Lattice-matched bimetallic CuPd-graphene nanocatalysts for facile conversion of biomass-derived polyols to chemicals

ACS Nano

Volumn 7, Issue 2, 2013, Pages 1309-1316

  Jin, Xin ^a   Dang, Lianna ^b   Lohrman, Jessica ^b   Subramaniam, Bala ^a   Ren, Shenqiang ^b   Chaudhari, Raghunath V ^a  

^a University of Kansas   (United States)

^b UNIVERSITY OF KANSAS   (United States)

Author keywords

bimetallic; biomass conversion; graphene; lactic acid; lattice; nanocatalysts

Indexed keywords

ACTIVE SURFACES; BIMETALLIC; BIO-POLYOLS; BIOMASS CONVERSION; CATALYTIC REACTIONS; CO-PRODUCTS; COPPER-BASED; FACILE CONVERSION; HETEROGENEOUS CATALYTIC REACTIONS; HIGH ACTIVITY; LARGE POPULATION; LATTICE; LATTICE-MATCHED; LINEAR ALCOHOLS; METAL-BASED CATALYSTS; NANO-CATALYST; NANOCATALYSTS; NANOSTRUCTURED METALS; NOVEL CATALYSTS; OVERALL STABILITIES; REDUCED GRAPHENE OXIDES; SURFACE CONFIGURATION; SYNERGISTIC SYSTEMS; SYNTHETIC METHODOLOGY; TRACE AMOUNTS; TURNOVER FREQUENCY; VALUE-ADDED CHEMICALS;

BIOCONVERSION; BIOMASS; CATALYSIS; CATALYSTS; GLYCEROL; INDUSTRIAL CHEMICALS; LACTIC ACID; PALLADIUM; SUGAR SUBSTITUTES;

GRAPHENE;

COPPER; GRAPHITE; NANOMATERIAL; PALLADIUM; POLYMER; POLYOL;

ARTICLE; BIOMASS; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; SURFACE PROPERTY;

BIOMASS; CATALYSIS; COPPER; GRAPHITE; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NANOSTRUCTURES; PALLADIUM; POLYMERS; SURFACE PROPERTIES;

EID: 84874418014     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn304820v     Document Type: Article

References (43)

