Effect of cellulose crystallinity on the formation of a liquid intermediate and on product distribution during pyrolysis

Journal of Analytical and Applied Pyrolysis

Volumn 100, Issue , 2013, Pages 56-66

  Wang, Zhouhong ^a   McDonald, Armando G ^b   Westerhof, Roel J M ^c   Kersten, Sascha R A ^c   Cuba Torres, Christian M ^d   Ha, Su ^d   Pecha, Brennan ^d   Garcia Perez, Manuel ^a  

^a WASHINGTON STATE UNIVERSITY   (United States)

^b UNIVERSITY OF IDAHO   (United States)

^c UNIVERSITY OF TWENTE   (Netherlands)

^d Washington State University   (United States)

Author keywords

Cellulose crystallinity; Depolymerization; Py GC MS; Pyrolysis; TGA

Indexed keywords

ACTIVATION ENERGY; ALDEHYDES; DEHYDRATION; DEPOLYMERIZATION; FURFURAL; KETONES; LIQUIDS; PYROLYSIS; REACTION INTERMEDIATES; SCANNING ELECTRON MICROSCOPY; THERMOGRAVIMETRIC ANALYSIS;

AMORPHOUS CELLULOSE; CELLULOSE CRYSTALLINITY; DEGRADATION ACTIVATION ENERGY; DEHYDRATION REACTIONS; FRAGMENTATION REACTIONS; METHYL VINYL KETONES; PRODUCT DISTRIBUTIONS; PY-GC/MS;

CELLULOSE;

EID: 84874109799     PISSN: 01652370     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jaap.2012.11.017     Document Type: Article

References (54)

