Carbohydrate pyrolysis mechanisms from isotopic labeling. Part 3. The Pyrolysis of d-glucose: Formation of C3 and C4 carbonyl compounds and a cyclopentenedione isomer by electrocyclic fragmentation mechanisms

Journal of Analytical and Applied Pyrolysis

Volumn 82, Issue 1, 2008, Pages 42-69

  Paine III, John B ^a   Pithawalla, Yezdi B ^a   Naworal, John D ^a  

^a Philip Morris USA Research Center   (United States)

Author keywords

1 Cyclopentene 3,4 dione; 2,3 Butanedione; 2 Butanone; Acetol; Acetone; Acrolein; Crotonaldehyde; Cyclic Grob fragmentation; d Glucose; Dihydroxyacetone; Isotopic labeling; Isotopolog; Methacrolein; Methyl reductone; Methyl vinyl ketone; Pinacol rearrangement; Propionaldehyde; Pyrolysis; Pyruvaldehyde

Indexed keywords

ACETONE; ALDEHYDES; CYCLIC VOLTAMMETRY; GLYCEROL; ISOMERS; PYROLYSIS;

ACETOL; ACROLEIN; CYCLIC GROB FRAGMENTATION; ISOTOPIC LABELING; ISOTOPOLOG; METHYL REDUCTONE; METHYL VINYL KETONE; PINACOL REARRANGEMENT; PROPIONALDEHYDE; PYRUVALDEHYDE;

GLUCOSE;

EID: 43049154357     PISSN: 01652370     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jaap.2007.12.005     Document Type: Article

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