1. Cortright, R. D.; Davda, R. R.; Dumesic, J. A. Hydrogen from Catalytic Reforming of Biomass-Derived Hydrocarbons in Liquid Water Nature 2002, 418, 964-967
2. Huber, G. W.; Iborra, S.; Corma, A. Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering Chem. Rev. 2006, 106, 4044-4098
3. Huber, G. W.; Cortright, R. D.; Dumesic, J. A. Renewable Alkanes by Aqueous-Phase Reforming of Biomass-Derived Oxygenates Angew. Chem., Int. Ed. 2004, 43, 1549-1551
4. Huber, G. W.; Chheda, J. N.; Barrett, C. J.; Dumesic, J. A. Production of Liquid Alkanes by Aqueous-Phase Processing of Biomass-Derived Carbohydrates Science 2005, 308, 1446-1450
5. Kunkes, E. L.; Simonetti, D. A.; West, R. M.; Serrano-Ruiz, J. C.; Gartner, C. A.; Dumesic, J. A. Catalytic Conversion of Biomass to Monofunctional Hydrocarbons and Targeted Liquid-Fuel Classes Science 2008, 322, 417-421
6. Ma, L.; He, D. H. Hydrogenolysis of Glycerol to Propanediols over Highly Active Ru-Re Bimetallic Catalysts Top. Catal. 2009, 52, 834-844
7. Yuan, Z. L.; Wang, L. N.; Wang, J. H.; Xia, S. X.; Chen, P.; Hou, Z. Y.; Zheng, X. M. Hydrogenolysis of Glycerol over Homogenously Dispersed Copper on Solid Base Catalysts Appl. Catal., B 2011, 101, 431-440
8. Li, N.; Tompsett, G. A.; Huber, G. W. Renewable High-Octane Gasoline by Aqueous-Phase Hydrodeoxygenation of C-5 and C-6 Carbohydrates over Pt/Zirconium Phosphate Catalysts ChemSusChem 2010, 3, 1154-1157
9. Maris, E. P.; Davis, R. J. Hydrogenolysis of Glycerol over Carbon-Supported Ru and Pt Catalysts J. Catal. 2007, 249, 328-337
10. King, D. L.; Zhang, L. A.; Xia, G.; Karim, A. M.; Heldebrant, D. J.; Wang, X. Q.; Peterson, T.; Wang, Y. Aqueous Phase Reforming of Glycerol for Hydrogen Production over Pt-Re Supported on Carbon Appl. Catal., B 2010, 99, 206-213
11. Torres, A.; Roy, D.; Subramaniam, B.; Chaudhari, R. V. Kinetic Modeling of Aqueous-Phase Glycerol Hydrogenolysis in a Batch Slurry Reactor Ind. Eng. Chem. Res. 2010, 49, 10826-10835
12. Maris, E. P.; Ketchie, W. C.; Murayama, M.; Davis, R. J. Glycerol Hydrogenolysis on Carbon-Supported PtRu and AuRu Bimetallic Catalysts J. Catal. 2007, 251, 281-294
13. Chia, M.; Pagan-Torres, Y. J.; Hibbitts, D.; Tan, Q. H.; Pham, H. N.; Datye, A. K.; Neurock, M.; Davis, R. J.; Dumesic, J. A. Selective Hydrogenolysis of Polyols and Cyclic Ethers over Bifunctional Surface Sites on Rhodium-Rhenium Catalysts J. Am. Chem. Soc. 2011, 133, 12675-12689
14. Yuan, Z. L.; Wang, J. H.; Wang, L. N.; Xie, W. H.; Chen, P.; Hou, Z. Y.; Zheng, X. M. Biodiesel Derived Glycerol Hydrogenolysis to 1,2-Propanediol on Cu/MgO Catalysts Bioresour. Technol. 2010, 101, 7088-7092
15. Roy, D.; Subramaniam, B.; Chaudhari, R. V. Cu-Based Catalysts Show Low Temperature Activity for Glycerol Conversion to Lactic Acid ACS Catal. 2011, 1, 548-551
16. Shen, Z.; Jin, F. M.; Zhang, Y. L.; Wu, B.; Kishita, A.; Tohji, K.; Kishida, H. Effect of Alkaline Catalysts on Hydrothermal Conversion of Glycerin into Lactic Acid Ind. Eng. Chem. Res. 2009, 48, 8920-8925
17. Huang, Z. W.; Cui, F.; Kang, H. X.; Chen, J.; Zhang, X. Z.; Xia, C. G. Highly Dispersed Silica-Supported Copper Nanoparticles Prepared by Precipitation-Gel Method: A Simple but Efficient and Stable Catalyst for Glycerol Hydrogenolysis Chem. Mater. 2008, 20, 5090-5099
18. Somorjai, G. A.; Frei, H.; Park, J. Y. Advancing the Frontiers in Nanocatalysis, Biointerfaces, and Renewable Energy Conversion by Innovations of Surface Techniques J. Am. Chem. Soc. 2009, 131, 16589-16605
19. Bienholz, A.; Schwab, F.; Claus, P. Hydrogenolysis of Glycerol over a Highly Active CuO/ZnO Catalyst Prepared by An Oxalate Gel Method: Influence of Solvent and Reaction Temperature on Catalyst Deactivation Green Chem. 2010, 12, 290-295
20. Lee, I.; Morales, R.; Albiter, M. A.; Zaera, F. Synthesis of Heterogeneous Catalysts with Well Shaped Platinum Particles To Control Reaction Selectivity Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 15241-15246