1. E. Meszaros, G. Varhegyi, E. Jakab, and B. Marosvolgyi Thermogravimetric and reaction kinetic analysis of biomass samples from an energy plantation Energy and Fuels 18 2004 497 507
2. D.J. Hayes An examination of biorefining processes, catalysts and challenges Catalysis Today 145 2009 138 151
3. M.R. Pelaez-Samaniego, M. Garcia-Perez, L.B. Cortez, F. Rosillo-Calle, and J. Mesa Improvements of Brazilian carbonization industry as part of the creation of a global biomass economy Renewable and Sustainable Energy Reviews 12 4 2008 1063 1086
4. L.R. Jarboe, Z. Wen, D.W. Choi, and R.C. Brown Hybrid thermochemical processing: fermentation of pyrolysis derived bio-oil Applied Microbiology and Biotechnology 91 6 2011 1519 1523
5. A. Broido, A.C. Javier-Son, A.C. Ouano, and E.M. Barrall II Molecular weight decrease in the early pyrolysis of crystalline and amorphous cellulose Journal of Applied Polymer Science 17 12 1973 3627 3635
6. O.P. Golova Chemical effects of heat on cellulose Russian Chemical Reviews 44 1975 687 697
7. F. Shafizadeh, R.H. Furneaux, T.G. Cochran, J.P. Scholl, and Y. Sakai Production of levoglucosan and glucose from pyrolysis of cellulosic materials Journal of Applied Polymer Science 23 1979 3525 3539
8. F. Shafizadeh, and T.T. Stevenson Saccharification of Douglas-Fir wood by a combination of prehydrolysis and pyrolysis Journal of Applied Polymer Science 27 1982 4577 4585
9. J. Piskorz, D. Radlein, and D.S. Scott On the mechanism of the rapid pyrolysis of cellulose Journal of Analytical and Applied Pyrolysis 9 2 1986 121 137
10. J. Piskorz, D. Radlein, D.S. Scott, and S. Czernik Pretreatment of wood and cellulose for production of sugars by fast pyrolysis Journal of Analytical and Applied Pyrolysis 16 1989 127 142
11. J. Piskorz, P. Majerski, D. Radlein, A. Vladars-Usas, and D.S. Scott Flash pyrolysis of cellulose for production of anhydro-oligomers Journal of Analytical and Applied Pyrolysis 56 2000 145 166
12. D. Radlein, J. Piskorz, A. Grinshpun, and D.S. Scott Fast pyrolysis of pre-treated wood and cellulose American Chemical Society, Division of Fuel Chemistry 32 2 1987 29 35
13. D. Radlein, A. Grinshpun, J. Piskorz, and D.S. Scott On the presence of anhydro-oligosaccharides in the syrups from the fast pyrolysis of cellulose Journal of Analytical and Applied Pyrolysis 12 1987 39 49
14. D. Radlein, J. Piskorz, and D.S. Scott Fast pyrolysis of natural polysaccharides as a potential industrial process Journal of Analytical and Applied Pyrolysis 19 1991 41 63
15. D.S. Scott, J. Piskorz, D. Radlein, P. Majerski, Process for the production of anhydrosugars from lignin and cellulose containing biomass by pyrolysis, US Patent: 5,395,455 (1995).
16. D.S. Scott, J. Piskorz, Process for the production of fermentable sugars from biomass, US Patent 4,880,473 (1989).
17. T. Hosoya, H. Kawamoto, and S. Saka Different pyrolytic pathways of levoglucosan in vapor and in liquid/solid phases Journal of Analytical and Applied Pyrolysis 83 2008 64 70
18. T. Hosoya, H. Kawamoto, and S. Saka Solid/liquid and vapor phase interactions between cellulose and lignin-derived pyrolysis products Journal of Analytical and Applied Pyrolysis 85 2009 237 246
19. H. Kawamoto, H. Morisaki, and S. Saka Secondary decomposition of levoglucosan in pyrolytic production from cellulosic biomass Journal of Analytical and Applied Pyrolysis 85 2009 247 251
20. R. Vinu, and L.J. Broadbelt A mechanistic model of fast pyrolysis of glucose-based carbohydrates to predict bio-oil composition Energy and Environmental Science 5 2012 9808 9826
21. M.S. Mettler, D.G. Vlachos, and P.J. Dauenhauer Top ten fundamental challenges of biomass pyrolysis for biofuels Energy and Environmental Science 5 2012 7797 7809
22. P.R. Patwardhan, J.A. Satrio, R.C. Brown, and B.H. Shanks Influence of inorganic salts on the primary pyrolysis products of cellulose Bioresource Technology 101 2010 4646 4655
23. J. Lian, S. Zhou, S. Chen, Z. Wang, C.-Z. Li, and M. Garcia-Perez Separation, hydrolysis and fermentation of pyrolytic sugars Bioresource Technology 101 2010 9688 9699
24. F. Shafizadeh Introduction to pyrolysis of biomass Journal of Analytical and Applied Pyrolysis 3 1982 283 305
25. M.J. Antal Biomass pyrolysis: a review of the literature. Part I. Carbohydrate pyrolysis K.W. Boer, J.A. Duffie, Advances in Solar Energy Vol. I 1982 American Solar Energy Society Boulder, CO 61 111
26. H.B. Mayes, and L.J. Broadbelt Unraveling the reactions that unravel cellulose Journal of Physical Chemistry A 116 26 2012 7098 7106
27. G.A. Zickler, W. Wagermaier, S.S. Funari, M. Burghammer, and O. Paris In situ X-ray diffraction investigation of thermal decomposition of wood cellulose Journal of Analytical and Applied Pyrolysis 80 2007 134 140
28. D.-Y. Kim, Y. Nishiyama, M. Wada, S. Kuga, and T. Okano Thermal decomposition of cellulose crystallites in wood Holzforschung 55 2001 521 524
29. U.-J. Kim, S.-H. Eom, and M. Wada Thermal decomposition of native cellulose: influence on crystallite size Polymer Degradation and Stability 95 5 2010 778 781
