Enhancement of mineralization of metronidazole by the electro-Fenton process with a Ce/SnO2-Sb coated titanium anode

Chemical Engineering Journal

Volumn 220, Issue , 2013, Pages 214-220

  Cheng, Wen ^a,b,c   Yang, Man ^a,b   Xie, Yingying ^a,b   Liang, Bin ^a,b   Fang, Zhanqiang ^a,b,c   Tsang, Eric Pokeung ^d  

^a SOUTH CHINA NORMAL UNIVERSITY   (China)

^b Guangdong Technology Research Center for Ecological Management and Remediation of Urban Water System   (China)

^c BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

^d THE EDUCATION UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

Electro Fenton; Electrochemical; Metronidazole; Mineralization

Indexed keywords

ADVANCED OXIDATION PROCESSES; ADVANCED PROCESS; BIOCHEMICAL TREATMENTS; CATALYST CONCENTRATION; COATED TITANIUM; DEGRADATION BEHAVIOR; DIFFERENT TREATMENTS; EF TREATMENT; ELECTRO-FENTON; ELECTRO-FENTON PROCESS; ELECTROCHEMICAL; FAVORABLE CONDITIONS; INPUT VARIABLES; METRONIDAZOLE; MINERALIZATION; MOLAR RATIO; NON-TOXIC; NON-TOXIC PRODUCTS; OPTIMUM CONDITIONS; PH LEVELS; PHOTOBACTERIUM; PRETREATMENT TECHNOLOGY; TOTAL ORGANIC CARBON; TOXICITY OF WASTE WATERS;

BIOASSAY; BIODEGRADATION; CHEMICAL OXYGEN DEMAND; TOXICITY;

MINERALOGY;

EID: 84873934863     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2013.01.055     Document Type: Article

References (32)

