, 610-613 (2009)
15. Ryu, S. et al. Reversible basal plane hydrogenation of graphene. Nano Lett. 8, 4597-4602 (2008)
16. Balog, R. et al. Bandgap opening in graphene induced by patterned hydrogen adsorption. Nat. Mater. 9, 315-319 (2010)
17. Luo, Z. Q. et al. Thickness-dependent reversible hydrogenation of graphene layers. ACS Nano. 3, 1781-1788 (2009)
18. Robinson, J. T. et al. Properties of fluorinated graphene films. Nano Lett. 10, 3001-3005 (2010)
19. Nair, R. R. et al. Fluorographene: A Two-Dimensional Counterpart of Teflon. Small 6, 2877-2884 (2010)
20. Jeon, K. J. et al. Fluorographene: a wide bandgap semiconductor with ultraviolet luminescence. ACS Nano. 5, 1042-1046 (2011)
21. Li, B. et al. Photochemical chlorination of graphene. ACS Nano. 5, 5957-5961 (2011)
22. Wu, J. et al. Controlled chlorine plasma reaction for noninvasive graphene doping. J. Am. Chem. Soc. 133, 19668-19671 (2011)
23. Lomeda, J. R., Doyle, C. D., Kosynkin, D. V., Hwang, W. F. & Tour, J. M. Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets. J. Am. Chem. Soc. 130, 16201-16206 (2008)
24. Bekyarova, E. et al. Chemical modification of epitaxial graphene: spontaneous grafting of aryl groups. J. Am. Chem. Soc. 131, 1336-1337 (2009)
25. Englert, J. M. et al. Covalent bulk functionalization of graphene. Nat. Chem. 3, 279-286 (2011)
26. Koehler, F. M. et al. Permanent pattern-resolved adjustment of the surface potential of graphene-like carbon through chemical functionalization. Angew. Chem. Int. Ed. 48, 224-227 (2009)
27. Sharma, R., Baik, J. H., Perera, C. J. & Strano, M. S. Anomalously large reactivity of single graphene layers and edges toward electron transfer chemistries. Nano Lett. 10, 398-405 (2010)
28. Quintana, M. et al. Functionalization of graphene via 1, 3-dipolar cycloaddition. ACS Nano 4, 3527-3533 (2010)
29. Liu, L. H. & Yan, M. D. Derivitization of pristine graphene with well-defined chemical functionalities. Nano Lett. 10, 3754-3756 (2010)
30. Liu, L. H. & Yan, M. D. Simple method for the covalent immobilization of graphene. Nano Lett. 9, 3375-3378 (2009)
31. Liu, L. H. et al. A simple and scalable route to wafer-size patterned graphene. J. Mater. Chem. 20, 5041 (2010)
32. Wang, X. et al. N-doping of graphene through electrothermal reactions with ammonia. Science 324, 768-771 (2009)
33. Sun, Z. Z. et al. Towards hybrid superlattices in graphene. Nat. Comm. 2, 559 (2011)
34. Liu, L. et al. Graphene oxidation: thickness-dependent etching and strong chemical doping. Nano Lett. 8, 1965-1970 (2008)
35. Leenaerts, O., Partoens, B. & Peeters, F. M. Graphene: a perfect nanoballoon. Appl. Phys. Lett. 93, 193107 (2008)
36. Bunch, J. S. et al. Impermeable atomic membranes from graphene sheets. Nano Lett. 8, 2458-2462 (2008)
37. Koenig, S. P., Boddeti, N. G., Dunn, M. L. & Bunch, J. S. Ultrastrong adhesion of graphene membranes. Nat. Nanotech. 6, 543-546 (2011)
38. Garaj, S. et al. Graphene as a subnanometre trans-electrode membrane. Nature 467, 190-193 (2010)
39. Merchant, C. A. et al. DNA translocation through graphene nanopores. Nano Lett. 10, 2915-2921 (2010)
40. Schneider, G. F. et al. DNA translocation through graphene nanopores. Nano Lett. 10, 3163-3167 (2010)
41. Zheng, Z. et al. Janus nanomembranes: a generic platform for chemistry in two dimensions. Angew. Chem. Int. Ed. 49, 8493-8497 (2010)
42. Malard, L. M., Pimenta, M. A., Dresselhaus, G. & Dresselhaus, M. S. Raman spectroscopy in graphene. Phys. Rep. 473, 51-87 (2009)
43. Pisana, S. et al. Breakdown of the adiabatic Born-Oppenheimer approximation in graphene. Nat. Mater. 6, 198-201 (2007) (Pubitemid 46353766)
44. Yang, M., Zhou, L., Wang, J., Liu, Z. & Liu, Z. Evolutionary chlorination of graphene: from charge-transfer complex to covalent bonding and nonbonding. J. Phys. Chem. C 116, 844-850 (2012)
45. Liu, H. et al. Photochemical reactivity of graphene. J. Am. Chem. Soc. 131, 17099-17101 (2009)
46. Zhang, Y. H. et al. Tuning the electronic structure and transport properties of graphene by noncovalent functionalization: effects of organic donor, acceptor and metal atoms. Nanotech. 21, 065201 (2010)
47. Zhang, L. et al. Photocatalytic patterning and modification of graphene. J. Am. Chem. Soc. 133, 2706-2713 (2011)
48. Gokus, T. et al. Making graphene luminescent by oxygen plasma treatment. ACS Nano 3, 3963 (2009)
49. Eck, W. et al. Generation of surface amino groups on aromatic self-assembled monolayers by low energy electron beams-A first step towards chemical lithography. Adv. Mater. 12, 805-808 (2000)
50. Lucchese, M. M. et al. Quantifying ion-induced defects and Raman relaxation length in graphene. Carbon 48, 1592-1597 (2010)
51. Boukhvalov, D. W. & Katsnelson, M. I. Chemical functionalization of graphene. J. Phys. Condens. Matter 21, 344205 (2009)
52. Rafiee, J. et al. Wetting transparency of graphene. Nat. Mater. 11, 217-222 (2012).