30. G.R. Ponder, G.N. Richards, and T.T. Stevenson Influence of linkage position and orientation in pyrolysis of polysaccharised: a study of several glucans Journal of Analytical and Applied Pyrolysis 22 1992 217 229
31. K.E. Cabradilla, and S.H. Zeronian Influence of crystallinity on the thermal properties of cellulose F. Shafizadeh, K.V. Sarkanen, D.A. Tillman, Thermal Uses and Properties of Carbohydrates and Lignins 1976 Academic Press New York 73 96
32. A. Broido, and M. Weinstein Thermogravimetric analysis of ammonia-swelled cellulose Combustion Science and Technology 1 4 1970 279 285
33. M. Weinstein, and A. Broido Pyrolysis-crystallinity relationships in cellulose Combustion Science and Technology 1 4 1970 287 292
34. J. Zhang, J. Luo, D. Tong, L. Zhu, L. Dong, and C. Hu The dependence of pyrolysis behavior on the crystal state of cellulose Carbohydrate Polymers 79 1 2010 164 169
35. J. Schroeter, and F. Felix Melting cellulose Cellulose 12 2005 159 165
36. P.J. Dauenhauer, J.L. Colby, C.M. Balonek, W.J. Suszynski, and L.D. Schmidt Reactive boiling of cellulose for integrated catalysis through an intermediate liquid Green Chemistry 11 2009 1555 1561
37. J. Lede Cellulose pyrolysis kinetics: an historical review on the existence of intermediate active cellulose Journal of Analytical and Applied Pyrolysis 94 2012 17 32
38. V. Mamleev, S. Bourbigot, M. Le Bras, and J. Yvon The facts and hypotheses relating the phenomenological model of cellulose pyrolysis. Interdependence of the steps Journal of Analytical and Applied Pyrolysis 84 2009 1 17
39. K. Mazeau, and L. Heux Molecular dynamics simulations of bulk native crystalline and amorphous structures of cellulose Journal of Physical Chemistry B 107 2003 2394 2403
40. A. Oja, and E.M. Suuberg Vapor pressures and enthalpies of sublimation of d-glucose, d-xylose, cellobiose and levoglucosan Journal of Chemical and Engineering Data 44 1999 26 29
41. S. Park, J.O. Baker, M.E. Himmel, P.A. Parilla, and D.K. Johnson Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance Biotechnology for Biofuels 3 2010 10
42. M.L. Nelson, and R.T. O'Connor Relation of certain infrared bands to cellulose crystallinity and crystal lattice type. Part II. A new infrared ratio for estimation of crystallinity in celluloses I and II Journal of Applied Polymer Science 8 3 1964 1325 1341
43. M. Garcia-Perez, A. Chaala, J. Yang, and C. Roy Co-pyrolysis of sugarcane bagasse with petroleum residue. Part I. Thermogravimetric analysis Fuel 80 2001 1245 1258
44. P.H. Hermans, and A. Weidinger Quantitative X-ray investigation on the crystallinity of cellulose fibers. A back ground analysis Journal of Applied Physics 19 1948 491 509
45. Y. Nakai, E. Fukuoka, S. Nakajima, and J. Hasegawa Crystallinity and physical characteristics of microcrystalline cellulose Chemical and Pharmaceutical Bulletin 25 1977 96 101
46. V. Mamleev, S. Bourbigot, and J. Yvon Kinetic analysis of the thermal decomposition of cellulose: the main step of mass loss Journal of Analytical and Applied Pyrolysis 80 2007 151 165
47. P.M. Molton, T.F. Demmitt, Reaction Mechanism in Cellulose Pyrolysis: A Literature Review, Report Prepared for the Energy Research and Development Administration under Contract EY-76-C-06-1830, 1977.
48. J. Scheirs, G. Camino, and W. Tumiatti Overview of water evolution during the thermal degradation of cellulose European Polymer Journal 37 2001 933 942
49. J. Scheirs, G. Camino, M. Avidano, and W. Tumiatti Origin of furanic compounds in thermal degradation of cellulosic insulating paper Journal of Applied Polymer Science 89 1998 2541 2547
50. J.B. Paine III, Y.B. Pithawalla, and J.D. Naworal Carbohydrate pyrolysis mechanism from isotopic labeling. Part 3. The pyrolysis of d-glucose: formation of C3 and C4 carbonyl compounds and a cyclopentanedione isomer by electrocyclic fragmentation mechanisms Journal of Analytical and Applied Pyrolysis 82 2008 42 69
51. I. Pastorova, R.E. Botto, P.W. Arisz, and J.J. Boon Cellulose char structure: a combines analytical Py-GC/MS, FTIR, and NMR study Carbohydrate Research 262 1994 27 47
52. J.B. Paine III, Y.B. Pithawalla, J.D. Naworal, and C.E. Thomas Carbohydrate pyrolysis mechanisms from isotopic labeling. Part 1. The pyrolysis of glycerin: discovery of competing fragmentation mechanisms affording acetaldehyde and formaldehyde and the implications for carbohydrate pyrolysis Journal of Analytical and Applied Pyrolysis 80 2007 297 311
53. J.B. Paine III, Y.B. Pithawalla, and J.D. Naworal Carbohydrate pyrolysis mechanism from isotopic labeling. Part 2. The pyrolysis of d-glucose: general disconnective analysis and the formation of C1 and C2 carbonyl compounds by electrocyclic fragmentation mechanisms Journal of Analytical and Applied Pyrolysis 82 2008 10 41
54. J.B. Paine III, Y.B. Pithawalla, and J.D. Naworal Carbohydrate pyrolysis mechanisms from isotopic labeling. Part 4. The pyrolysis of d-glucose: the formation of furans Journal of Analytical and Applied Pyrolysis 83 2008 37 63