1. Lindberg R., Jarnheimer P.A., Olsen B., Johansson M., Tysklind M. Determination of antibiotic substances in hospital sewage water using solid phase extraction and liquid chromatography/mass spectrometry and group analogue internal standards. Chemosphere 2004, 57:1479-1488.
2. Rosal R., Rodriguez A., Perdigon-Melon J.A., Petre A., Garcia-Calvo E., Gomez M.J., Aguera A., Fernandez-Alba A.R. Occurrence of emerging pollutants in urban wastewater and their removal through biological treatment followed by ozonation. Water Res. 2010, 44:578-588.
3. Bendesky A., Menendez D., Ostrosky-Wegman P. Is metronidazole carcinogenic?. Mutat. Res. - Rev. Mutat. Res. 2002, 511:133-144.
4. Lanzky P.F., HallingSorensen B. The toxic effect of the antibiotic metronidazole on aquatic organisms. Chemosphere 1997, 35:2553-2561.
5. Rivera-Utrilla J., Prados-Joya G., Sanchez-Polo M., Ferro-Garcia M.A., Bautista-Toledo I. Removal of nitroimidazole antibiotics from aqueous solution by adsorption/bioadsorption on activated carbon. J. Hazard. Mater. 2009, 170:298-305.
6. Dantas R.F., Rossiter O., Teixeira A.K.R., Simoes A.S.M., da Silva V.L. Direct UV photolysis of propranolol and metronidazole in aqueous solution. Chem. Eng. J. 2010, 158:143-147.
7. 30. Wuhan Univ. J. Nat. Sci. 2010, 15:345-349.
8. Vertzoni M., Carlsson A., Abrahamsson B.L., Goumas K., Reppas C. Degradation kinetics of metronidazole and olsalazine by bacteria in ascending colon and in feces of healthy adults. Int. J. Pharm. 2011, 413:81-86.
9. Shemer H., Kunukcu Y.K., Linden K.G. Degradation of the pharmaceutical Metronidazole via UV Fenton and photo-Fenton processes. Chemosphere 2006, 63:269-276.
10. Fang Z., Chen J., Qiu X., Qiu X., Cheng W., Zhu L. Effective removal of antibiotic metronidazole from water by nanoscale zero-valent iron particles. Desalination 2011, 268:60-67.
11. Cronly M., Behan P., Foley B., Malone E., Regan L. Development and validation of a rapid method for the determination and confirmation of 10 nitroimidazoles in animal plasma using liquid chromatography tandem mass spectrometry. J. Chromatogr. B 2009, 877:1494-1500.
12. El-Ashtoukhy E.S.Z., Amin N.K. Removal of acid green dye 50 from wastewater by anodic oxidation and electrocoagulation - a comparative study. J. Hazard. Mater. 2010, 179:113-119.
13. Dirany A., Sires I., Oturan N., Oturan M.A. Electrochemical abatement of the antibiotic sulfamethoxazole from water. Chemosphere 2010, 81:594-602.
14. Guinea E., Garrido J.A., Rodriguez R.M., Cabot P.L., Arias C., Centellas F., Brillas E. Degradation of the fluoroquinolone enrofloxacin by electrochemical advanced oxidation processes based on hydrogen peroxide electrogeneration. Electrochim. Acta 2010, 55:2101-2115.
15. 2) anode. Chemosphere 2012, 87:614-620.
16. Jara C.C., Fino D., Specchia V., Saracco G., Spinelli R. Electrochemical removal of antibiotics from wastewaters. Appl. Catal. B - Environ. 2007, 70:479-487.
17. Zhao G., Gao J., Shen S., Liu M., Li D., Wu M., Lei Y. Ultrasound enhanced electrochemical oxidation of phenol and phthalic acid on boron-doped diamond electrode. J. Hazard. Mater. 2009, 172:1076-1081.
18. Estrada A.L., Li Y.Y., Wang A. Biodegradability enhancement of wastewater containing cefalexin by means of the electro-Fenton oxidation process. J. Hazard. Mater. 2012, 227-228:41-48.
19. Masomboon N., Ratanatamskul C., Lu M.C. Chemical oxidation of 2,6-dimethylaniline by electrochemically generated Fenton's reagent. J. Hazard. Mater. 2010, 176:92-98.
20. Pignatello J.J., Oliveros E., Mackay A. Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry. Crit. Rev. Environ. Sci. Technol. 2006, 36:1-84.
21. Kurt U., Apaydin O., Gonullu M.T. Reduction of COD in wastewater from an organized tannery industrial region by electro-Fenton process. J. Hazard. Mater. 2007, 143:33-40.
22. Sires I., Guivarch E., Oturan N., Oturan M.A. Efficient removal of triphenylmethane dyes from aqueous medium by in situ electrogenerated Fenton's reagent at carbon-felt cathode. Chemosphere 2008, 72:592-600.
23. Wang A., Qu J., Liu H., Ru J. Mineralization of an azo dye acid red 14 by photoelectro-Fenton process using an activated carbon fiber cathode. Appl. Catal. B - Environ. 2008, 84:393-399.
24. (R) and peroxi-coagulation processes using a flow reactor for wastewater treatment. Chemosphere 2002, 47:241-248.
25. Gozmen B., Oturan M.A., Oturan N., Erbatur O. Indirect electrochemical treatment of bisphenol in water via electro-chemically generated Fenton reagent. Environ. Sci. Technol. 2003, 37:3716-3723.
26. Ghoneim M.M., El-Desoky H.S., Zidan N.M. Electro-Fenton oxidation of sunset yellow FCF azo-dye in aqueous solutions. Desalination 2011, 274:22-30.
27. Mohajeri S., Aziz H.A., Isa M.H., Zahed M.A., Adlan M.N. Statistical optimization of process parameters for landfill leachate treatment using electro-Fenton technique. J. Hazard. Mater. 2010, 176:749-758.
28. 5 based anodes for wastewater treatment. J. Appl. Electrochem. 2003, 33:1211-1215.
29. Prados-Joya G., Sanchez-Polo M., Rivera-Utrilla J., Ferro-Garcia M. Photodegradation of the antibiotics nitroimidazoles in aqueous solution by ultraviolet radiation. Water Res. 2011, 45:393-403.
30. Sir ́es I., Arias C., Cabot P.L., Centellas F., Garrido J.A., Rodŕi{dotless}guez R.M., Brillas E. Degradation of clofibric acid in acidic aqueous medium by electro-Fenton and photoelectro-Fenton. Chemosphere 2007, 66:1660-1669.
31. Shen R.Y., Luo Y.M., Sun Y.H., Zhang G.Y., Li Z.G., Teng Y., Qian W. Synthetic biological toxicity of municipal sludges from the Yangtze River Delta Region. J. Ecol. Rural Environ. 2006, 22:54.
32. Sarria V., Parra S., Invernizzi M., Peringer P., Pulgarin C. Photochemical biological treatment of a real industrial biorecalcitrant wastewater containing 5-amino-6-methyl-2-benzimidazolone. Water Sci. Technol. 2001, 44:93-101.