21. Gokhale, A. A.; Dumesic, J. A.; Mavrikakis, M. On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper J. Am. Chem. Soc. 2008, 130, 1402-1414
22. Madon, R. J.; Braden, D.; Kandoi, S.; Nagel, P.; Mavrikakis, M.; Dumesic, J. A. Microkinetic Analysis and Mechanism of the Water Gas Shift Reaction over Copper Catalysts J. Catal. 2011, 281, 1-11
23. Greeley, J.; Mavrikakis, M. Methanol Decomposition on Cu(111): A DFT Study J. Catal. 2002, 208, 291-300
24. Balaraju, M.; Rekha, V.; Prasad, P. S. S.; Prasad, R. B. N.; Lingaiah, N. Selective Hydrogenolysis of Glycerol to 1,2 Propanediol over Cu-ZnO Catalysts Catal. Lett. 2008, 126, 119-124
25. Xia, S. X.; Yuan, Z. L.; Wang, L. N.; Chen, P.; Hou, Z. Y. Hydrogenolysis of Glycerol on Bimetallic Pd-Cu/Solid-Base Catalysts Prepared via Layered Double Hydroxides Precursors Appl. Catal., A 2011, 403, 173-182
26. Blanc, B.; Bourrel, A.; Gallezot, P.; Haas, T.; Taylor, P. Starch-Derived Polyols for Polymer Technologies: Preparation by Hydrogenolysis on Metal Catalysts Green Chem. 2000, 2, 89-91
27. 4: A Precursor for Copper Catalyst with High Thermal Stability and Activity Catal. Lett. 2005, 100, 89-93
28. Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.; Booth, T. J.; Roth, S. The Structure of Suspended Graphene Sheets Nature 2007, 446, 60-63
29. Geim, A. K. Graphene: Status and Prospects Science 2009, 324, 1530-1534
30. Li, X. S.; Cai, W. W.; An, J. H.; Kim, S.; Nah, J.; Yang, D. X.; Piner, R.; Velamakanni, A.; Jung, I.; Tutuc, E. et al. Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils Science 2009, 324, 1312-1314
31. Wang, Y.; Zheng, Y.; Xu, X. F.; Dubuisson, E.; Bao, Q. L.; Lu, J.; Loh, K. P. Electrochemical Delamination of CVD-Grown Graphene Film: Toward the Recyclable Use of Copper Catalyst ACS Nano 2011, 5, 9927-9933
32. 2-2,5]}, Where R = Cl, Me, Bu Inorg. Chim. Acta 2011, 321, 142-148
33. Chen, S. S.; Brown, L.; Levendorf, M.; Cai, W. W.; Ju, S. Y.; Edgeworth, J.; Li, X. S.; Magnuson, C. W.; Velamakanni, A.; Piner, R. D. et al. Oxidation Resistance of Graphene-Coated Cu and Cu/Ni Alloy ACS Nano 2011, 5, 1321-1327
34. Rioux, R. M.; Vannice, M. A. Hydrogenation/Dehydrogenation Reactions: Isopropanol Dehydrogenation over Copper Catalysts J. Catal. 2003, 216, 362-376
35. Balogh, L.; Tomalia, D. A. Poly(amidoamine) Dendrimer-Templated Nanocomposites. 1. Synthesis of Zerovalent Copper Nanoclusters J. Am. Chem. Soc. 1998, 120, 7355-7356
36. Chan, G. H.; Zhao, J.; Hicks, E. M.; Schatz, G. C.; Van Duyne, R. P. Plasmonic Properties of Copper Nanoparticles Fabricated by Nanosphere Lithography Nano Lett. 2007, 7, 1947-1952
37. Rao, R. S.; Bansil, A.; Asonen, H.; Pessa, M. Electronic-Structure of Copper-Rich Copper-Palladium Alloys Phys. Rev. B 1984, 29, 1713-1721
38. Toshima, N.; Wang, Y. Preparation and Catalysis of Novel Colloidal Dispersions of Copper Noble-Metal Bimetallic Clusters Langmuir 1994, 10, 4574-4580
39. Roy, D.; Subramaniam, B.; Chaudhari, R. V. Aqueous Phase Hydrogenolysis of Glycerol to 1,2-Propanediol without External Hydrogen Addition Catal. Today 2010, 156, 31-37
40. Contescu, C. I.; Brown, C. M.; Liu, Y.; Bhat, V. V.; Gallego, N. C. Detection of Hydrogen Spillover in Palladium-Modified Activated Carbon Fibers during Hydrogen Adsorption J. Phys. Chem. C 2009, 113, 5886-5890
41. Davda, R. R.; Shabaker, J. W.; Huber, G. W.; Cortright, R. D.; Dumesic, J. A. A Review of Catalytic Issues and Process Conditions for Renewable Hydrogen and Alkanes by Aqueous-Phase Reforming of Oxygenated Hydrocarbons over Supported Metal Catalysts Appl. Catal., B 2005, 56, 171-186
42. Zope, B. N.; Hibbitts, D. D.; Neurock, M.; Davis, R. J. Reactivity of the Gold/Water Interface during Selective Oxidation Catalysis Science 2010, 330, 74-78
43. Auneau, F.; Michel, C.; Delbecq, F.; Pinel, C.; Sautet, P. Unravelling the Mechanism of Glycerol Hydrogenolysis over Rhodium Catalyst through Combined Experimental-Theoretical Investigations Chem.-Eur. J. 2011, 17, 14288-14299