Selective hydrogenolysis of polyols and cyclic ethers over bifunctional surface sites on rhodium-rhenium catalysts

Journal of the American Chemical Society

Volumn 133, Issue 32, 2011, Pages 12675-12689

  Chia, Mei ^a   Pagán Torres, Yomaira J ^a   Hibbitts, David ^b   Tan, Qiaohua ^b   Pham, Hien N ^c   Datye, Abhaya K ^c   Neurock, Matthew ^b   Davis, Robert J ^b   Dumesic, James A ^a  

^a University of Wisconsin Madison   (United States)

^b University of Virginia   (United States)

^c University of New Mexico   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACID SITE DENSITY; BI-FUNCTIONAL CATALYSTS; BIFUNCTIONAL; CARBENIUM ION; CYCLIC ETHER; DEHYDRATION REACTIONS; DFT CALCULATION; GENERAL DESCRIPTION; HETEROGENEOUS CATALYST; HYDROXYL GROUPS; OXOCARBENIUM; OXYGEN ATOM; PROTON DONATION; RING OPENING; STANDARD ENTHALPY; STRONG BINDING; SURFACE ACID SITES; SURFACE SITES; THEORETICAL CALCULATIONS; TRANSITION STATE;

ADSORPTION; ALCOHOLS; CATALYSIS; CATALYSTS; DEHYDRATION; DENSITY FUNCTIONAL THEORY; DEWATERING; ETHERS; FEEDSTOCKS; HYDROGENOLYSIS; HYDROLYSIS; IONS; RHENIUM; RHENIUM COMPOUNDS; RHODIUM; TEMPERATURE PROGRAMMED DESORPTION;

RHODIUM COMPOUNDS;

AMMONIA; ETHER DERIVATIVE; HYDROXYL GROUP; OXYGEN; POLYOL; RHENIUM; RHODIUM;

ARTICLE; ATOM; CALCULATION; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DESORPTION; HYDROGEN BOND; HYDROGENATION; HYDROGENOLYSIS; HYPOTHESIS; PHASE TRANSITION; PROTON TRANSPORT; RING OPENING; SURFACE PROPERTY;

EID: 80051581517     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2038358     Document Type: Article

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